The invention discloses an environment-friendly low-resilience low-alkaline liquid setting accelerator and a preparation method thereof. The environment-friendly low-resilience low-alkaline liquid setting accelerator is prepared from, by mass, 50-60% of a modified polyaluminium sulfate solution, 1-5% of modified fluoride salt, 1-4% of modified alcohol amine, 1-3% of a dispersant and 30-42% of water. The preparation method specifically includes the following steps that 1, the a modified polyaluminium sulfate solution is prepared; 2, modified fluoride salt is prepared; 3, modified alcohol amine is prepared; 4, the dispersant and the balance water are added, stirring is carried out for 1-4 h at 40-70 DEG C, and the finished product is obtained. As for the total alkali amount of the prepared low-alkaline liquid setting accelerator, Na2O+K2O<3%, the pH ranges from 3 to 5, and harm to the skin is small; when applied to spraying concrete, the low-alkaline liquid setting accelerator guarantees construction safety and has the advantages of being low in resilience, capable of significantly improving later-stage strength and the like.