The invention belongs to the technical field of inorganic salt materials, and specially relates to a preparation method of calcium carbonate particulates. The method comprises the following steps of adding 0.001 to 2 mol/L of a calcium salt into an 0.0005 to 1 g/L of additive solution to obtain a mixed solution, standing, adjusting a pH value of the mixed solution to a pH value of 5 to 12, through adopting different carbonate sources and corresponding different concentrations, carrying out a reaction at a temperature of 10 to 60 DEG C in an inclosed system for 10 minutes to 30 days, separating a product obtained by the previous step, and drying to obtain a desired product. Calcium carbonate particulates prepared by the method have different sizes which are in a range of 0.1 to 50 micrometers, different shapes such as a hexagonal petal shape and a globular shape, and high thermal stability. The method has the advantages of wide raw material source, low price, simple process, good operability, low pollution of adopted solvents, no toxic effect, good conformity with green chemistry requirements, and great potential for large-scale production.