The invention discloses a preparation method of a high barrier LDPE film. The preparation method comprises the following steps: adding LDPE, tetrabutyl
titanate,
ammonium bicarbonate, and nano
calcium carbonate into a sealing type rubber mixing mill, fully stirring to obtain a mixed material; then stirring and fully mixing butyl etherized
urea resin,
zinc stearate,
polyvinylidene difluoride, nano
montmorillonite,
toluene diisocyanate, and
peanut oil, carrying out reactions for 2 to 4 hours in a reactor, after reactions, delivering the
reaction product into a double screw granulator to carry out
granulation to obtain master batch; finally, fully stirring the master batch and the mixed material for an half hour, delivering the mixture to a double screw extruder to carry out melting and extruding, cooling,
cutting, splitting to obtain granules; adding residual raw materials into the granules, stirring and mixing, and finally performing melting, plasticizing, mouth model molding, blowing,
corona disposing, and reeling in a film blowing facility. Through the nano material modification, the prepared LDPE film has a good performance on blocking
oxygen, high
chemical stability, good heat sealing property, excellent waterproof property, and good performance on resisting damp and cold. Moreover, the preparation method is simple. The LDPE film has a good application value.