The invention relates to a preparation method of a flexible
OLED light-emitting device based on the
anode structure of a novel laminated film. The
OLED light-emitting device comprises a light-emitting layer and a
cathode positioned on one side of the light-emitting layer. The method comprises the following steps: S1, growing
graphene on a
copper foil by adopting a
chemical vapor deposition method; S2, transferring the
graphene onto a flexible
PET substrate; S3, putting the prepared
graphene / PET into an HNO3 solution for soaking, and then
drying; S4, spraying a PEDOT:PSS solution on the treated graphene, then putting on a heating plate for
drying; and S5, putting a prepared graphene / PEDOT:PSS
composite film into a vacuum cavity, adopting a
vacuum evaporation technology to heat and plate the graphene / PEDOT:PSS
composite film on the side, at the back of the
cathode, of the light-emitting layer as an
anode, and thus preparing the
OLED light-emitting device. The graphene serves as the
anode of a photoelectric device, so that the anode has the characteristics of high carrier mobility, good mechanical flexibility,
high transmittance and the like; and the PEDOT:PSS enables the anode to be of the characteristics of
high conductivity, high
work function and
high transmittance.