The invention discloses a CC-NiO-CuCoS composite material. The CC-NiO-CuCoS composite material is composed of CC, NiO and CuCo2S4, wherein CC is a base material, the microstructure of CC is of a fibrous structure, and CC is used for providing a substrate, so NiO nanosheets cannot be stacked, and the conductive substrate is beneficial to ultra-high-speed transportation of electrons; the microstructure of NiO is a nanosheet structure, and NiO is loaded on the surface of CC and is used for providing extra pseudocapacitance; and the microstructure of CuCo2S4 is a nano-particle structure, and CuCo2S4 is attached to the surfaces of the CC and NiO nanosheets, and is used for stabilizing the sheet structure of NiO and covering a part of exposed CC. According to the invention, the CC-NiO-CuCoS composite material is prepared from CC, nickel nitrate hexahydrate, ammonium fluoride, urea, cupric acetate monohydrate, cobalt acetate tetrahydrate and thiourea are used as initial raw materials throughtwo-step hydrothermal preparation. The preparation method comprises the following steps of (1) cleaning and activation of CC; (2) preparation of a CC-NiO composite material; and (3) preparation of theCC-NiO-CuCo2S4 composite material. When the composite material is used as a supercapacitor electrode material, specific capacitance is 840 F g<-1>, and cycling stability after 3000 cycles is 100%.