The invention discloses a preparation method of
antioxidant compact compound
tungsten carbide-based rare
metal ceramic, and relates to the field of
metal ceramic. Firstly, a
silicon carbide substance is introduced through polycarbosilane,
ceramic pores are filled with
metal zirconium through a metal infiltration reaction, compactness is improved, and meanwhile the
oxidation resistance of a ceramic matrix is enhanced; and then, a
tungsten carbide enrichment layer is formed on the surface of the ceramic in a mode of combining
ion injection infiltration and spraying, and the high-temperature and high-speed
tungsten carbide and the metal
adhesive are combined with the originally injected
tungsten carbide enrichment layer into a whole during spraying. Secondly, high-proportion rare metal nano
rhenium is adopted, and material surface densification of the
tungsten carbide-based metal ceramic compound
coating in a high-temperature environment is achieved; finally, through
hydrogen reduction treatment, the
oxygen content of the
powder is further reduced, and the high-activity low-
oxygen compound carbide rare metal ceramic with the nanocrystalline structure is produced. The ceramic prepared by the invention has the effects of
oxidation resistance and compactness.