The invention discloses a film electrode and a manufacturing method thereof and application. The electrode is composed of a conductive polymer film and a substrate, and is characterized in that the conductive polymer film has a conductive polymer grid structure; and the conductive polymer can be applied to the substrate such as glass, quartz, fiber, fabric, a plastic film and a polymer film to form the conductive film electrode. Particularly, when a flexible or an extensible transparent substrate is selected, a flexible and transparent film electrode can be manufactured. Patterned grid manufacturing can be realized through a printing method, the process is simple, convenient, economic and efficient, materials are saved, the structure can be controlled, the shape and the size can be adjusted randomly, and more importantly, large-area quick manufacturing can be realized. The electrode can be used as a transparent film electrode to replace an indium tin oxide (ITO) transparent electrode and can be widely used for building a flexible organic light-emitting device, a flexible organic solar cell device, a flexible organic field-effect transistor device or a flexible energy storage device.