The invention relates to the technical field of electrocatalytic degradation application, in particular to a method for conducting electrocatalytic oxidation treatment on phenol organic wastewater through a novel anode. The method includes the following steps of S1, preparing a titanium dioxide nanotube array; S2, modifying NiO in nanotubes through a pulse depositing method and a high-temperaturecalcination method to prepare a Ti/TiO2NTs-NiO electrode high in conductivity; S3, using the Ti/TiO2NTs-NiO electrode as a working electrode, and preparing a high-performance Ti/TiO2NTs-NiO/PbO2 anodematerial through pulses; S4, conducting electrocatalytic oxidation treatment on the phenol organic wastewater through the prepared Ti/TiO2NTs-NiO/PbO2 anode material. The Ti/TiO2NTs-NiO/PbO2 modifying electrode is used as the anode, electrocatalytic oxidation treatment is conducted on the toxic phenol organic wastewater in an electrolytic cell, the degradation efficiency is higher than that of anordinary lead electrode, the degradation rate of COD of the phenol organic wastewater can reach 92.7%, the average current efficiency in the degradation process is remarkably improved compared with that of the ordinary lead electrode, the average current efficiency reaches 34%, electric energy loss is effectively reduced, and meanwhile degradation efficiency is improved.