The application discloses a preparation method of a P / N / Si multi-element reactive
halogen-free
flame retardant, specifically comprising the following steps: preparing DOPO grafted 3-chloropropyl trimethoxysilane, which is denoted as PPTMS; preparing a cage-like POSS containing DOPO, which is denoted as PSC; mixing the PSC with
toluene to obtain a PSC solution; uniformly mixing
maleimide MI with
toluene, dropwise adding the PSC solution into the
maleimide MI solution to perform a condensation
reflux reaction, and performing vacuum rotary
evaporation to obtain the P / N / Si multi-element reactive
halogen-free
flame retardant. The
phosphorus-containing
monomer, the
nitrogen-containing
monomer and the
silicon-containing
monomer in the
flame retardant are covalently bonded, and the multi-elements in the molecule exist in the form of a collection acid source, a
carbon source, a gas source and a ceramicization, wherein the
phosphorus-containing monomer is dehydrated into carbon, the
nitrogen-containing monomer releases non-
combustible gas to dilute the
gas phase, and the
silicon-containing monomer forms a dense
ceramic barrier layer to improve the triple
synergy of carbon residue strength and anti-dripping property, thereby greatly improving the flame retardant efficiency.