This invention discloses a piezoelectric self-renewing gradient
ceramic catalytic membrane and its preparation method, belonging to the field of porous
ceramic technology. The method includes the preparation of a porous piezoelectric
ceramic substrate, LDH
transition layer modification, and catalyst
electrophoretic deposition. The catalyst
electrophoretic deposition method involves dispersing the catalyst in a
solvent, adjusting the suspension to make the catalyst particle surface positively charged, obtaining a catalyst suspension; using a
ceramic substrate modified with a positively charged
transition layer as the
cathode and a
graphite rod as the
anode, immersing both electrodes in the catalyst suspension, controlling the distance between the two electrodes to 1.4-1.6 cm, connecting a
constant voltage DC power supply of 20-40V, and depositing for 5-15 minutes. After deposition, the sample is removed and subjected to post-
processing and polarization treatment to obtain the catalytic
ceramic membrane product. This invention utilizes
fluid pressure fluctuations to excite the piezoelectric effect, achieving in-situ mechanical exfoliation and self-renewal of catalytically activated and surface-deactivated catalysts, significantly improving
catalytic efficiency and long-term stability.