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54results about How to "Promote dehydrogenation" patented technology

Method and system for hydrogen evolution and storage

A method and system for storing and evolving hydrogen employ chemical compounds that can be hydrogenated to store hydrogen and dehydrogenated to evolve hydrogen. A catalyst lowers the energy required for storing and evolving hydrogen. The method and system can provide hydrogen for devices that consume hydrogen as fuel.
Owner:TRIAD NAT SECURITY LLC

Carbon material film with high electric conductivity, heat conductivity and strength and preparing method thereof

The invention provides a carbon material film with high electric conductivity, heat conductivity and strength and a preparing method thereof. The carbon material film is prepared according to the steps of adding functional carbon material powder and a dispersant to a solvent to be mixed and stirred; adding a binder and a plasticizer, and conducting mixing to obtain uniform and stable slurry; forming a blank film; placing the blank film in the solvent for reaction; evaporating the solvent; increasing temperature to 1000-3000 DEG C for sintering lasting 1-10 h to obtain the carbon material film. Through functional modification and then tape-casting and sintering of the surface of the carbon material, active groups between different sheets of the carbon material react with one another to form chemical bonds, and a carbon net stable structure is formed finally so that different sheets of the carbon material can be connected in the true sense. In this way, the mechanical strength, electric conductivity and heat conductivity of the carbon material film are improved greatly.
Owner:HEFEI GENIUS NEW MATERIALS

Method for preparing conducting film LiFePO4 cladding material containing nitrogen

InactiveCN101924204AImplementation of the problem of non-uniform growth rateEliminate the problem of non-uniform growth rateCell electrodesPhosphorus compoundsCarbon filmReaction temperature
The invention relates to a preparation method of a lithium ion battery anode material, aiming to provide a method for preparing a conducting film LiFePO4 cladding material containing nitrogen. The method comprises the following steps of: ball milling and mixing FePO4.4H2O, LiOH.H2O and a polyacrylonitrile emulsion, blending into a paste and putting the paste into a quartz reactor; regulating and controlling the microwave output power and controlling the reaction temperature to be at 150 DEG C; raising the microwave output power in an oxygen atmosphere and heating up to 300 DEG C from 150 DEG C; switching to a highly pure nitrogen atmosphere, raising the microwave output power and heating up to 600 DEG C from 300 DEG C; and continuously raising the microwave output power under the highly pure nitrogen atmosphere and annealing at 700-800 DEG C for denitrifying. Nitrogen atoms remain on the conducting carbon film formed by the invention, and lone pair electrons of the nitrogen atoms can effectively improve the conductivity of the carbon film so as to improve electrochemical and dynamic properties of the anode, reduce the electrode polarization and improve the velocity volume of the lithium cell, thus the invention can be applied to power cells of electric vehicles.
Owner:ZHEJIANG UNIV

High-performance sulfenyl composite anode material and preparation method thereof

The invention discloses a high-performance sulfenyl composite anode material and a preparation method thereof. The composite material is formed by compounding a conductive polymer with M-doped sulfur,and is xP.{(1-x)[yM.(1-y)S]} particularly, wherein P stands for the conductive polymer, S is sulfur, M is one or two of Se and Te, x and (1-x) are separately the mass percent of the conductive polymer and the mass percent of the M-doped sulfur, y and (1-y) are separately the mass percent of M in the M-doped sulfur and the mass percent of sulfur, 0<x<1, and 0<y<1. The high-performance sulfenyl composite anode material can be obtained by modifying and further optimizing various components in the sulfenyl composite anode material and the corresponding ratios, the corresponding preparation methods and the like, and the problems that in the prior art, the electrical conductivity is low, and the activity of an electrode is low and the cycle life is poor due to solubility and diffusion of polysulfide are solved.
Owner:HUAZHONG UNIV OF SCI & TECH

Copper-azole microporous crystalline material and preparation method thereof

InactiveCN102532169AMaterial Structure RulesUniform channel sizeCopper organic compoundsCopper chlorideCrystalline materials
The invention discloses a nano porous crystalline material {[Cu (HTCPZ) 0.5]} infinity and a preparation method thereof. The preparation method of the nano porous crystalline material is characterized in that: 3-(4-tetrazole-phenyl) amine and copper chloride are subjected to solvothermal synthesis according to a molar ratio of 1:(3-15) at a temperature of 80-180 DEG C; the molecular formula of the obtained Cu-based microporous crystalline material is {[Cu (HTCPZ) 0.5]} infinity, wherein HTCPZ is 3-(4-tetrazole-phenyl) amine which is a tridentate ligand having the following molecular structure shown in the accompany drawing; and the porous crystalline material is a hexagonal system crystalline material, the space group is P6122, the size range of a pore canal is 1-1.2nm, and the inner surface of the pore canal contains a coordinatively unsaturated surface of metal Cu. The preparation method provided by the invention has the advantages of simpleness, mild reaction conditions, high yield and high purity of products. The porous crystalline material prepared by the invention has the advantages of uniform pore canal, nanopore size, and metal center immobilizing.
Owner:UNIV OF SCI & TECH OF CHINA

Method for preparing steroidal drug intermediate

The invention relates to a method for preparing a steroidal drug intermediate. The method comprises the steps that microbial conversion is conducted on a first compound with Nocardioides simplex to obtain the steroid drug intermediate, the first compound is shown as a formula I, the steroidal drug intermediate is as shown in a formula II, and in the formula I and the formula II, R is H, a halogenatom, an alkyl group, an alkoxy group, a hydroxyl group or a phenyl group. The method selects 4, 9 (11)-pregnant-17-hydroxy group-3,20 dioxin-21-acetate as a substrate, uses only the Nocardioides simplex for biotransformation, dehydrogenation at position 1,2 and hydrolysis of acetate at position 21 are simultaneously conducted on the substrate, 1,4,9 (11)-pregnene-17,21-diol-3,20-dione is obtained, products formed through transformation are mainly the 1,4,9(11)-pregnene-17,21-diol-3,20-dione, the proportion of by-products is low, the purified products are white or off-white crystals, relativesubstrate weight yield is 75%-85%, a target product yield is high, after a HPLC analysis, the purity is >=99%, and external standard content is 98%.
Owner:HUNAN NORCHEM PHARMACEUTICAL CO LTD

Catalyst for selective paraffin isomerization and preparation method and use thereof

The present invention discloses a catalyst for paraffin isomerization, as well as a preparation method and use thereof. The catalyst comprises a TON molecular sieve modified by rare earth, an inorganic refractory oxide modified by zirconium oxide and a noble metal of group VIII. The weight ratio of the TON molecular sieve modified by rare earth to the inorganic refractory oxides modified by zirconium oxide is 10:90 to 90:10, and the content of the metal of group VIII is 0.1 to 10 wt % based on the metal. When used in the process of isomerization dewaxing of various raw materials containing paraffins, the catalyst can not only decrease the solidifying points of raw oil containing paraffins, but also increase the yield of liquid products. Particularly, when used in the process of isomerization dewaxing of lubricating oil distillates, the catalyst is advantageous in producing base oil for lubricating oil with a high a higher yield, a lower pour point (solidifying point) and a higher viscosity index.
Owner:CHINA PETROCHEMICAL CORP +1

High-strength low-abrasion abrasion-resisting ball used for ball mill and preparation method of high-strength low-abrasion abrasion-resisting ball

InactiveCN107739994AGood toughening effectStrengthen the toughening effect, effectively improve the wear resistance of wear-resistant ballsMetallic material coating processesHigh intensityBall mill
The invention discloses a high-strength low-abrasion abrasion-resisting ball used for a ball mill and a preparation method of the high-strength low-abrasion abrasion-resisting ball. The high-strengthlow-abrasion abrasion-resisting ball used for the ball mill comprises a cladding layer and an abrasion-resisting ball base body, and the abrasion-resisting ball base body comprises the following components of C, B, Ti, Mg, Si, W, Cr, Mn, Ni, V, Zr, Nb, Mo, Ce, Nd, Sm, Er and the balance Fe and inevitable impurities. According to the high-strength low-abrasion abrasion-resisting ball used for the ball mill and the preparation method of the high-strength low-abrasion abrasion-resisting ball, through optimization of the matching ratio and a preparation technology, the high-strength low-abrasion abrasion-resisting ball has the advantages of being large in impact toughness, good in corrosion resistance, large in strength, small in abrasion and the like, and the working efficiency of the abrasion-resisting ball is effectively improved.
Owner:蚌埠市光辉金属加工厂

Pt-Ni binary alloy supported CeO2 nanoparticles and preparation method thereof

ActiveCN110993967AImprove anti-poisoning performanceImproved resistance to CO poisoningCell electrodesPtru catalystCerium(IV) oxide
The invention relates to Pt-Ni binary metal alloy supported cerium dioxide nanoparticles and a preparation method thereof. The Pt-Ni binary metal alloy loaded cerium dioxide is synthesized in one stepby utilizing a solvothermal method. Specifically, oleylamine oleic acid is adopted as a dispersing agent to inhibit growth of crystals, and added formaldehyde can induce CeO2 in gaps in the surface of Pt-Ni alloy, so that whether rare earth metal oxide has the effects of improving CO poisoning resistance of the catalyst and improving electro-catalysis of the catalyst or not is explored. The synthesized CeO2 with very small diameter is added to the surface of the catalyst by utilizing gaps in Pt-Ni alloy groups, and the CO poisoning resistance of the metal catalyst is improved by utilizing thestrong oxidation effect of the CeO2 on CO, so that the electro-catalytic stability of the metal catalyst is remarkably improved.
Owner:UNIV OF JINAN

Preparation method of catalyst for high efficient catalytic degradation of harmful gas PH3

The invention discloses a preparation method of a catalyst for high efficient catalytic degradation of harmful gas PH3. According to the preparation method, low cost natural halloysite nano tubes (HNTs) are taken as the carrier; nickel chloride, ferric chloride, and ferrous sulfate are taken as the precursors; based on a chemical plating technology, and a nickel nano clad layer is plated on the halloysite nano tubes (HNTs) to form a one-dimensional shell / core structure. Then through a co-precipitation method, Fe3O4 nano particles are loaded on the nickel clad layer surface in a dotted mode toform a one dimensional shell / dual core structure. The preparation method has the advantages that there is no severe requirement on physical conditions, the method is simple, the price of HNTs is low,and the efficiency of using the catalyst to degrade PH3 catalytically is high, and the service life is long.
Owner:天津格林凯恩化工科技有限公司

Traditional Chinese medicine preparation for treating hyperplasia of mammary glands

The invention discloses a traditional Chinese medicine preparation for treating hyperplasia of mammary glands. The preparation is composed of the following bulk pharmaceutical chemicals in grams by weight: 20-30g of cornu cervi degelatinatum, 20-30g of poria cocos, 20-30g of epimedium Herb, 15-25g of semen raphani, 15-25g of red flower, 15-25g of honeysuckle, 15-25g of agastache rugosus, 15-25g of rehmannia glutinosa, 10-20g of scorpio, 10-20g of parasitic loranthus, 10-20g of cortex acanthopanacis, 5-15g of cortex Erythrinae, 5-15g of sandalwood, 5-15g of prunella vulgaris, 5-15g of galangal and 5-15g of Chinese mahonia. During treatment, the preparation is orally taken once for every breakfast, lunch and supper everyday by 3g every time. By regarding fifteen days as a course of treatment, two to six courses are generally required for curing. The traditional Chinese medicine preparation for treating hyperplasia of mammary glands provided by the invention has the advantages of scientific and rigorous composition, strong pointedness, good therapeutic and curative effect without toxic side effect. Moreover, the total effective rate is about 94.6 after years of clinical application.
Owner:赵辉

Preparation method of ultra-pure G102Cr18Mo stainless bearing steel

The invention discloses a preparation method of ultra-pure G102Cr18Mo stainless bearing steel, and belongs to the technical field of metal smelting. According to the method, firstly, base metal needed for preparing the ultra-pure G102Cr18Mo stainless bearing steel is obtained through intermediate frequency furnace smelting, LF furnace refining, sedation treatment and die casting, the oxygen content ranges from 20 ppm to 30 ppm, and conditions are created for ultra-pure stainless steel bearing steel smelting; then, the base metal is subjected to forging and scaling treatment and then is put into a vacuum induction furnace to be melted and refined, and no alloy element is added in the vacuum induction treatment process; a consumable electrode subjected to vacuum induction melting is subjected to vacuum consumable remelting twice, and the G102Cr18Mo stainless bearing steel with extremely high purity can be obtained.
Owner:ANHUI FUKAI STAINLESS STEEL

Combined reactor for preparing olefin by alkane dehydrogenation and hydrocarbon catalytic cracking

The invention relates to a combined reactor for preparing olefin by alkane dehydrogenation and hydrocarbon catalytic cracking. The reactor for preparing olefin by catalytic dehydrogenation-cracking ofalkane comprises a catalytic dehydrogenation-cracking reactor and a reactor settling section, the reactor settling section is located at the upper part of the reactor, the reactor comprises a dehydrogenation reaction section and a cracking reaction section, the dehydrogenation reaction section is located below the cracking reaction section, and one end of a catalyst regeneration inclined pipe isconnected with the dehydrogenation reaction section. The method is beneficial to dehydrogenation reaction and catalytic cracking reaction.
Owner:SHANGHAI SUPEZET ENG TECH CO LTD +4

Method for growing graphene on silicon substrate by using PEALD

The invention discloses a method for growing graphene on a silicon substrate by using PEALD. The clean silicon substrate is placed in a reaction chamber for carrying out PEALD cycles, and each cycle comprises the following steps: (1) carrying out adsorption of a carbon source or an auxiliary source, wherein the carbon source is selected from at least one of benzene series and methane, and the auxiliary source is an oxygen-containing organic matter; (2) cleaning the adsorbed silicon substrate, and carrying out plasma pulse; and (3) cleaning the silicon substrate after plasma pulse. According tothe method, graphene can be grown on the silicon substrate in a large area, and has good compatibility with a current silicon-based semiconductor technology. According to the method, growth is promoted by using oxygen-containing small molecules, on one hand, vacancy-type defects are compensated by taking graphene as small molecular carbon, the D peak of a defect peak after the reaction is reduced, on the other hand, the participation of oxygen element promotes a dehydrogenation process of benzene in the growth process, the size of wrinkles after film formation is reduced, and the quality of large-area grown graphene through atomic layer deposition and growth on the silicon substrate is improved.
Owner:ZHEJIANG UNIV

Nickel-magnesium-chromium composite oxide catalyst for auto-thermal reforming of acetic acid to produce hydrogen

The invention relates to a nickel-magnesium-chromium mesoporous composite oxide catalyst for auto-thermal reforming of acetic acid to produce hydrogen. The invention aims to solve the problem that inthe prior art, during the acetic acid auto-thermal reforming process, the structure of a conventional catalyst changes, the active components are oxidized and sintered, and thus the catalyst is deactivated, and provides a novel catalyst having the advantages of stable structure, sintering resistance, carbon deposition resistance, oxidation resistance and high activity. The chemical formula of thecatalyst is (NiO)a(MgO)b(CrO1.5)c; wherein a is 0.08-0.12, b is 0.55-0.92, c is 0-0.33, and nickel oxide accounts for 12.0 to 20.0 wt.% of the catalyst, magnesium oxide accounts for 40.0 to 88.0 wt.%of the catalyst, and chromium oxide accounts for 0 to 40.0 wt.% of the catalyst. A catalyst precursor is prepared by a co-precipitation method, chromium is introduced into the catalyst and is taken asan auxiliary agent; after burning, a stable mesoporous composite oxide catalyst, which comprises a MgCr2O4 and NiCr2O4 spinel structure and a Mg-Ni-Cr-O solid solution, is formed; the reducing performance and stability of the active components are enhanced; at the same time, the hydrogen yield of acetic acid auto-thermal reforming, sintering resistant performance, and carbon deposition resistantperformance are all strengthened.
Owner:CHENGDU UNIVERSITY OF TECHNOLOGY

Preparation method of tetraene intermediates

The invention relates to a preparation method of tetraene intermediates. According to the preparation method, a first compound is converted by Nocardioides simplex to obtain tetraene intermediates; wherein the first compound is represented by a formula I, tetraene intermediates are represented by a formula II, and R in the formula I and the formula II represents H, a halogen atom, an alkyl group,an alkoxyl group, a hydroxyl group, or a phenyl group. According to the preparation method, the first compound is taken as the substrate, only Nocardioides simplex is used to carry out biological conversion; the substrate is subjected to 1,2-dehydrogenation and 21-acetate hydrolysis at the same time; most of the conversion products is target products, the byproduct ratio is low; after purification, the product is white or white-like crystals; relative to the weight of the substrate, the yield is 80-90%; the target product yield is high; through HPLC analysis, the purify of the product is not less than 95%; and the total content of target products and secondary products is not less than 99%.
Owner:HUNAN NORCHEM PHARMACEUTICAL CO LTD

Gasification slag magnesium-nickel alloy hydrogen storage composite material and preparation method thereof

ActiveCN111876640ASerious pollutionAccelerated hydrogen collectionHydrogenSlagExhaust fumes
The invention provides a preparation method of a gasification slag magnesium-nickel alloy hydrogen storage composite material. The method is characterized in that after magnesium powder, nickel powderand gasification slag are mixed, by means of a porous structure of the gasification slag, pore channels of the gasification slag are filled with the magnesium powder and the nickel powder through ball milling, ultrasonic vibration and other modes, and a mixture is uniformly mixed; and then through pressing, sintering and cooling, the gasification slag magnesium-nickel alloy hydrogen storage composite material is prepared. When the composite material is used for hydrogen storage, the porous gasification slag serving as a catalyst is distributed in a magnesium-nickel alloy matrix, so that alloyhydrogenation and hydride dehydrogenation can be promoted, alloy hydrogen collection and hydrogen desorption speed can be increased, and the activation energy of a hydrogen storage system can be reduced; and fine magnesium-nickel alloy particles are distributed in the gasification slag pore channels, so that the growth, caused by heating in a hydrogen desorption process, of the magnesium-nickel alloy particles can be effectively inhibited, and then the hydrogen storage cycle stability of the composite material is maintained. The preparation method is low in cost and wide in raw material source, has the effects of solid waste gasification slag treatment, and reclamation and higher value application of the gasification slag at the same time, and is remarkable in advantage and suitable for popularization.
Owner:YULIN UNIV

Preparation method of gallium-containing zeolite and application to coal pyrolysis volatile matter transformation

The invention discloses a preparation method of gallium-containing zeolite and an application to coal pyrolysis volatile matter transformation. A solution is prepared from water, a microporous template agent, NaOH and a mesoporous template agent, a silicon source is added dropwise, stirring is performed after addition of the silicon source, a gallium source and an aluminum source are added after the silicon source is hydrolyzed and dispersed, an obtained mixture is crystallized for 2-6 days at 100-180 DEG C after aging, ammonium nitrate ion exchange is performed after crystallization and roasting, roasting is performed again after drying, and hierarchically porous gallium-containing zeolite with an MFI skeleton is obtained. According to gallium-containing zeolite, carbon deposition inactivation of a catalyst can be reduced to a certain degree; aiming at various substances contained in coal pyrolysis volatile matter, a weak acid site formed by skeleton gallium and gallium outside the skeleton can be subjected to concerted catalysis with Si-OH-Al (a strong B acid site) in a molecular sieve, dehydrogenation, pyrolysis, oligomerization and aromatization of macromolecular alkane can bepromoted, CH4 can be activated by formed olefins under the action of Ga2O3, and methane is promoted to be converted into long-chain olefins and arenes.
Owner:NORTHWEST UNIV(CN)

Liquid chromatography-DAD-tandem mass spectrometry method for simultaneously detecting four enantiomers in cyfluthrin and application of liquid chromatography-DAD-tandem mass spectrometry method

ActiveCN113834892AMeet the requirement that no aqueous phase system can be usedPromote dehydrogenationComponent separationUltraviolet detectorsAlcohol
The invention provides a liquid chromatography-DAD-tandem mass spectrometry method for simultaneously detecting four enantiomers in cyfluthrin and application of the liquid chromatography-DAD-tandem mass spectrometry method, and the method comprises the following steps: dissolving a sample to be detected in chromatographic grade absolute ethyl alcohol to obtain a detection solution, and detecting the detection solution by adopting a liquid chromatography-DAD-tandem mass spectrometry technology, wherein the liquid chromatography adopts reversed-phase liquid chromatography, the mobile phase is a water-free alcohol solution, and the mass spectrum adopts a DAD-ultraviolet detector. According to the method, absolute ethyl alcohol is selected as the mobile phase, so that the maximum separation effect of four enantiomers can be ensured, and the requirement that a chiral chromatographic column cannot use any water phase system can be met; 0.2-0.45 v% of ammonia water is added into the mobile phase, so that the cyfluthrin is ionized, and the detection sensitivity is improved; and according to the method, a DAD-ultraviolet detector is matched, so that the mass spectrum response of the method is improved, parameters such as collision energy are optimized, and quantitative analysis of four enantiomers of the cyfluthrin is realized.
Owner:BEE RES INST CHINESE ACAD OF AGRI SCI

Dehydrogenation catalyst as well as preparation method and application thereof

The invention discloses a dehydrogenation catalyst which comprises modified aluminum oxide as a carrier, Pt as an active component and Ga-containing perovskite as aids, wherein the mass percentage content of Pt in the dehydrogenation catalyst is 0.1-0.5%, and the mass percentage of Ga is 0.4-3.1%. The invention further provides a method for preparing the dehydrogenation catalyst and the application of the dehydrogenation catalyst in alkane dehydrogenation to prepare olefin. The catalyst is simple in preparation method, and the dehydrogenation catalyst prepared by using the preparation method has high catalysis performance in alkane dehydrogenation. The dehydrogenation catalyst disclosed by the invention has the characteristics of being high in activity, good in carbon prevention and good in stability, and the preparation method is simple and easy to achieve, and has a wide application prospect.
Owner:XIAN CATALYST NEW MATERIALS CO LTD

Preparation method and application of NiCu/BDD composite electrode used for directional catalytic oxidation of ammonia nitrogen in wastewater

ActiveCN113173627AExcellent rate of direct ammonia oxidationAccelerate the rate of ammonia oxidationWater contaminantsEnergy based wastewater treatmentCatalytic oxidationNitrogen gas
The invention discloses a preparation method of a NiCu / BDD composite electrode and application of the NiCu / BDD composite electrode to directional catalytic oxidation of ammonia nitrogen in wastewater, belonging to the field of novel material wastewater treatment. According to the method, after a diamond film is deposited on a tantalum sheet through a hot wire vapor deposition method, an electrode is ultrasonically cleaned through HCl, acetone, ethyl alcohol and ultrapure water in sequence, and the electrode is dried through a drying oven; and then electrochemical deposition of a Ni and Cu bimetallic compound is conducted in an electrolyte solution containing a certain amount of NiSO4, CuSO4 and lauryl sodium sulfate (SDS), and the deposited electrode is fully cleaned with ultrapure water, and then naturally aired. The prepared NiCu / BDD composite electrode can be applied to directional catalytic oxidation of ammonia nitrogen in wastewater. By optimizing the preparation parameters of the BDD electrode and the deposition parameters of the NiCu bimetallic oxide, the synergistic denitrification effect of the BDD substrate and the NiCu bimetallic oxide catalytic material can be effectively exerted, efficient directional catalytic oxidation of ammonia nitrogen can be realized under low voltage, and excellent nitrogen selectivity and stability are shown.
Owner:ZHEJIANG UNIV

Method for dehydrogenating dihydromyricetin

The invention relates to the field of organic synthesis, in particular to a method for dehydrogenating dihydromyricetin. The method comprises the following steps: S01, pretreating an electrode; S01, modifying p-benzenesulfonic acid-modified graphene on the surface of the electrode obtained in step S1; So3, connecting a modified electrode obtained in step S2 to a negative electrode of a power supply, and connecting a positive electrode of the power supply to an inert electrode; S04, placing an electrolysis system of step S3 into a solution containing dihydromyricetin; and S05, standing the electrolyte in an icy domain for 12 to 15 hours, and filtering. The dehydrogenation reaction of the dihydromyricetin is promoted by adopting an electrochemical method. The reaction is performed under an alkaline condition, so that the dehydrogenation of the dihydromyricetin can be facilitated. In the whole dihydromyricetin process, the method has the characteristics of high conversion rate and high conversion speed.
Owner:湖南中茂生物科技有限公司

A preparation method of gallium-containing zeolite and its application in coal pyrolysis volatile modification

A preparation method of gallium-containing zeolite and its application in coal pyrolysis volatilization modification. Water, microporous template agent, NaOH and mesoporous template agent are made into a solution, and silicon source is added drop by drop, and stirred after dropping After the silicon source is hydrolyzed and dispersed, the gallium source and the aluminum source are added, and after aging, it is crystallized at 100-180°C for 2-6 days. After crystallization and roasting, ammonium nitrate ion exchange is performed, and then roasted after drying to obtain a multi-level MFI skeleton. Porous gallium-containing zeolite; the gallium-containing zeolite of the present invention can reduce the carbon deposition and deactivation of the catalyst to a certain extent; for various substances contained in coal pyrolysis volatiles, the weak acid sites formed by the framework gallium and the extra-framework gallium can be combined with molecular sieves Si‑OH‑Al (strong B acid site) can promote the dehydrogenation, cracking, oligomerization and aromatization of macroalkanes, and the formed olefins can be 2 o 3 Activation of CH under the action of 4 , to promote the conversion of methane to long-chain olefins and aromatics.
Owner:NORTHWEST UNIV

Processes for selective naphtha reforming

Processes for reforming a hydrocarbon feedstock by selectively reforming different sub-components or fractions of the feedstock using at least two compositionally-distinct reforming catalysts. Advantages may include a decreased rate of reforming catalyst deactivation and an increased yield of a liquid hydrocarbon reformate product that is characterized by at least one of an increased octane rating and a decreased vapor pressure (relative to conventional one-step reforming processes and systems).
Owner:PHILLIPS 66 CO

Mesoporous silica-supported tungsten-promoted nickel-based catalyst for autothermal reforming of acetic acid for hydrogen production

The invention relates to a mesoporous silica supported tungsten-promoted nickel-based catalyst for hydrogen production by autothermal reforming of acetic acid. Aiming at the inactivation problem of anexisting catalyst in the acetic acid autothermal reforming process, the invention provides a novel catalyst with high activity, carbon deposition resistance and oxidation resistance. The molar composition of the catalyst is (NiO)a(WO3)b(SiO2)c, wherein a ranges from 0.0764 to 0.1367, b ranges from 0 to 0.0353, b is not 0, and c ranges from 0.8281 to 0.8889. According to the invention, Ni and W species are impregnated on a SiO2 carrier by adopting an impregnation method, and the stable mesoporous composite oxide catalyst containing NiWO4 and SiO2 is formed by roasting. The catalyst provided bythe invention effectively promotes acetic acid conversion, inhibits the generation of acetone and other byproducts, and improves the yield and reaction stability of hydrogen.
Owner:成都富鼎鑫瑞科技股份有限公司
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