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Preparation method of high-gold-attribute entropy-based oxide catalyst and application thereof in hydrogen production by acidic electrolysis of water

ActiveCN119075983BBreaking the seesaw relationshipSimple technical solutionMetal/metal-oxides/metal-hydroxide catalystsElectrodesPtru catalystElectrolysed water
The application relates to a preparation method of an entropy-based oxide catalyst with high metallic property and application of the entropy-based oxide catalyst in hydrogen production by acidic electrolytic water, and belongs to the field of catalysis. A water-soluble salt containing at least Ru, Ir and A is uniformly mixed, hydrolyzed and reduced under water bath stirring condition by taking zinc oxide as a carrier and a sodium borohydride solution as a reducing agent, then the black powder of the medium-entropy alloy is formed through filtration, washing and drying, and finally the black powder is subjected to rapid incomplete oxidation under the condition of 300-500 DEG C and air atmosphere, and then is subjected to acid pickling, filtration, washing and drying to prepare the entropy-based oxide catalyst with high metallic property. The catalyst contains a large amount of Ir-Ir metal bonds and / or Ir-Ru metal bonds, and the proportion can reach 30%-40%. The mismatch between the metal atom fingerprint structure and the metal-oxygen atom coordination structure causes serious lattice distortion, induces unbalanced distribution of stress and strain, and promotes the kinetics of the acidic oxygen evolution reaction.
Owner:BEIJING UNIV OF CHEM TECH +1