The invention discloses a preparation method of a high-
metallicity entropy-based
oxide catalyst and application of the high-
metallicity entropy-based
oxide catalyst in
hydrogen production by acidic electrolyzed water, and belongs to the field of
catalysis.
Zinc oxide serves as a carrier, a
sodium borohydride solution serves as a
reducing agent, water-soluble salt at least containing Ru, Ir and A is evenly mixed under the water bath stirring condition,
hydrolysis and reduction are conducted, then medium-entropy
alloy black
powder is formed through suction
filtration, washing and
drying, finally, rapid incomplete oxidation is conducted in the
air atmosphere of 300-500 DEG C, then acid
pickling, suction
filtration, washing and
drying are conducted, and the medium-entropy
alloy black
powder is obtained. And the entropy-based oxide catalyst with high
metallicity is prepared. The catalyst contains a large number of Ir-Ir metallic bonds or / and Ir-Ru metallic bonds, and the proportion of the Ir-Ir metallic bonds or / and the Ir-Ru metallic bonds can reach 30%-40%. Serious lattice
distortion is caused by mismatching of a
metal atom
fingerprint structure and a
metal-
oxygen atom coordination structure, stress-strain imbalance distribution is induced, and acidic
oxygen evolution reaction
kinetics is promoted.