The invention discloses low-temperature sintered microwave dielectric ceramic and a sintering method thereof. The low-temperature sintered microwave dielectric ceramic comprises Li2MTi3O8 and N, wherein an M element is Zn, Ni, Co or Mg, and N is B2O3, V2O5, CuO or Bi2O3. The performance of a product prepared by adopting a microwave sintering method disclosed by the invention is superior to that of a traditional solid-phase sintered product, the high-frequency dielectric constant (epsilonr) of the product reaches 20 to 30, a Q*f value reaches up to 6000 to 59000GHz, and the temperature coefficient (tauf) of a resonance frequency is small. Moreover, the presintering time and the sintering time can be shortened, and the sintering temperature is decreased, so that the requirements of LTCC (Low Temperature Co-fired Ceramic) production can be met, the performance of the product is improved, energy sources are saved, the production cost is lowered, the low-temperature sintered microwave dielectric ceramic can be used for the manufacture of microwave devices, such as an LTCC system, a multilayer dielectric resonator, a microwave antenna, a filter and the like, the volatilization of low-melting-point substances is inhibited, the environment is protected, and the low-temperature sintered microwave dielectric ceramic has an important industrial application value.