540 results about "Sumanene" patented technology

Disclosed is a novel compound of Formula 1 and an organic electroluminescent device using the same. In Formula 1, X and Y independently represents a hydrogen, an aromatic or a hetero aromatic hydrocarbon having C5 to C10 carbons; X and Y may be the same or different; Ar1 to Ar2 each represent a hydrogen, an unsubstituted or substituted aromatic hydrocarbon having C4 to C12 carbons, or an unsubstituted or substituted condensed polycyclic aromatic hydrocarbon having C4 to C12 carbons; Ar1 to Ar2 can form a fused aromatic ring system with the adjacent aromatic hydrocarbons. The compound of Formula 1 is present in the electron injection or a transport material, or an exciton blocking layer in the organic light emitting device, and thereby improving the device stability, lowering the operational voltage.

New anionic surfactants and methods of preparation which are derived from aromatic or substituted aromatic molecules and alkenesulfonic acid. Wherein the aryl compound is alkylated and sulfonated in one-step with an alkene sulfonic acid prior to sulfonic acid neutralization. The methods allow the functional sulfonate group to be attached to the end of the alkyl chain rather than to the aromatic ring thus allowing for selective substituted groups, either branched, linear or alkoxylated or combinations thereof to be placed on the aryl compound prior to sulfonation and alkylation. The invention uses the alkene sulfonic acid produced from thin-film sulfonation of an alpha-olefin to alkylate benzene, mono-substituted aromatic, poly-substituted aromatic, alkylbenzene, alkoxylated benzene, polycyclic aromatic, mono-substituted polycyclic aromatic, poly-substituted polycyclic aromatic, naphthalene, alkylnaphthalene, phenol, alkylphenol, alkoxylated phenol, and alkoxylated alkylphenolalkyl substituted or polysubstituted cyclic or polycyclic compounds to produce the corresponding sulfonic acid having an additional alkyl group derived from the alpha-olefin used during the thin-film sulfonation which is either linear or branched.

Processes are provided for the storage and release of hydrogen by means of a substantially reversible catalytic hydrogenation of extended pi-conjugated substrates which include large polycyclic aromatic hydrocarbons, polycyclic aromatic hydrocarbons with nitrogen heteroatoms, polycyclic aromatic hydrocarbons with oxygen heteroatoms, polycyclic aromatic hydrocarbons with alkyl, alkoxy, ketone, ether or polyether substituents, pi-conjugated molecules comprising 5 membered rings, pi-conjugated molecules comprising six and five membered rings with nitrogen or oxygen hetero atoms, and extended pi-conjugated organic polymers. The hydrogen, contained in the at least partially hydrogenated form of the extended pi-conjugated system, can be facilely released for use by a catalytic dehydrogenation of the latter in the presence of a dehydrogenation catalyst which can be effected by lowering the hydrogen gas pressure, generally to pressures greater than 0.1 bar or raising the temperature to less than 250° C. or less, or by a combination of these two process parameters.

Disclosed is a ribbon of graphene less than 3 nm wide, more preferably less than 1 nm wide. In a more preferred embodiment, there are multiple ribbons of graphene each with a width of one of the following dimensions: the length of 2 phenyl rings fused together, the length of 3 phenyl rings fused together, the length of 4 phenyl rings fused together, and the length of 5 phenyl rings fused together. In another preferred embodiment the edges of the ribbons are parallel to each other. In another preferred embodiment, the ribbons have at least one arm chair edge and may have wider widths.The invention further comprises a method of making a ribbon of graphene comprising the steps of:a. placing one or more polyaromatic hydrocarbon (PAH) precursors on a substrate;b. applying UV light to the PAH until one or more intermolecular bonds are formed between adjacent PAH molecules; andc. applying heat to the PAH molecules to increase the number of intermolecular bonds that are formed to create a ribbon of graphene.The invention further comprises an electrical device structure having two or more ribbons of graphene in surface to surface contact with a non conductive substrate. Each of the ribbons has a width less than 3 nm and each of the ribbons has edges that are parallel to one another. In a preferred embodiment the ribbons comprise a channel in a Field Effect Transistor (FET).

Processes are provided for the storage and release of hydrogen by means of a substantially reversible catalytic hydrogenation of extended pi-conjugated substrates which include large polycyclic aromatic hydrocarbons, polycyclic aromatic hydrocarbons with nitrogen heteroatoms, polycyclic aromatic hydrocarbons with oxygen heteroatoms, polycyclic aromatic hydrocarbons with alkyl, alkoxy, nitrile, ketone, ether or polyether substituents, pi-conjugated molecules comprising 5 membered rings, pi-conjugated molecules comprising six and five membered rings with nitrogen or oxygen hetero atoms, and extended pi-conjugated organic polymers. The hydrogen, contained in the at least partially hydrogenated form of the extended pi-conjugated system, can be facilely released for use by a catalytic dehydrogenation of the latter in the presence of a dehydrogenation catalyst which can be effected by lowering the hydrogen gas pressure, generally to pressures greater than 0.1 bar or raising the temperature to less than 250° C. or less, or by a combination of these two process parameters.

The invention relates to a bacterial strain of Rhodococcus ruber P14 CGMCC NO.2343. The bacterial strain has the characteristic of floating up from oil matters; the bacterial strain can grow by taking the oil matters as unique carbon source and energy source and degrade the oil matters; and the bacterial strain can grow by taking polycyclic aromatic hydrocarbon as unique carbon source and energy source and degrade hydrocarbon compounds, such as phenanthrene, pyrene, benzopyrene, and the like. The bacterial strain can degrade the oil matters and hydrocarbon compounds, especially the polycyclic aromatic hydrocarbon can be applied in the biological treatment of oily waste water and the biological repair (biological remediation) of oil-contaminated soil.

Graphene and graphene-like materials may be formed by preparing a solution of a suitable polycyclic aromatic hydrocarbon (PAH) in a solvent that is immiscible with water (or other suitable underlying liquid). A suitably thin layer of the PAH solution is formed on the surface of a thin layer of water. The solvent is evaporated from the solution layer to form a film of PAH material organized in contiguous molecular discs. The organized PAH material may be further processed by careful removal or evaporation of the water layer to deposit the PAH residue on a desired surface. The PAH residue may then be heated to remove hydrogen atoms and form a carbon-enriched or wholly carbon, graphene structure.

The invention relates to a preparation method for a compound fungus agent for specifically degrading an organic matter for a biological enhancing water treatment system. The compound fungus agent is added into a biological treatment process, has high biological activity, a stable effect and low cost, is easy to adsorb on the surface of a carrier and is difficult to lose. The preparation method issimple and practical, and has a short preparation period and low cost. The compound fungus agent comprises the following four strains: 20 to 30 percent of pseudomonas-stutzeri, 20 to 30 percent of pseudomonas putida, 10 to 20 percent of pseudomonas-pertucinogena and 30 to 50 percent of bacillus subtilis. The compound fungus agent is prepared by combining and screening the strains, performing slant culture and primary culture, mixing according to the proportion, and performing secondary cycle culture. The preparation method is widely used in a biological enhancing water treatment process, has a long-term and stable operation period, and has specific degradation ability for toxic and harmful organic pollutants such as halogenated hydrocarbons, phenol, benzoic acid, aromatics, polycyclic aromatic hydrocarbon, heterocyclic compounds, phthalic acid ester and the like.

Disclosed is a chemistry-microorganism combination restoration method of polycyclic aromatic hydrocarbons and heavy metal composite contaminated site soil. The method comprises steps of (1), preparing soil particles and air drying and grinding contaminated site soil; (2), setting a restoration system, adding methyl beta cyclodextrin leacheate to a blender; (3), adjusting the reaction temperature to be 50+ / -2 DEG C; (4), adjusting an ultrasonic emission device to 35kHz for ultrasound of 30 minutes; (5) conducting continuous leaching, and repeating the continuous leaching for 3 times; and (6) conducting depth restoration of degrading bacteria, and inoculating polycyclic aromatic hydrocarbons degrading bacteria to soil which is subjected to continuous leaching restoration, adjusting the N / P to be 10:1 and conducting degradation for 90-140 days continuously. By the aid of the method, the restoration of the polycyclic aromatic hydrocarbons and heavy metal contaminated site soil generated by enterprises such as transferred coking plants, steel mills and power plants has wide application prospects.

The present invention is related to a process oil using as a raw material a deasphalted oil obtained by deasphalting a vacuum residual oil of a crude oil and a manufacturing method of the process oil, the process oil having properties of:(a) a polycyclic aromatics (PCA) content of less than 3 mass %;(b) a viscosity (100° C.) of 40 to 70 mm2 / s;(c) an aniline point of 85 to 100° C.;(d) a flash point of 250° C. or higher;(e) an aromatic hydrocarbon content of 40 to 55 mass %; and(f) a polar substance content of 10 to 15 mass %.The present invention is also related to a process oil and a manufacturing method of the process oil, the process oil obtained by mixing: an extract obtained by deasphalting and solvent-extracting a vacuum residual oil of a crude oil; and a lubricant base oil having a polycyclic aromatics (PCA) content of less than 3 mass %, and having properties of:(a) a polycyclic aromatics (PCA) content of less than 3 mass %;(i) a viscosity (100° C.) of 30 to 80 mm2 / s;(j) an aniline point of 90° C. or lower;(k) a flash point of 240° C. or higher;(l) a benzo(a)pyrene content of 1 mass ppm or less;(m) a specified aromatic compound content of 10 mass ppm or less; and(n) a polar substance content of 10 to 30 mass %.

A process for reducing content of sulphur compounds and polyaromatic hydrocarbons in a hydrocarbon feed having a boiling range between 200° C. and 600° C., which process comprises in combination contacting the feed and hydrogen over a hydrotreating catalyst and hydrotreating feed at hydrotreating conditions, cooling the hydrotreated effluent and hydrogen-rich gas from the hydrotreating reactor contacting said effluent and hydrogen gas over a hydrotreating catalyst in a post-pretreatment reactor at a temperature sufficient to lower the polyaromatic hydrocarbon content.

The invention provides a strain of Mycobacterium sp.16F for efficiently degrading polycyclic aromatic hydrocarbon and benzene organic matters, which has a preservation number of CGMCC No.6367. The mycobacterium 16F can efficiently, safely and rapidly degrade polycyclic aromatic hydrocarbons and benzene organic matters, can grow and degrade by using fluorene, naphthalene, anthracene, acenaphthene, phenanthrene, pyrene and benzopyrene as the sole carbon source and energy in aerobic condition, and can utilize benzene, m-xylene, toluene, salicylic acid, catechol and other multiple aromatic organic matters. The mycobacterium 16F is sensitive to streptomycin, rifampin, tetracycline, kanamycins and other antibiotics, has good degradation effects to mixed polycyclic aromatic hydrocarbons in aging soils and monocyclic benzene organic matters in water bodies, can be used for restoring and purifying the water-soil environment combinedly polluted by aromatic hydrocarbon organic matters, is important for promoting sustainable development, and has a wide application prospect.

The invention relates to the preparation of biferrocene aromatic salt which is used as novel cationic photo initiator and the application thereof, pertaining to the technical field of organic synthesis and cationic photo polymerization. The invention provides a biferrocene aromatic salt that is collectively named (2(cyclopentadienyl-Fe) aromatic) salt, which is used as a photo initiator in the cationic photo polymerization. In the preparation of the compound, the ferrocene and polycyclic aromatic hydrocarbon are used as the raw materials and Lewis acid is adopted as an activator, providing simple and convenient preparation. The compound still has relatively high absorbency over 300nm and can match with a long-wave ultraviolet source, thus efficiently activating the photopolymerization of epoxy compounds and vinyl ether compounds.

The invention discloses a solid phase microextraction coating of a hydroxyl cucurbituril as well as a preparation method and an application thereof, relates to an analyzing sample pre-treatment technology, and belongs to the technical field of analytical chemistry. The solid phase microextraction coating is characterized in that a common pentabasic cucurbituril or six-membered cucurbituril is subjected to potassium peroxodisulfate oxidation and cation exchange resin separation and purification so as to obtain the hydroxyl cucurbituril through, the hydroxyl cucurbituril is bonded on a sol-gel mesh through a chemical reaction so as to obtain the solid phase microextraction coating, the coating is utilized to prepare a solid phase microextraction fibre which is combined with a gas chromatography, the environmental water sample containing polycyclic aromatic hydrocarbon is analysed, and the coating is utilized to prepare a solid phase microextraction stirring rod which is combined with a high performance liquid chromatography so as to analyze non-steroid antiinflammatory drugs. The solid phase microextraction coating provided by the invention has the advantages that the superficial area of the coating is large, and the extraction capacity is large; and the solid phase microextraction coating is a novel solid phase microextraction coating, is used for analyzing, high in selectivity, low in detection limitation, wide in linearity range, and good in selectivity.

A method is provided for the removal of polychlorinated contaminants including polychlorinated dioxins, furans, byphenyls, and polycyclic aromatic hydrocarbons from marine oils by a process that minimizes processing of the oil, and the degradation of polyunsaturated fatty acids. Also provided are marine oils such as cod liver oil obtained by the method of the invention than can be used otherwise unrefined as a source of economical, contaminant-reduced bulk marine oil.

A bis-phenanthroimidazolyl compound having a following formula is disclosed. Where A1 and A2 comprise identical or different aromatic rings, A3 comprises a polyaromatic hydrocarbon or at least two aromatic groups, and each carbon in A1 to A3 and phenanthrol groups is independently substituted or non-substituted. The bis-phenanthroimidazolyl compound exhibits relatively better thermal properties with higher glass-transition temperature and efficient blue emission. The bis-phenanthroimidazolyl compound may function as a host emitter or charge-transporter. An electroluminescent device is also disclosed.

A device for treating high density organic waste water by a multiphase photocatalysis combined film bioreactor, comprises a filter, a primary photocatalyst reactor, a secondary photocatalyst reactor, an acidifying hydrolysis pool, and a film bioreactor; wherein a pipeline is communicated among the filter, the primary photocatalyst reactor, the secondary photocatalyst reactor, the acidifying hydrolysis pool, and the film bioreactor. High density organic matters, under action of ultraviolet light and a catalyst, can be rapidly degraded to be innocuous and unpoisonous small molecules such as CO2, H2O, etc. The device and the method have advantages of: (1) fast catalytic reaction speed, stay time of organic sewage in a photocatalytic reactor can be controlled in 4h; (2) non-selectivity degradation: comprising difficultly-degraded organic matters like chlorinated organic compounds and polycyclic aromatic hydrocarbons; (3) no secondary pollution: the organic matters are thoroughly differentiated and degraded to be harmless substances such as CO2, H2O, etc.; (4) wide application range: the device and the method can almost be applied on all organic sewage, such as papermaking waste water, printing waste water, pesticide waste water, etc., and (5) combination with an MBR film bioreactor technology, small system equipment investment and low operation cost.

The invention discloses a method for detecting 17 polycyclic aromatic hydrocarbons in cigarette gas. The detection method comprises the steps of gas component extraction and on-line HPLC-GC / MS detection. First, a Cambridge filter pad capturing gas components is subjected to ultrasonic extraction by using cyclohexane; an extraction liquid is filtered by using a filtration membrane and is directly fed; and polycyclic aromatic hydrocarbons are detected by using a high-performance liquid chromatography-gas chromatography / mass spectrometer which is the on-line HPLC-GC / MS, such that qualitative and quantitative analyses upon the 17 polycyclic aromatic hydrocarbons in the cigarette gas are simultaneously carried out. The method provided by the invention has the advantages of high sensitivity, high selectivity, low volatilization loss, simple operation, high repeatability, and the like. With the method, accurate quantitative analysis can be carried out upon various polycyclic aromatic hydrocarbons in the gas. The method is also suitable for qualitative and quantitative analyses of polycyclic aromatic hydrocarbons in other complex systems.

The invention relates to a fuel oil adsorption-desulfurization sorbent which contains metal ions and Y-type molecular sieves and is characterized in that grains of the Y-type molecular sieves are less than 100 nm. The fuel oil adsorption-desulfurization sorbent is prepared in such a way that alumino silica gel of NaY molecular sieves are firstly prepared by the conventional method and then are concentrated and crystallized to obtain nanometer NaY molecular sieves, and then the molecular sieves and the metal ions are processed by ion exchange. The sorbent is used for the adsorption and the desulfurization of fuel oil containing polycyclic aromatic hydrocarbon and has large adsorption-desulfurization capability.

The invention refers to the use of a device for determining PAH concentration in a solid state sample, which device comprises a) means for exposing the sample to diffuse reflectance infrared spectroscopy, b) detecting means for recording at least one spectroscopic parameter of infrared diffuse reflection of said sample, which is a signal obtained at one or more frequencies within a range of frequencies (+ / −10 cm−1) selected from the group consisting of 3000-3100 cm−1, 740, 777, 814, 842, 1430, 1510, 1600, 4055-4056, 4642-4646, 5924, and 5951-5953 cm−1, and c) computing means for performing data analysis by correlating the at least one spectroscopic parameter with variables of a trained multivariate calibration model related to PAH concentrations, thereby obtaining prediction of PAH concentrations in the sample, and a method of determining a PAH concentration by diffuse reflectance infrared spectroscopy.

The invention relates to a method for preparing liquid smoking spice for meat from pecan shells. In the method, the byproduct shells of wild pecans in China are used as the materials. The method comprises the following steps: selecting the material, pulverizing, carrying out dry distillation, filtering, fractionating, and aging at variant temperatures to obtain the stable finished product. The liquid smoking spice can be used for meat. The content of smoking characteristic flavoring substance 2,6-dimethoxyphenol is up to 8.0-18.0 (mg / mL), and the content of polycyclic aromatic hydrocarbon 3,4-benzopyrene is controlled within 2.0 mu g / kg, thereby enriching the diversity of smoking spice products and fully utilizing the pecan shells. By combining variant temperature aging with micro-filtering to remove precipitated tar, the aging time is shorted to 4 days, which is shortened by more than half as compared with the current like products, thereby greatly enhancing the production efficiency.

A bis-phenanthroimidazolyl compound having a following formula is disclosed.Where A1 and A2 comprise identical or different aromatic rings, A3 comprises a polyaromatic hydrocarbon or at least two aromatic groups, and each carbon in A1 to A3 and phenanthrol groups is independently substituted or non-substituted. The bis-phenanthroimidazolyl compound exhibits relatively better thermal properties with higher glass-transition temperature and efficient blue emission. The bis-phenanthroimidazolyl compound may function as a host emitter or charge-transporter. An electroluminescent device is also disclosed.

The invention relates to modified coal tar pitch and a preparation method thereof. The technical scheme is as follows: the preparation method comprises the steps of firstly, putting 30-40 parts by mass of coal tar pitch into a reaction kettle with a reflux device, then adding 57-67 parts by mass of a mixed solvent into the reaction kettle at 75-95 DEG C, and stirring for 10-15 minutes at a stirring speed of 100-150r / min; secondly, under the condition that the temperature and stirring speed are same, adding 1.8-3.5 parts by mass of a modifier and 0.20-0.35 part by mass of a catalyst, and stirring for 1-4 hours to obtain a modified coal tar pitch mixture; finally, performing reduced pressure distillation on the obtained modified coal tar pitch mixture at 95-110 DEG C to recycle a solvent so as to obtain the modified coal tar pitch. The modified coal tar pitch and the preparation method thereof disclosed by the invention have the characteristics of simple process, low reaction temperature, small dose of the modifier, recyclable solvent and low cost, and can effectively reduce the content of polycyclic aromatic hydrocarbon 3,4-benzopyrene in the coal tar pitch.

The invention discloses a passive sampler for polycyclic aromatic hydrocarbon in indoor air and a sampling testing method thereof and belongs to the fields of sampling and determining of the polycyclic aromatic hydrocarbon. The sampler comprises a sampling bottle and a sampling support, the sampling bottle is filled with granular CarbotrapB or XAD-4 resin which serves as an adsorbent, and the sampling support is a double-layer metal support. Sampling testing steps comprise washing adsorbent; inversely placing the sampling bottle filled with the adsorbent at the position of a circular hole of the upper layer of the sampling support for sampling; extracting the polycyclic aromatic hydrocarbon in the adsorbent; determining quality Mg, i of 15 kinds of PAHs obtained by sampling of the passive sampler through gas-mass chromatography; determining sample rate through fitted line slope fitted by Veq-t; and calculating mean concentration Cg, i of the polycyclic aromatic hydrocarbon in the indoor air. The passive sampler is simple in manufacture and assembly and low in cost, only uses accelerated solvent extraction to extract the polycyclic aromatic hydrocarbon in the adsorbent, greatly reduces use of organic solvent, shortens analysis time and is applicable to sampling of the polycyclic aromatic hydrocarbon in the indoor air.

A process for forming an aryl-aryl bond comprises the step of reacting an arene hydrocarbon compound with either (1) an organic oxidant selected from the group consisting of a quinone, a quinone imine, a quinone diimine, and a nitroarene, or (2) an oxidizing salt selected from the group consisting of a triarylaminium salt, an oxonium salt, and a nitrosium salt, or (3) a hypervalent iodine compound, each in the presence of a Brönsted or Lewis acid.

The invention provides a microorganism bacterium agent for degrading polycyclic aromatic hydrocarbon. The microorganism bacterium agent for degrading the polycyclic aromatic hydrocarbon consists of light yellow mycobacteria P6, and stenotrophomonas acidaminiphila P56. The bacterium agent has the capacity of degrading multiple kinds of polycyclic aromatic hydrocarbon of soil and sewage, an obvious effect of repairing soil polluted by the polycyclic aromatic hydrocarbon, and good application prospect; and the capacity of degrading polycyclic aromatic hydrocarbon (pyrene and fluoranthene), which are dissolved in a solution, by the microorganism bacterium agent is over 90 percent.

The invention discloses a chemistry-plant combined remediation method of fluoride-type combined pollution site soil. The chemistry-plant combined remediation method of fluoride-type combined pollution site soil comprises the following steps: firstly, crushing and screening pollution soil particles; then placing the soil particles into a soil multielement ex-situ remediation device, adding mixed eluant, and carrying out continuous ex-situ synergism elution by adopting the mode of ultrasonic intensification and warming treatment synchronously; then inoculating purslane for eluted soil, and applying a nutritious source buffer liquid equal to 30%-40% of soil mass; culturing and growing artificially, and completing the remediation. Perfluorinated compounds, polycyclic aromatic hydrocarbon and multiple types of heavy metals in site soil can be eluted efficiently and synchronously; purslane inoculation and outer source nutritional substance adding are beneficial to the deep degradation by combining with residual state polycyclic aromatic hydrocarbon after soil elution, and are also beneficial to the recovery of microorganism ecological function universality and stability of the pollution soil environment.

The invention provides an analytical method of polycyclic aromatic hydrocarbon content and application thereof. The method includes the steps of: dissolving a to-be-tested sample and an internal standard substance in n-hexane, using n-hexane to perform elution on a silica gel column to obtain saturate fraction; connecting the silica gel column to the upper end of an alumina column in series, flushing the silica gel column and the alumina column with a mixed solution of n-hexane and dichloromethane to obtain aromatic fraction 1; separating the silica gel column from the alumina column, using a mixed solution of dichloromethane and n-hexane to flush the alumina column to obtain aromatic fraction 2; then using a mixed solution of dichloromethane and anhydrous ethanol to flush the alumina column to obtain aromatic fraction 3; concentrating the aromatic fraction 3, then employing toluene to bring the substance to a constant volume, and performing GC / MS analysis, thus obtaining the polycyclic aromatic hydrocarbon content of the to-be-tested sample. The method provided by the invention can perform quantitative analysis on the polycyclic aromatic hydrocarbon contained in environment friendly rubber filling oil and raw oil thereof.

The invention provides a hydrogenation catalyst for polycyclic aromatic hydrocarbons. The hydrogenation catalyst is a molybdenum disulfide (MoS2) catalyst prepared in a microemulsion system. The molybdenum disulfide catalyst provided by the invention has the advantages of sulfur tolerance, high hydrodesulfurizing activity, high polycyclic-aromatic-hydrocarbon hydrogenation activity, simplicity in process operation, and the like.

The invention discloses a Paracoccus aminovorans LH-N40 CGMCC No.6971. The invention also discloses a heterotrophic nitrification-aerobic denitrification microbial inoculum which contains the Paracoccus aminovorans LH-N40. The invention also discloses a preparation method of the microbial inoculum. The microbial inoculum disclosed by the invention can solve the problem of difficulty in removing total nitrogen in the traditional reactor, can effectively remove ammonia nitrogen and total nitrogen in the water body in one reactor, has tolerance or degradation capability for phenols, amines, heterocycles, cyanides, polycyclic aromatic hydrocarbons and other toxic substances in wastewater, is especially applicable to nitrogenous chemical wastewater, has the advantages of simple treatment process, stable effect and environmental toxicant impact resistance, and has very wide application prospects in various actual nitrogenous chemical wastewater treatment processes.