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45results about How to "Short modification time" patented technology

Surface modification method of hollow glass beads

The invention discloses a surface modification method of hollow glass beads. The method comprises the following steps: firstly, removing surface impurities of the hollow glass beads with absolute ethanol or acetone, and then drying the hollow glass beads for 3 to 5 hours; secondly, adding the dried hollow glass beads into an agitator to be continuously heated after the agitator is preheated, and adding a coupling reagent 0.2-1.5% of the mass of the glass beads after the surface temperature of the hollow glass beads is increased to 95 to 135 DEG C; and thirdly, continuously stirring the hollow glass beads for 10-30min at 95 to 135 DEG C, and then discharging the hollow glass beads to obtain the hollow glass beads with modified surfaces. According to the method, the agitator is adopted to perform dry modification, the technology is simple, the operation is easy, the modification time is short, the cost is low, subsequent drying is not required, and the energy consumption is reduced. The hollow glass beads treated through the method can be better dispersed in epoxy resin, the binding property between the resin and fillers is improved, the material strength is improved, and the mechanical property of the composite material is obviously improved.
Owner:BENGBU HUAYANG POWDER TECH +2

Homogeneous method for preparing wood fiber derivative under room temperature

The invention discloses a homogeneous method for preparing a wood fiber derivative under room temperature. The method comprises the following steps: drying ground wood fiber powder, suspending the dried wood fiber powder in a solvent, and stirring till the wood fiber is dissolved completely to obtain wood fiber solution; dissolving an acylation reagent in the same solvent, and stirring under the room temperature till the acylation reagent is dissolved completely to obtain acylation reagent solution; adding the acylation reagent solution into the wood fiber solution, and carrying out esterification reaction under the room temperature and a moisture isolated condition; and depositing the solution obtained after the esterification reaction, collecting, washing, freezing and drying deposits, and preparing to obtain the required wood fiber derivative. The invention has the advantages that homogeneous derivatization of wood fiber is realized under the room temperature; and not only can the homogeneity and the stability of the product be improved effectively, but also equipment requirements and energy requirements can be reduced. Therefore, the invention has a significant scientific value and practical significance on the development and the utilization of renewable resources such as wood fiber, biological substances and the like.
Owner:广西南宁绿园北林木业有限公司

Method of modifying hollow glass microbeads with ionic liquid and flame-retarding thermoplastic polyurethane elastomer with the modified hollow glass microbeads as flame retardant

The invention discloses a method of modifying hollow glass microbeads with an ionic liquid and a flame-retarding thermoplastic polyurethane elastomer with the modified hollow glass microbeads as a flame retardant. The method includes the steps of: 1) treating the hollow glass microbeads with a hydrochloric acid solution; 2) after the acid treatment, repeatedly washing and drying the hollow glass microbeads; 3) activating the hollow glass microbeads, adding a silane coupling agent, and performing mechanical stirring reflux; 4) stopping the reaction and cooling the reaction product to room temperature, and performing suction filtration with acetonitrile, ethanol and deionized water and drying the reaction product; 5) adding the ionic liquid to the silanized hollow glass microbeads and performing mechanical stirring reflux; 6) stopping the reaction and cooling the reaction product to room temperature, performing suction filtration successively with ethanol, a mixed solution of ethanol and deionized water, and ethanol, and drying the reaction product. By means of the hollow glass microbeads modified with the ionic liquid as the flame retardant for preparing flame-retarding thermoplastic polyurethane (TPU) elastomer, not only is oxygen index of the composite material improved, but also the vertical combustion performance, which reflects melt-dripping resistance, is improved, so that heat release rate is reduced and smoke is significantly inhibited.
Owner:JIANGSU STERRIC CHEM IND

Preparation method of composite modified asphalt

The invention discloses a preparation method of composite modified asphalt. The preparation method comprises the steps of heating 1-3 parts by weight of polyphosphoric acid as an inorganic modifying agent to 105 DEG C and performing heat preservation, heating 2-4 parts by weight of styrene-butadiene segmented copolymer as an organic modifying agent to 65 DEG C, then adding the styrene-butadiene segmented copolymer into the heat-preserving polyphosphoric acid, heating to 120 DEG C, stirring at the speed of 120r / min until obvious styrene-butadiene segmented copolymer particles do not exist so as to prepare a composite modifying agent, heating 100 parts by weight of asphalt to 135 DEG C, then adding the prepared asphalt composite modifying agent, and stirring for 30min at the speed of 500r / min at 135 DEG C to obtain the composite modified asphalt. The composite modified asphalt prepared by the preparation method improves both high-temperature performance and low-temperature performance obviously compared with SBS (styrene butadiene styrene) modified asphalt prepared by a conventional method; the storage stability is obviously improved as well; in the preparation process, the stabilizer adding step is omitted, the heating temperature in the production process is reduced to 135 DEG C from 190 DEG C, and the production difficulty and production cost are reduced while the energy is saved.
Owner:HENAN NORMAL UNIV

A kind of modification method that iron ions promote the rapid formation of γ-feooh layer on the surface of iron filings

The invention relates to a modification method for promoting the rapid formation of a γ-FeOOH layer on the surface of iron filings by iron ions, comprising the following steps: (1) selecting scrap iron filings of low carbon steel, medium carbon steel and low alloy structural steel, and carrying out pretreatment; (2) placing the iron filings obtained in step (1) in a mixed modification liquid containing an oxidant and a promoter for modification, and the modification liquid includes the following composition by mass percentage: 0.05% to 0.45% of the oxidant , accelerator 0.025~0.5%, polyvinyl butyral resin 0~2g / L, polyethylene glycol 0~1g / L, the balance is water, the pH of the modification solution is 2~4, and the temperature is 15-40℃ (3) After the modification in step (2) is completed, continue to add oxidant to the modification system to keep its mass concentration at 0.05% to 0.45%, and continue to modify for 20 to 60 min; (4) after the modification is completed, from The product is taken out from the above modification solution, air-dried naturally, and then the residual resin on the surface is cleaned. Compared with the prior art, the method of the invention can shorten the growth time of the γ-FeOOH layer, improve the modification efficiency, and the obtained product has stable catalytic performance and surface components.
Owner:TONGJI UNIV +1

Method for modifying hollow glass microspheres by ionic liquid and flame-retardant thermoplastic polyurethane elastomer using it as flame retardant

The invention discloses a method of modifying hollow glass microbeads with an ionic liquid and a flame-retarding thermoplastic polyurethane elastomer with the modified hollow glass microbeads as a flame retardant. The method includes the steps of: 1) treating the hollow glass microbeads with a hydrochloric acid solution; 2) after the acid treatment, repeatedly washing and drying the hollow glass microbeads; 3) activating the hollow glass microbeads, adding a silane coupling agent, and performing mechanical stirring reflux; 4) stopping the reaction and cooling the reaction product to room temperature, and performing suction filtration with acetonitrile, ethanol and deionized water and drying the reaction product; 5) adding the ionic liquid to the silanized hollow glass microbeads and performing mechanical stirring reflux; 6) stopping the reaction and cooling the reaction product to room temperature, performing suction filtration successively with ethanol, a mixed solution of ethanol and deionized water, and ethanol, and drying the reaction product. By means of the hollow glass microbeads modified with the ionic liquid as the flame retardant for preparing flame-retarding thermoplastic polyurethane (TPU) elastomer, not only is oxygen index of the composite material improved, but also the vertical combustion performance, which reflects melt-dripping resistance, is improved, so that heat release rate is reduced and smoke is significantly inhibited.
Owner:JIANGSU STERRIC CHEM IND

A special heavy calcium carbonate modification method and device for wire and cable

The invention relates to a modification method for heavy calcium carbonate special for wires and cables. The modification method is characterized by including the following steps that heavy calcium carbonate is added into a grinding device and ground into fine powder with the average particle size being 1500-2000 meshes; water, stearic acid, an aluminate coupling agent and polyester type hyperdispersant are added into the powder through four feeding pipes respectively and are stirred to form a mixture, wherein the water, stearic acid, the aluminate coupling agent and the polyester type hyperdispersant account for 0.4-0.5%, 0.9-1.1%, 1-1.2% and 0.5-0.8% of the total weight of the mixture respectively. The modification method has the advantages that the time for modifying heavy calcium carbonate is shorter due to the function from inside to outside, modification is more sufficient, modified heavy calcium carbonate has heat resistance and dispersity, and can be compatible with a resin organic carrier and a high polymer material, so that toughness, brightness, plastic thermal hysteresis performance and bending strength of wires and cables are improved, and light resistance and ageing resistance are enhanced.
Owner:HUNAN LEIXIN NEW MATERIAL TECH

Modifying method of quick lime for sintering

The invention relates to a modifying method of quick lime for sintering. The modifying method comprises the following steps of (1) crushing quick lime which is not treated; (2) adding water to the quick lime which is crushed in the step (1), performing sufficient stirring, and then performing standing for 30-40min; (3) adding sodium hydroxide solid to a solution prepared in the step (2), and performing uniform stirring; (4) heating the solution prepared in the step (3) to 60-70 DEG C, and continuing performing stirring; (5) mixing sodium sulfide with water in the mass ratio of the sodium sulfide to the water being 1 to 100 so as to obtain a sodium sulfide aqueous solution; (6) uniformly adding the sodium sulfide aqueous solution which is prepared in the step (5) to the solution prepared inthe step (4); (7) charging carbon dioxide to the solution prepared in the step (6), after the solution become turbid, continuing charging the carbon dioxide until a clarifying layer appears at the upper layer of the solution; and (8) filtering the solution prepared in the step (7). According to steel products prepared from the modified quick lime, the mechanical property is obviously improved, the life is prolonged, and the steel products are excellent in quality and high in stability.
Owner:SHANDONG TAISHAN STEEL GROUP
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