The invention belongs to the technical field of
catalysis and particularly relates to a preparation method of nano
platinum oxide powder. The preparation method comprises the following steps: step one, adding
platinum chloride into
distilled water and stirring until
platinum chloride is completely dissolved; then slowly dropwise adding an alkali solution until no precipitate is produced, filteringand washing to obtain platinic
hydroxide precipitate; step two, adding the platinic
hydroxide precipitate into absolute ethyl
alcohol for stirring and uniformly dispersing; then adding
crown ether and stirring until
crown ether is completely dissolved to obtain mixed
ethanol liquid; step three, carrying out thermostatic standing on the mixed
ethanol liquid for 2 to 5 hours, carrying out gradientdepressurization, standing for 4 to 8 hours and filtering to obtain
crystal; step four, putting the
crystal into a ball-milling device and carrying out constant temperature ball-milling reaction for 1to 2 hours to obtain
crystal fine powder; step five, adding the crystal
fine powder into
electrolyte, carrying out electrolytic reaction for 2 to 4 hours and filtering to obtain precipitate; step six, putting the precipitate into absolute ethyl
alcohol, carrying out ultrasonic washing for 30 to 40 minutes, filtering and
drying to obtain the nano
platinum oxide powder. According to the preparationmethod disclosed by the invention, a double
passivation mode is utilized, so that the nano-structure of
platinum oxide is ensured; in addition, the agglomeration is avoided.