The invention discloses a method for preparing a
benzaldehyde catalyst prepared from heteropolyacid type
benzyl alcohol.
Nickel nitrate, a COF-1 nanometer material,
citric acid,
phosphotungstic acid,dioxane,
mesitylene, glacial
acetic acid, 2,4,6-tri(4-aminophenyl)-1,3-5
triazine and 2,5-dimethoxy-terephthalaldehyde are taken as main raw materials; the
benzaldehyde catalyst prepared from heteropolyacid type
benzyl alcohol (NH4)0.5H2.5PW12O40-NiO / COF-1 is prepared by adopting layered loading of
nickel nitrate and
phosphotungstic acid, nanometer heteropolyacid is sufficiently and uniformly laoded on a COF-1 porous carrier, the loading capacity is improved, nanometer active sites are prepared by adopting a
liquid phase reduction method, immediate reaction and immediate loading are realized,the activity of nanometer particles is maintained, and an aggregation effect is avoided; and the catalyst prepared in the invention integrally has relatively
high activity, selectivity and
carbon deposit resistance, the stability of the catalyst is improved, the service life of the catalyst can be prolonged, the comprehensive reaction performance of the
reaction system is improved, and the catalyst has higher product yield.