The invention discloses an
aluminum phosphate molecular sieve with a ZON structure as well as a synthesis method and application of the
aluminum phosphate molecular sieve. The synthesis method of the ZON structure
aluminum phosphate molecular sieve comprises the following steps: S1, mixing an aluminum source, water, a
phosphorus source, a main template agent TMA < + >, a
seed crystal and a co-template agent co-SDA to obtain initial gel; tMA < + > is tetramethyl
ammonium, and co-SDA is an organic amine
reagent different from TMA < + >; and S2, crystallizing the initial gel in the step S1 under a closed condition to obtain the aluminum
phosphate UiO-7 molecular
sieve raw
powder with the ZON structure. The UiO-7 molecular
sieve synthesized by the method is high in
crystallinity, and the yield reaches 70% or above. The molecular
sieve can be used for adsorbing heat storage materials,
heat pump materials,
refrigeration materials or gas
adsorption separation, and the effect is good; the method is simple and convenient to operate,
fluoride-free, low in cost, commercially available in raw materials and suitable for industrial production.