The invention discloses a composite nanometer phosphotungstic acid-titanium dioxide photocatalysis material and a preparation method thereof. The method includes the steps: firstly, titanium dioxide cThe invention discloses a composite nanometer phosphotungstic acid-titanium dioxide photocatalysis material and a preparation method thereof. The method includes the steps: firstly, titanium dioxide cstill be maintained.an still be maintained.ght; and further more, after the subsequent step of heating photocatalysis materials is accomplished, the keggin structure of the phosphotungstic acid is not affected, and high catalytic activity can ght; and further more, after the subsequent step of heating photocatalysis materials is accomplished, the keggin structure of the phosphotungstic acid is not affected, and high catalytic activity c liollosol, phosphotungstic acid and propylene glycol methyl ether, of which the mass ratio is 20 to 3 to 50, are uniformly mixed to form composite collosol; secondly, the composite collosol is heated foollosol, phosphotungstic acid and propylene glycol methyl ether, of which the mass ratio is 20 to 3 to 50, are uniformly mixed to form composite collosol; secondly, the composite collosol is heated for 30 minutes at the temperature of 300 DEG C to form dried gel; and finally, the dried gel is mechanically processed for two hours by ball milling so as to obtain phosphotungstic acid-titanium dioxider 30 minutes at the temperature of 300 DEG C to form dried gel; and finally, the dried gel is mechanically processed for two hours by ball milling so as to obtain phosphotungstic acid-titanium dioxidephotorecombination photocatalyst materials. Compared with the prior art, the phosphotungstic acids of the invention are combined into a stable netty structure in the form of W-O-P molecular linkages, photorecombination photocatalyst materials. Compared with the prior art, the phosphotungstic acids of the invention are combined into a stable netty structure in the form of W-O-P molecular linkages, thereby reducing the oxidation-reduction potential, enabling a titanium dioxide composite membrane photoabsorption wavelength to generate redshift, and improving the utility ratio of titanium visiblethereby reducing the oxidation-reduction potential, enabling a titanium dioxide composite membrane photoabsorption wavelength to generate redshift, and improving the utility ratio of titanium visibleli