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121results about How to "High Vickers hardness" patented technology

Preparation method of silicon nitride-based self-lubricating ceramic cutter material containing alumina-coated hexagonal boron nitride composite powder

The invention relates to a preparation method of a silicon nitride-based self-lubricating ceramic cutter material containing alumina-coated hexagonal boron nitride composite powder. The silicon nitride-based self-lubricating ceramic cutter material comprises, by volume, 57-70% of micrometer silicon nitride, 5-15% of nanometer silicon nitride, 5-15% of micrometer titanium carbide, 3.2% of alumina, 4.8% of yttrium oxide, and 2-15% of alumina-coated hexagonal boron nitride. The preparation method comprises preparing alumina-coated hexagonal boron nitride composite powder with particle sizes of 4-12 micrometers, weighing micrometer silicon nitride, nanometer silicon nitride and micrometer titanium carbide, respectively preparing their suspension liquids, carrying out ultrasonic dispersion, carrying out mixing, adding alumina and yttrium oxide into the mixture, carrying out ultrasonic dispersion for 15-20min to obtain a composite suspension liquid, carrying out ball milling, adding the alumina-coated hexagonal boron nitride composite powder into the composite suspension liquid, carrying out ball milling, carrying out vacuum drying to obtain mixed powder and carrying out vacuum hot pressing sintering molding. The silicon nitride-based self-lubricating ceramic cutter material containing alumina-coated hexagonal boron nitride composite powder can improve ceramic cutter mechanical properties and guarantee self-lubricating performances.
Owner:QILU UNIV OF TECH

Iron-base amorphous alloy, powder material of alloy and wear-resisting anticorrosion coating of alloy

The invention provides an iron-base amorphous alloy. The chemical formula of the iron-base amorphous alloy is FeaCrbNicModPeCfBgSih, wherein a, b, c, d, e, f, g and h are molar contents of corresponding atoms, b is larger than or equal to 5 and smaller than or equal to 15, c is larger than or equal to 2 and smaller than or equal to 15, d is larger than or equal to 2 and smaller than or equal to 8, e is larger than or equal to 6 and smaller than or equal to 12, f is larger than or equal to 2 and smaller than or equal to 6, g is larger than or equal to 3 and smaller than or equal to 6, h is larger than or equal to 1 and smaller than or equal to 5, and the balance is iron. According to the chemical formula, compounding and smelting are carried out to obtain an ingot casting; then, resmelting is carried out, and through vacuum spraying and cooling, a powder material of the iron-base amorphous alloy is obtained. By means of the supersonic speed flame spraying technology, the iron-base amorphous alloy powder is sprayed to the surface of a base body to prepare an iron-base amorphous alloy coating. The coating is high in amorphous content, low in porosity and oxygen content and high in diamond pyramid hardness and has the good wear-resisting anticorrosion performance and has the wide application prospect in fields of energy, chemical engineering, national defense, aerospace, ships and the like.
Owner:NINGBO INNOVATION CENT FOR APPLIED MAGNETICS CO LTD

Beryllium-free nickel-free high-ductility zirconium-base block body amorphous alloy and preparation method thereof

ActiveCN106756647AGood biocompatibilityWide temperature range of subcooled liquid phase regionBiocompatibility TestingNickel free
The invention provides a beryllium-free nickel-free high-ductility zirconium-base block body amorphous alloy and a preparation method thereof. The alloy comprises, by atom, 38-50% of Zr, 2-15% of Hf, 20-30% of Cu, 5-10% of Fe, 10-15% of Al, 0-5% of Co, 0-5% of Ag and 0-5% of Nb. The electric arc melting copper mould casting method is adopted for preparation. The amorphous alloy is free of metal elements such as Be and Ni, and biocompatibility of the zirconium-base alloy is improved. The high amorphous forming capacity is achieved, and the zirconium-base block body amorphous alloy with the critical size being no less than 5 mm can be prepared through the copper mould casting method. According to the beryllium-free nickel-free high-ductility zirconium-base block body amorphous alloy, high hardness is achieved, and vickers hardness is larger than 540 Hv; the plastic deformation capacity being larger than 3% is achieved; and the super-cooled liquid phase region range is wide and reaches 92 K at most. The beryllium-free nickel-free high-ductility zirconium-base block body amorphous alloy and the preparation method thereof has very wide application prospects in the fields of biomedical materials such as a precise complex medical component, a joint prosthesis and a human skeleton.
Owner:UNIV OF SCI & TECH BEIJING

Quartz crucible for single crystal growth and preparation method of quartz crucible for single crystal growth

InactiveCN104389014AImprove interface connection performanceHigh strengthBy pulling from meltSilicon dioxideSingle crystal growth
The invention discloses a quartz crucible for single crystal growth. The quartz crucible comprises an inner layer and an outer layer, wherein the inner layer is prepared from silicon dioxide particles being 0.5mm-2mm, nano silicon dioxide being smaller than 100nm, the outer layer is prepared from silicon dioxide particles being 0.5mm-2mm, nano silicon dioxide being smaller than 100nm, a stable-phase substance and silicon nitride in proportion; the stable-phase substance is any one of titanium oxide, zirconium oxide, aluminum oxide, titanium nitride, aluminum nitride and zirconium nitride. According to the quartz crucible for single crystal growth and the preparation method of the quartz crucible for single crystal growth disclosed by the invention, the quartz crucible production is divided into inner layer production and outer layer production, wherein the inner layer is made from synthesized quartz, and the particle sizes of the quartz particles including large particles and small particles are controlled; in the outer layer, the quartz strength is controlled by adding a reinforcing phase which is natural silica sand silicon dioxide, and a stable phase. According to a preparation method of the quartz crucible, physical properties such as high strength, good durability and high outer-layer viscosity of the quartz crucible can be provided, and cracking and silicon leakage of the quartz crucible due to high-temperature heating can be prevented.
Owner:JIANGSU UNIV OF SCI & TECH

N-containing Be-free Ni-free high-hardness Zr matrix body amorphous alloy and preparation method thereof

The invention relates to an N-containing Be-free Ni-free high-hardness Zr matrix body amorphous alloy. The expression of the alloy in atomic percentage is Zr Cu A <c> B <d> X <e>Z <f> N<g>, wherein A is one of Hf and Ti; B is a IIIA group element; X is one or more elements of VIII group elements or rare-earth elements except Ni; Z is one or more elements of IB group elements and VB group elements; a+b+c+d+e+f+g=100%, a is greater than or equal to 25 %, and is lower than or equal to 65 %; b is greater than or equal to 15 %, and is lower than or equal to 65 %; c is greater than or equal to 5 %, and is lower than or equal to 15 %; d is greater than or equal to 0, and is lower than or equal to 15 %; e is greater than or equal to 0, and is lower than or equal to 15 %; f is greater than or equal to 0, and is lower than or equal to 10 %; and g is greater than or equal to 0.05 %, and is lower than or equal to 0.5 %. The N-containing Be-free Ni-free high-hardness Zr matrix body amorphous alloy disclosed by the invention does not contain a metallic element Be and a metallic element Ni, so that the biocompatibility of a Zr -base alloy is improved; the N-containing Be-free Ni-free high-hardness Zr matrix body amorphous alloy has high glass forming ability, and the Zr matrix body amorphous alloy of which the critical dimension is not less than 2mm can be prepared through adopting a copper mold suction casting method; and compared with a N-free amorphous alloy, the N-containing Be-free Ni-free high-hardness Zr matrix body amorphous alloy has the advantage that the vickers hardness of an alloy system is not less than 540Hv.
Owner:UNIV OF SCI & TECH BEIJING

Nano twin-crystal nickel with extremely small twin-crystal lamella thickness and ultrahigh strength and preparation thereof

The invention relates to a superhard nanocrystal metal material, in particular to nano twin-crystal nickel with extremely small twin-crystal lamella thickness and ultrahigh strength and a preparationmethod thereof. The nano twin-crystal nickel with a thickness of hundreds of microns to millimeters is prepared by utilizing an electrolytic deposition technology, wherein a microstructure of the nanotwin-crystal nickel is composed of columnar crystal particles with lengths of 200-3000 nm and widths of about 10-50 nm, twin-crystal lamella structures with high density and consistent orientation are contained in columnar crystals, a thickness of each twin-crystal lamella structure is 0.5-10 nm, the crystal particles with the twin-crystal structures can account for 100% of the crystal particlesof a whole sample, a room-temperature microhardness of a material can reach 8.5 GPa or above and is 1.5-2 times or above that of common electroplating nano nickel, and after annealing is carried out at 250 DEG C for half an hour, the hardness is increased to 9.6 GPa and a structure roughening temperature can reach 350 DEG C or above and is 150 DEG C or above higher than a structure roughening temperature of common nanocrystal nickel. A prepared nanocrystal coating can be applied to wear-resistant protection of metal materials such as copper, nickel, alloys of the copper and nickel, and stainless steel, and can also be applied to the fields of micromechanical systems (MEMS) and the like.
Owner:INST OF METAL RESEARCH - CHINESE ACAD OF SCI

Gel casing preparation method of reaction-sintered boron carbide ceramic composite material

A gel casing preparation method of reaction-sintered boron carbide ceramic composite material includes the steps of firstly, mixing resorcinol, formaldehyde and sodium carbonate with deionized water, and adding B4C powder to form B4C mixed slurry; secondly, performing vacuum degassing and injection molding sealing on the mixed slurry; performing sol gelation in water bath, and aging for 4-50 hours; drying under normal pressure, and performing high-temperature carbonization to obtain a B4C/C biscuit; thirdly, placing silicon on the B4C/C biscuit, performing high-temperature infiltration to obtain a sintered body, and cooling to remove redundant silicone to obtain the reaction-sintered boron carbide ceramic composite material. The method has the advantages that the mesoporous carbon is introduced during the formation of the biscuit, and the B4C/C biscuit with an even structure and a controllable hole structure is obtained; the strength of the B4C/C biscuit is 10-50MPa, machining is facilitated, and the B4C/C biscuit can be used for preparing products of complex shapes; the Vickers hardness of the reaction-sintered boron carbide ceramic composite material is 17-26GPa, the bending strength of the reaction-sintered boron carbide ceramic composite material is 255-484MPa, and the fracture toughness of the reaction-sintered boron carbide ceramic composite material is 3-5MPa.m<1/2>.
Owner:NORTHEASTERN UNIV

Method for preparing diamond film on stainless steel surface with Cr/CrAlN as transition layer

The invention discloses a method for preparing a diamond film on a stainless steel surface with Cr/CrAlN as a transition layer. The method is characterized by comprising the following steps of S1, pretreatment of a stainless steel sample, wherein the stainless steel sample is polished with abrasive paper, ultrasonically treated with acetone and absolute ethyl alcohol, and then dried for later use;S2, deposition of the Cr/CrAlN layer on the stainless steel surface, wherein the stainless steel sample treated in step S1 is placed on a sample table of a magnetron sputtering device, Cr and Al target materials are mounted on a target base, and a Cr film and a CrAlN film are deposited on the surface of a stainless steel substrate, so that the stainless steel sample comprising the Cr/CrAlN transition layer is obtained; and S3, preparation of the diamond film on the stainless steel surface, wherein the stainless steel sample, comprising the Cr/CrAlN transition layer, obtained in step S2 is ultrasonically crystallized, and the diamond film is deposited by means of a heating wire through HFCVD, so that the diamond film is prepared on the stainless steel surface with Cr/CrAlN as the transition layer. By the adoption of the technique, the bonding force between the diamond film and stainless steel is high, and the film does not fall under a load with the Rockwell hardness of 150K.
Owner:ZHEJIANG UNIV OF TECH

Micro-nano polycrystalline diamond composite material and preparation method thereof

The invention discloses a micro-nano polycrystalline diamond composite material and a preparation method thereof. The micro-nano polycrystalline diamond composite material comprises the following components: carbon nano onions and micron diamond, wherein the mass percent of the micron diamond is 20-50wt.%, and the balance is the carbon nano onions; and the Vickers hardness of the micro-nano polycrystalline diamond composite material ranges from 30 GPa to 200 GPa. The preparation method comprises the following steps: carrying out annealing treatment on detonation nano diamond powder to preparecarbon nano onions; adding micron diamond crystal grains for mixing, wherein the mass percent of the micron diamond is 20-50wt.%; a mixture formed by the micron diamond and the carbon nano onions is filled into a WC hard alloy die to be pre-pressed, the pre-pressing pressure is 400-600 MPa, and pre-pressing is conducted for 10-30 s; and a pre-pressed sample is put into a mold for high-temperatureand high-pressure sintering, and the micro-nano polycrystalline diamond composite material is prepared. The Vickers hardness of the micro-nano polycrystalline diamond is nearly one time higher than the Vickers hardness of a common PCD, and the performance of the micro-nano polycrystalline diamond is obviously improved.
Owner:YANSHAN UNIV
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