The invention relates to
oxide high-entropy
ceramic with a defective
fluorite structure and a preparation method of an anti-
ablation coating of the
oxide high-entropy
ceramic. The preparation method comprises the following steps of: firstly, preparing high-entropy
ceramic powder by adopting a high-temperature
solid-
phase reaction method; and then, by using a supersonic
plasma spraying technology, preparing a high-entropy
ceramic coating with corresponding components on the surface of a base material by using the high-entropy ceramic
powder having been subjected to
spray drying treatment. The high-entropy
ceramic coating (HfZr(3RE))O2-
delta (wherein RE is selected from Sm, Er, Ce, Y, Yb) provided by the invention has excellent
phase stability and
ablation resistance. In a supersonic
plasma spraying process, the high-entropy ceramic is free of
phase change and phase
decomposition, and the prepared high-entropy
ceramic coating still keeps the phase structure of the original high-entropy ceramic
powder. The high-entropy ceramic
coating is ablated and examined in oxyacetylene flames with
heat flux density of 2.38 MW / m<2>, the highest temperature of the surface of the
coating in the ablating process reaches 1900-2100 DEG C, the ablated coating does not have the phenomena of stripping, peeling and the like, an ablating rate is low, and excellent anti-ablating performance is shown.