The application provides a high-
alkalinity wastewater pH self-adaptive type
polyaluminum chloride modification preparation process and belongs to the technical field of
water treatment agents. Through a step-by-step in-situ
polymerization process, a basic
polyaluminum chloride solution is prepared from
hydrochloric acid, aluminum
hydroxide and
calcium aluminate, then an organic modifier containing a carboxyl-phosphonic
acid group, a composite pH buffer component and modified nano
magnesium-aluminum
hydrotalcite are introduced in sequence, and a pH self-adaptive type modified
polyaluminum chloride is obtained through
polymerization control. The modified polyaluminum
chloride prepared by the application has a salt basicity of 75-90%, and the pH application range is widened to 4-12. The modified polyaluminum
chloride can still stably play a coagulation role in high-
alkalinity wastewater with pH=10-12 without additional adjustment of the
wastewater pH. The removal rate of heavy
metal ions such as lead,
cadmium and
hexavalent chromium is increased by more than 40%, and the
alum flower
sedimentation speed is increased by more than 35%. The treatment cost and secondary
pollution of high-
alkalinity wastewater are significantly reduced, and the application is suitable for the treatment of high-alkalinity industrial wastewater such as printing and
dyeing,
electroplating and
chemical industry.