214results about How to "Improve flocculation ability" patented technology

The invention discloses a method of preparing high-purity vanadium pentoxide from roasting-method vanadium solution. The method comprises the following steps: adding a purifying agent into the roasting-method vanadium solution, wherein the purifying agent is polyaluminium chloride, magnesium chloride or calcium chloride, or the purifying agent is polyaluminium chloride and magnesium chloride, or polyaluminium chloride and calcium chloride; uniformly stirring the roasting-method vanadium solution containing the purifying agent, standing for settling, then filtering, and adding ammonium salt into the filtrate to precipitate vanadium; and finally, calcining meta-ammonium and deaminizing to prepare vanadium pentoxide with the purity being higher than 99.5%. Polyaluminium chloride serving as the purifying agent can be used for polymerizing jellies with several molecules into large particles with several tens of thousands of molecules, even hundreds of thousands of molecules. The large-particle molecular polymer is easy to settle in the vanadium solution and can be separated from the solution. The method provided by the invention has the advantages that the consumption of polyaluminium chloride is low, the flocculation process is simple, the flocculation capacity is strong, the flocculation speed is high, pollution is hardly caused and the cost is low.

A process for flocculating and dewatering oil sands fine tailings is provided, comprising: adding the oil sands fine tailings as an aqueous slurry to a stirred tank reactor; adding an effective amount of a polymeric flocculant to the stirred tank reactor containing the oil sands fine tailings and operating the reactor at an impeller tip speed for a period of time that is sufficient to form a gel-like structure; subjecting the gel-like structure to shear conditions in the stirred tank reactor for a period of time sufficient to break down the gel-like structure to form flocs and release water; and removing the flocculated oil sands fine tailings from the stirred tank reactor when the maximum yield stress of the flocculated oil sands fine tailings begins to decline but before the capillary suction time of the flocculated oil sands fine tailings begins to substantially increase from its lowest point.

The invention discloses a composite reagent for deep removal of heavy metals in wastewater and a preparation method thereof. The composite reagent is prepared from the following raw materials in parts by weight: a component A including 20-30 parts of modified attapulgite powder, 30-50 parts of a modified natural high molecular polymer and 0-3 parts of a surfactant; a component B namely an inorganic flocculating agent, wherein the weight ratio of the component A to the component B is (2.5-8.3):1. The composite reagent disclosed by the invention has very strong adsorption, chelating and flocculation performances on heavy metal ions in water, has a plurality of effects of auxiliary reduction of COD (chemical oxygen demand), decoloration, dephosphorization and the like at the same time, and is good in treatment effect, and the preparation method is simple and easy.

The invention belongs to the technical field of a gelling agent for geologic hazard control as well as filling control of goaf and waste laneway or collapse craters after exploitation of other mines, and provides a formula and a method of a novel polymer composite gelling agent for grouting. The gelling agent comprises the following components in percentage by weight: 10-25% of bentonite, 5-20% of cellulose, 5-20% of vegetable gum, 10-15% of calcium hydroxide, 10-25% of inorganic hygroscopic agent, 0.5-1.5% of inorganic dispersant, 0.5-2% of inorganic flocculent, 6-18% of organic flocculent, and 5-15% of alkali metal carbonate. The gelling agent is used for processing and crushing, mixing with water, and injecting to slurry for gelling. According to the invention, the characteristics of high-hydroscopicity mineral matters and hydroscopic synthetic resin are sufficiently absorbed and utilized, and various ion groups are introduced and adjusted to obtain specific performance, so that the gelling agent has strong water solubility, can form hydrophile and water-insoluble gel in the slurry, and has excellent adhesion force to solids and dissolved matters in the slurry, good gelling property, strong water control function, high and adjustable jelling speed, low cost and no pollution.

The invention relates to a magnetic flocculant and a preparation method thereof, wherein the magnetic flocculant is cationic polyacrylamide-modified magnetic nanometer Fe3O4 particles. The magnetic flocculant provided by the invention retains the advantages of low dosage of organic high molecular flocculant, high flocculation speed, coexistence of salts, low pH value and temperature influence, low total amount of flocculating constituent and the like; and the superparamagnetism of the flocculant enables the flocculant to quicken the precipitation under the effect of an applied magnetic field and to realize quick and efficient separation of residual flocculant and flocculation. The magnetic flocculant provided by the invention has the advantages of simple preparation technique, low cost, easiness in amplification and no secondary pollution, and facilitates realizing efficient and economic flocculation operation.

The invention relates to a water purifying agent, in particular to a water purifying agent for purifying an aquaculture water environment. The water purifying agent comprises the following components in parts by mass: 12 to 15 parts of poly dimethyl diallyl ammonium chloride, 25 to 40 parts of a microbial flocculant, 5 to 8 parts of an aquaculture oxygen supply agent, 9 to 12 parts of a biological enzyme and 7 to 10 parts of cellulose. After the formula is adopted, the microbial flocculant has the characteristics of biodegradability, safety, high efficiency, no toxicity and no secondary pollution, and overcomes the defects of inorganic polymer and synthetic organic polymer flocculants, and finally non-pollution discharge is realized. The poly dimethyl diallyl ammonium chloride is used as the organic water purifying agent and has the characteristics of small use amount, strong flocculation capacity, high efficiency and the like. The oxygen supply agent can rapidly and effectively increase dissolved oxygen in water, improves water quality, adsorbs and degrades organisms in the water and also can effectively sterilize the water.

The invention discloses composite microbial inoculum for improving the settling performance of activated sludge, which consists of Aspergillussojae CGMCC3.661, Rhodococcuserythropolis ACCC02579 and Pseudomonasaeruginosa CGMCCNo.1.239. The composite microbial inoculum has the advantages that the flocculating capability is high, no public hazard exists, a good synergistic effect with original microbes of activated sludge can be generated, the settling performance of the activated sludge is improved, the activated sludge expansion is effectively prevented, and the secondary settling pool treatment efficiency is improved. In addition, the culture medium designed in the composite microbial inoculum has low price and meets the industrial high-intensity fermentation requirement of the composite microbial inoculum, the designed fermentation process control condition reaches the high-intensity production requirement of the composite microbial inoculum (the dry weight of thalli in fermentation liquid reaches 30 g.L<-1> or higher after the fermentation is completed), the investment saving of production factors such as equipment and the like is realized, and the basis is laid for the scale production and the application of the composite microbial inoculum.

The invention discloses water-soluble polyurethane dispersoid slurry and a method for preparing a wet method base thereof. Water-soluble polyurethane dispersoid in the slurry is negative non-ionic type polyurethane dispersoid prepared by an acetone method; after foaming, the water-soluble polyurethane dispersoid slurry is smeared on a base cloth, and then a flocculation and solidification process is conducted; the flocculation ability of the water-soluble polyurethane dispersoid slurry is good in flocculation liquid; and the water-soluble polyurethane base which is dense in surface and good in handfeel is obtained. The preparation method for the water-soluble wet method base is similar to a preparation method of a solvent type wet method base, except that DMF in the flocculation liquid is replaced with water, and the preparation method is an ecological leather synthetic method. The production process is environmentally friendly and free of pollution, continuous production is achieved, operation is easy, the preparation method is efficient, and meanwhile, the obtained water-soluble wet method base is comparable to the solvent wet method base in leather texture and can replace an oiliness wet method base.

The invention relates to the field of water-soluble polymer auxiliary chemicals, in particular to a method for preparing net-shaped cationic polyacrylamide, wherein raw materials are selected from the followings: 200-270 parts of nonionic monomer, 80-170 parts of cationic monomer, 0.006-0.01 part of structure modifier, 600-700 parts of deionized water, 0.08-0.12 part of initiator in parts by weight. The preparation method comprises the steps of: preparing a mixed solution of the nonionic monomer, the cationic monomer and the deionized water, adding the structure modifier into the solution, introducing nitrogen into the solution to remove oxygen, adjusting the pH value to 4- 5, and adding the initiator into the solution to perform polymerization at the temperature of 2-5 DEG C; after the reaction, granulating the polymer, drying the colloidal particles at the temperature of 70-80 DEG C and finally crushing to obtain a product with a net-shaped structure. The product is stronger in the absorption and capture capabilities for colloid and suspended particles in the water, better flocculation effect can be achieved with fewer amount of the product, in addition, flocculation blocks are firm, the shear resistance performance is stronger, and the influence of large shearing force of a centrifugal machine on the flocculation effect is smaller.

The invention discloses a polyacrylamide composite modified macromolecule poly silicon iron flocculant, which comprises polysilicon ferric sulfate and non-ionic polyacrylamide. The mass ratio between the polysilicon ferric sulfate and the non-ionic polyacrylamide is 21-2120:1. The method for preparing the flocculant comprises the following steps: (i) dissolving sodium silicate in distilled water and blending to obtain sodium silicate solution, and adjusting the pH value of the sodium silicate solution so as to obtain polysilicic acid solution; (ii) dissolving ferric sulfate in distilled water and blending to obtain ferric sulfate solution, mixing the ferric sulfate solution and the polysilicic acid solution, adding alkaline liquor and aging to obtain polyferric silicate sulfate; and (iii) mixing the polyferric silicate sulfate and nonionic polyacrylamide according to the mass ratio, stirring and aging. The flocculant provided by the invention is not only good in storage stability but also high in flocculating activity and high in COD removal rate when being used for pharmacy waste water treatment, and can be widely used for the treatment of waste water produced by large-scale pharmaceutical enterprises.

The invention relates to a mineral composite sewage treatment method. calcium based, sodium based or acidic bentonite is crushed into 101 to 600 mesh, other minerals are crushed into 60 to 600 mesh, the bentonite and other kinds of minerals form a mineral composite, the mineral composite is poured into sewage to be treated, and is blended, then 24% octadecyl trimethyl ammonium chloride is poured into the sewage and stirred, then a flocculating agent is poured into the sewage and stirred for subsiding, and then soil and water separation and micro-organism treatment are performed , and satisfying drainage standard can be reached; the weight ratio of the sewage and the added mineral composite is (1000:0.2)-(1000:2.5), the ratio of the dosage of the bentonite and the dosage of any another mineral is (1:1)-( 4:1), the dosage ratio of the mineral composite and the octadecyl trimethyl ammonium chloride is (2:1)-(17:1), and the dosage ratio of the mineral composite and the flocculating agent is (0.5:1)-(4:1). The method can be used for the treatment of toilets, printing and dyeing, coking, agricultural chemicals and galvanization sewage, and has the advantages of low treatment cost, wide application range and smaller sludge deposit, and has no influence on the subsequent microorganism treatment.

The invention provides a method for treating degradation-resistant organic pollutants in waste water and overcomes the defect that iron nanoparticles are prone to agglomeration when the iron nanoparticles are subjected to waste water treatment in the prior art. In order to solve the technical problem, the technical scheme includes that the method includes the following steps: under the pneumatic ultrasonic action, adjusting pH to be 1-5, adding ferrous ion salt, casting the iron nanoparticles in, adding hydrogen peroxide, performing solid-liquid separation after the pneumatic ultrasonic action, and discharging the waste water after the waste water reaches the standard. Comparing a pneumatic ultrasonic field with a common electric ultrasonic field, dispersion and radiation range can be widened, and the iron nanoparticles can be dispersed in the waste water more easily; air serves as a medium generating the pneumatic ultrasonic field, functions of an oxidizing agent (O2), stirring and cutting are provided for a waste water treating system, but only an air compressor generating the pneumatic ultrasonic field is energy-consuming equipment, so that energy-saving effect is achieved.

The invention relates to the technical field of water treatment, in particular to Halomonas taeanensis and a method for preparing flocculants by the same. Bacterial strain Halomonas sp.GHF11 of the Halomonas taeanensis is separated and purified from sludge spitted by short-necked clams, cultures of the bacterial strain are subjected to amplification culture to obtain culture liquid, the culture liquid is subjected to fermenting culture to secrete exopolysaccharides, flocculation carriers are added into fermentation bacteria solutions in later period of fermentation to provide adhesion places for thalli, the thalli are adhered to cluster and settle, and the exopolysaccharides completely settle under the further action of ethyl alcohol. The exopolysaccharides secreted by the bacterial strainHalomonas sp.GHF11 has high flocculation effect; the carriers are added during preparation of the flocculants, exopolysaccharide sedimentation is accelerated, and consumption of the ethyl alcohol isreduced; the obtained flocculants have high flocculation capability and stable performance.

The invention particularly relates to a forsterite bio-filter material for sewage treatment and a preparation method of the forsterite bio-filter material. The technical scheme is as follows: the preparation method comprises the following step: uniformly mixing 45-55wt% of forsterite raw ore fine powder, 20-30wt% of talc fine powder, 15-25wt% of magnesium oxide fine powder and 2-6wt% of dravite micropowder as raw materials with additional 2-6wt% of starch to prepare a mixed material; then, putting the mixed material and polystyrene balls in a pelletizer in a volume ratio of the polystyrene balls and the mixed material of (1.5-2.0) to 1; then, adding 10-20wt% of water to prepare particles with the grain size being 5-13mm; and then, roasting the prepared particles for 16-24 hours at 110-150 DEG C, and sintering for 2-4 hours at 1300-1500 DEG C to prepare the forsterite bio-filter material for sewage treatment. The forsterite bio-filter material for sewage treatment is simple in process and wide in source of raw materials and the prepared forsterite bio-filter material for sewage treatment has the characteristics of good flora biofilm culturing effect, high flora survival rate, good decoloring effect and high strength.

The invention discloses a preparation method and an application of hydrophobization beta-cyclodextrin cation polyelectrolyte. In a water phase, three monomers, namely polymerizable beta-cyclodextrin derivatives, acryloyl oxyethyl trimethyl ammonium chloride and styrene, are subjected to a free radical copolymerization reaction under an oxidation/reduction (potassium peroxodisulfate/sodium hydrogen sulphite) initiating system to obtain the hydrophobization beta-cyclodextrin cation polyelectrolyte product. The hydrophobization beta-cyclodextrin cation polyelectrolyte product is white powder solids and is stable in structure and convenient to store and transport, hydrophilcity is reduced and better solubility is still maintained; the preparation method of the hydrophobization beta-cyclodextrin cation polyelectrolyte product is simple, and low in energy consumption; no other auxiliaries such as a surface active agent is added in an aqueous solution polymerization process, and environmental pollution is less; and the hydrophobization beta-cyclodextrin cation polyelectrolyte product can serve as a novel flocculating agent for decoloration, the specific structure of beta-cyclodextrin (beta-CD) is reserved, toxicity and cost are low, flocculation capacity is strong, decoloration speed is high, an applicable pH range is wider (2-12), and salt tolerance is high.

The invention relates to a flocculation-sterilization double-effect macromolecule and a preparation method thereof. Diallyl amine and hydrochloric acid are adopted as raw materials to firstly synthesize diallyl amine hydrochloride, the diallyl amine hydrochloride is polymerized to poly-diallyl amine hydrochloride under the effect of a free radical initiator, and the poly-diallyl amine hydrochloride is reacted with epoxy long chain alkyl dimethyl ammonium halides which is obtained by Long-chain alkyl dimethyl amine and epoxy propane halogen in absolute ethyl alcohol in a water-alcohol mixed solvent to prepare the flocculation-sterilization double-effect macromolecule. The flocculation-sterilization double-effect macromolecule overcomes the weaknesses that the conventional flocculant does not have the sterilization function, the bactericide is lack of flocculation capacity, the flocculation and the sterilization are always separated in the application, the residual flocculant is reacted with the oxidization bactericide in the sterilization procedure to a harmful substance, and the bacteria dirty after the sterilization cannot be eliminated through the flocculation. The product of the invention can realize the flocculation and the sterilization functions at the flocculation procedure, so the traditional water treatment process can be simplified, and the cost can be reduced. The flocculation-sterilization double-effect macromolecule is suitable for being used as a processing agent for original water, waste water and drinking water.

The invention relates to an industrial wastewater treating agent, and belongs to the field of sewage treatment. The industrial wastewater treating agent comprises raw materials of flue ash, bentonite, corn starch, citric acid, sodium chloride, saccharide and activated carbon. According to the industrial wastewater treating agent, the flue ash and the bentonite are taken as main raw materials for sewage treatment, so that the sewage treatment cost is reduced; the absorption and flocculation capacity of the bentonite is high, the sedimentation time is shorter, and less sludge exists, so that the effect and the efficiency of sewage treatment are further improved; and corn starch, saccharide and activated carbon are added, so that the absorption and flocculation capacity is further improved, and no chemical agent is left in treated water.

The invention relates to a water purification agent, in particular to an oily sewage purificant used for treating oily sewage in oil fields, which consists of the following components according to weight percentage: 30 to 40 percent of aluminum chloride hexahydrate, 10 to 25 percent of epoxypropyl polyquaternary amine and 35 to 50 percent of poly(diallyldimethylammonium chloride. The oily sewage purificant is mainly used for the emulsion breaking and oil removing of oily sewage emulsion liquid or other 0/W sewage, has enough strong electrophilicity to neutralize negative charge formed by an emulsifier, has enough strong flocculation capability to flocculate particles in the emulsion liquid for facilitating the formation of large vanadium flowers, and has enough strong surface activity to break the interfacial energy of the emulsion liquid. The purificant is characterized by high deoiling rate, limpid water of dehydration, quick floating upwards of oil clots and even oil-water boundary. In addition, the purificant has the advantages of low dosage, low cost and broad application prospect.

The invention discloses alkenyl-branched monomers and a preparation method thereof, and belongs to the field of organic synthetic chemistry. The monomers are prepared by the steps of reacting a hydroxyethyl-containing branched polyamide intermediate and acryloyl chloride at a room temperature in presence of an organic solvent and an acid-trapping agent; standing; separating an organic phase; washing for a plurality of times by neutralizing with a saturated sodium bicarbonate solution; drying by using anhydrous sodium sulfate; steaming the organic solvent out to obtain a crude product; and further purifying the crude product to obtain a polymer grade product. The monomers can be used as co-polymerization monomers to prepare hyperbranched polymers used for oilfields and to prepare branched water-soluble polymers for other applications and emulsifiers for emulsion polymerization.

The invention discloses a cationic polymer as well as a preparation method and application thereof. The cationic polymer is prepared by the following five process steps in sequence: metering and mixing, hydroxymethylation reaction, polycondensation, inhibition reaction and free formaldehyde elimination. The cationic polymer has the advantages of high cationic degree, high molecular weight, long storage life and low formaldehyde content, and can serve as a flocculating agent, a reverse-phase demulsifier, a water reducing agent for concrete or a treating agent of textile fibers.

The invention discloses a demulsification water purifying agent for combination-flooding produced fluid and a preparation method for the demulsification water purifying agent and belongs to the technical field of petroleum extraction. The demulsification water purifying agent is prepared from the following ingredients in percentage by mass: 45% to 50% of polyether block copolymer, 30% to 40% of polyether polyol and 10% to 20% of esterification-terminated polyether surfactant, wherein the polyether block copolymer is multiblock polyether of polyoxyethylene and polyoxypropylene which takes propylene glycol as an initiator, the polyether polyol is polyethylene oxide ether which takes propylene glycol as an initiator, and the esterification-terminated polyether surfactant is diblock esterification-terminated polyether of polyoxyethylene and polyoxypropylene which takes propylene glycol as an initiator. The demulsification water purifying agent has the actions of demulsification, agglomeration-flocculation, adsorption-displacement and the like. By adding the demulsification water purifying agent into the combination-flooding produced fluid, other flocculation water purifying agents are not required to be added during the treatment of dehydrated sewage, and thus the effect of achieving two purposes by one agent can be achieved.