The invention relates to a pearlescent
pigment comprising a
metal oxide-containing,
platelet-shaped substrate and having a first and a second protective layer, wherein the
metal oxide has a
refractive index greater than 1.8, and in which the first protective layer comprises
cerium oxide and / or hydrated
cerium oxide and / or
cerium hydroxide, the second protective layer consists substantially, preferably completely, of SiO2, wherein the second protective layer is disposed on top of the first protective layer, and between the first and second protective
layers there can be disposed
metal oxide
layers which differ from
cerium oxide and / or hydrated
cerium oxide and / or
cerium hydroxide and SiO2, wherein the second protective layer has an organochemical aftercoat and the organochemical aftercoat comprises at least one
silane bonded to the second protective layer by means of at least one
oxygen atom, said α-
silane having the formula—O(4-n-m)—Si(—R1)m(—CH2—Y)n (I),in which 1≦n+m≦3; m=0 to 2; n=1 to 3 andR1 is a
hydrogen atom or an Si—C-bonded C1-C20-
hydrocarbon radical or a C1-C15-hydrocarbonoxy radical, in which in each case one or more
methylene units not adjacent to one another can be replaced by the groups —O—, —CO—, —COO—, —OCO—, or —OCOO—, —S—, or —NRx— and in which one or more methine units not adjacent to one another can be replaced by the groups —N═, —N═N—, or —P═, wherein R1 can independently be the same or different, Rx can be a
hydrogen atom or a linear, branched and / or cyclic C1-C15-
hydrocarbon radical or
aryl radical, and Y is a functional binding group reactive with a binder
system.