The invention provides a method for separating and extracting silver,
palladium,
copper and
germanium in silver separation residues. The method comprises the steps that S1, water is added into the silver separation residues for size mixing, after uniform stirring, an acid solution and a
chlorine-containing oxidant are added, a
system is heated and distilled,
germanium chloride liquid is obtained, and the
germanium chloride liquid is subjected to hydrolyzing and post-treatment to obtain
germanium oxide; S2, the silver separation residues obtained after the reaction in the step S1 are filtered, leaching residues and filtrate are obtained, the leaching residues and
sodium carbonate are smelted after being uniformly mixed, and
metal silver is obtained; S3, organic extraction liquid is added into the filtrate obtained in the step S2, element
palladium element and element
copper are extracted and separated, and the organic extraction liquid comprises an extraction agent and an organic
diluent; S4, a mixed liquid loaded organic phase obtained in the step S3 is subjected to reverse extraction and separation on the element
palladium and the element
copper, and copper reverse extraction liquid and palladium reverse extraction liquid are obtained; S5, the copper reverse extraction liquid is concentrated and crystallized to obtain
copper salt, and a precipitator is added into the palladium reverse extraction liquid to prepare
ammonium chloropalladate precipitate; and S6,
ammonium chloropalladate is subjected to calcining and reduction to obtain
metal palladium.