The application discloses an inorganic composite
solid electrolyte and a preparation method thereof, and relates to the technical field of
lithium batteries, and specifically discloses an inorganic composite
solid electrolyte and a preparation method thereof. The preparation method of the inorganic composite
solid electrolyte comprises the following steps: S1, mixing
lithium salt,
metal oxide A,
metal oxide B and
ammonium dihydrogen
phosphate, wherein the
metal oxide B is
titanium oxide, and intermittent vibration ball milling is performed to obtain mixed
powder; S2, adding
lanthanum oxide and
germanium oxide into the mixed
powder obtained in the step S1, and continuing to perform intermittent vibration ball milling to obtain composite
powder; and S3, performing low-temperature
sintering on the composite powder obtained in the step S2, and pressing to obtain an inorganic composite solid electrolyte film layer. The preparation method can significantly improve the reaction activity and synergistic effect among raw materials by adopting two-step intermittent vibration ball milling and one-step low-temperature
sintering, and the
conductivity of the inorganic composite solid electrolyte and the
lithium ion transmission performance and cycle life of the solid battery are improved, and meanwhile, no
solvent is used in the preparation process, and the
sintering cost is reduced.