41 results about "Coniferyl alcohol" patented technology

Particular aspects provide novel methods for redirecting carbon allocation in plants or cell culture from lignification to inherently more useful and tractable materials, and to facilitate the generation of, e.g., biofuels from the remaining plant roculture biomass. Particular aspects provided novel methods for converting monolignols into allyl / propenyl phenols, and for chavicol / eugenol formation or production. Additional aspects relate to the discovery of novel chavicol / eugenol synthases that convert p-coumaryl / coniferyl alcohol esters into chavicol / eugenol, and to novel compositions (e.g., novel proteins and nucleic acids encoding same), and novel methods using same for producing or forming chavicol / eugenol and other derivatives in cell culture and / or genetically modified plants, and for re-engineering the composition of plant biomass. Particular aspects provide novel methods for generation in culture or in planta of liquid / combustible allyl / propenyl phenols, and these phenolic products are utilized for (non-ethanol) biofuel / bioenergy purposes, while the remaining plant biomass facilitates the generation of other biofuels.

The invention discloses an enhancer for papermaking and a preparation method thereof, and belongs to the field of papermaking. The enhancer for papermaking comprises the following components in parts by weight: 20-30 parts of cationic polyacrylamide, 15-20 parts of hydroxypropyl methyl cellulose, 20-30 parts of coniferyl alcohol, 15-20 parts of polyethylene glycol, 10-20 parts of glyceryl stearate, 10-20 parts of starch, 5-8 parts of aluminum sulfate and 1-2 parts of sodium bicarbonate. The enhancer prepared by the method can be applied to the field of papermaking, paper prepared by the enhancer has good strength and certain waterproofness, and meanwhile, the preparation method disclosed by the invention is simple and can be applied to repeated production.

A process for the production of natural ferulic acid, coniferyl alcohol and / or vanillin, includes the bio-conversion of eugenol by a bacteria belonging to the Streptomyces genes including at least one nucleotide sequence SEQ ID NO:1 or SEQ ID NO:8 or any nucleotide sequence having at least 70%, preferably 80% and very preferably 90%, identity with the sequence SEQ ID NO:1 or SEQ ID NO:8.

An inductive production-increase agent for the honeybee pollination on flowering plants comprises (E)-9-Oxodec-2-enoic acid (9-ODA), R (-)-9-hydroxy-(E)-2-decenoic acid (R(-)-9HDA), S(+)-9-hydroxy-(E)-2-decenoic acid (S (+) -9HDA), Methyl 4-hydroxybenzoate (HOB), 4-hydroxy-3-methoxyphenylacetic (HVA), 9-Octadecenoic acid methyl ester (methyl oleate), (E)-4-(4-Hydroxy-3-methoxypheny)-3-2-propen-1-ol (coniferyl alcohol), hexadecanol and (Z9, Z12, Z15)-9, 12, 15-octadecatrienoic acid (linolenic acid); the invention can effectively induce a honeybee to pollinate on flowering plants. The inductive production-increase agent has a positive effect on the production increase of honeybee pollination on blueberries and cherries; it effectively extrudes the application of the queen bee flowing element in the inductive production increase in the pollination on blueberries and cherries.

The invention belongs to the technical field of medicine preparation, and particularly relates to a eucommia ulmoides extract composition and a preparation method and application thereof. The composition comprises the following components: geniposidic acid, chlorogenic acid, aucubin, and a mixture of pinoresinol diglucoside and dehydrodiconiferyl alcohol diglucoside. The extract composition can effectively treat primary hypertension or kidney deficiency syndrome, has no toxic or side effect, is small in dosage, and can effectively reduce the medication cost.

The invention relates to a fabricating method of a formaldehyde-free wheat straw medium density fiberboard, which comprises the following steps: wheat straw chemical-mechanical pulp is added with NaAc-HAc buffer to dilute pulp into wheat straw fiber suspension with mass concentration of 2-10%; coniferol-beta-D-glucoside that is 1-10% of oven dry wheat straw pulp, 0.05-0.5% of beta-glucosidase with concentration of 6.3u / mg, 1-12% of pectin colloid and 1-8% of cationic paraffin emulsion are respectively added in the suspension; and then, 10U / g-80U / g of laccase is added in the suspension to start reaction; the processed wheat straw fiber is scattered through an electric mixer; a fiberboard former is used to shape the fiberboard; excess water is removed by prepressing; and at last the fiberboard is obtained by hot pressing. By virtue of the fabricating method, the physical mechanical property and water-resistant performance of the wheat straw medium intensity fiberboard are improved; the pollution problem of free formaldehyde generated during the process of artificial board production and utilization is solved; waste materials such as crop wheat straw can be utilized; and the environment pollution is reduced.

The invention discloses a method for degrading lignin in seawater. The method comprises the following steps: at the temperature of 150-500 DEG C, after the lignin is mixed with the seawater for reaction for no less than 0.5 h, separating to obtain the mixed product of phenolic compounds, wherein the total weight of the mixed product of the phenolic compounds accounts for more than 20% of the weight of the lignin in feeding materials. The method has the advantages of wide source of raw materials, simplicity in separation, high product yield and the like, and is suitable for preparing the phenolic compounds such as coniferyl alcohol, tonquinol, vanillic aldehyde, syringyl derivatives and the like by using biomass resources as raw materials.

The invention discloses a method for synthesizing silibinin by virtue of an enzyme catalysis reaction, belonging to the field of biochemical industry. According to the method, four isomerides of the silibinin are synthesized by catalyzing coniferyl alcohol and taxifoliol by virtue of peroxidase in the presence of hydrogen peroxide. The reaction is carried out in a water phase, and the use of an organic solvent is avoided; and moreover, the reaction efficiency is high, 18.52mg / L of silibinin can be generated within 5 minutes, and the conversion rate is 85.31 percent. The method is a safe and high-efficiency method for synthesizing silibinin.

A process for preparing the Chinese-medicinal extract rich in coniferylester ferulate includes such steps as providing the powder of Chinese-medicinal material rich in coniferylester ferulate, supercritical CO2 extracting or organic solvent extracting, volatilizing the organic solvent to obtain refined oil, extracting by the mixture of organic solvents or organic solvent, and evaporating out the organic solvent. The application of said extract in preparing medicine, health-care product, or cosmetics for preventing and treating cardiovascular and cerebrovascular diseases is also disclosed.

The invention provides a spiraea salicifolia stem and branch anti-rheumatoid-arthritis effective part and a preparation method and application thereof.According to the effective part, spiraea salicifolia stems and branches serve as raw materials, extract is obtained after 60% ethyl alcohol reflux extraction and ethyl alcohol pressure reduction recovery, the extract is purified with macroporous adsorption resin, and the total lignanoside effective part is obtained.The sum of weights of (+)-8'-hydroxy pinoresinol-8'-O-beta-d-glucopyranoside, (7R,8S)-dihydro dehydrogenation bis-coniferyl alcohol-9'-O-beta-d-glucopyranoside, (+)-lyonia ovalifolia tree ring lignans-9-O-beta-d-glucopyranoside and (+)-isolariciresinol-9-O-beta-d-pyran xyloside in the effective part ranges from 40% to 50%.The effective part is determined through the method that a modern separation means and pharmacological activity screening are combined, the ingredients of obtained effective part are clear, the content of active ingredients is high, it is shown through the in-vitro and in-vivo experiment results that the spiraea salicifolia stem and branch anti-rheumatoid-arthritis effective part inhibits generation of pro-inflammatory cytokine tumor necrosis factor-alpha, interleukin-1 beta and interleukin-6 to achieve the effect of treating rheumatoid arthritis.

The invention discloses a high-temperature-resistance low-square-resistance conductive silver slurry and a preparation method for the same. The high-temperature-resistance low-square-resistance conductive silver slurry is made by the weight parts of the following ingredients: silver powder 45-55, yttria nanometer powder 1-2, thallium oxide nanometer powder 1.1-1.2, urea 1.5-2.7, methyl cellulose 0.5-0.9, fatty alcohol sodium sulfate 0.4-0.8, medical stone 2-4, pastern 3-5, alkyd 1-3, glycerinum 2.4-3.7, coniferyl alcohol 2.4-3.6, accessory ingredient 30-40 and water. The conductive silver slurry has excellent performance of resisting high temperature, can resist high temperature of being over 200 DEG, and uses the yttria nanometer powder and the thallium oxide nanometer powder to increase the conductivity and adherence of the conductive slurry and is very promising.

The invention belongs to the technical field of papermaking, and particularly relates to a multi-functional composite reinforcing agent for papermaking and a preparation method thereof. The preparation method comprises the steps of: preparing doped halloysite nanotubes from halloysite nanotubes and aluminum nitrate as raw materials, and then using gamma-aminoethyl aminopropyl trimethoxy silane for modification treatment to obtain a modified nano material; by taking hydroxymethyl acrylamide as a raw material, preparing gelatinous polyhydroxymethyl acrylamide through an inverse emulsion polymerization method; preparing starch into starch slurry, adding polyhydroxymethyl acrylamide, carrying out grafting reaction to obtain grafted starch slurry, and carrying out etherification modification by using 3-chloro-2-hydroxypropyl-trimethoxy ammonium chloride to obtain modified starch slurry; and finally, adding the modified nano material and coniferyl alcohol into the modified starch slurry, and stirring for reaction. By adding the reinforcing agent, the strength of paper can be obviously improved.

The invention provides a spiraea salicifolia stem and branch anti-rheumatoid-arthritis effective part and a preparation method and application thereof.According to the effective part, spiraea salicifolia stems and branches serve as raw materials, extract is obtained after 60% ethyl alcohol reflux extraction and ethyl alcohol pressure reduction recovery, the extract is purified with macroporous adsorption resin, and the total lignanoside effective part is obtained.The sum of weights of (+)-8'-hydroxy pinoresinol-8'-O-beta-d-glucopyranoside, (7R,8S)-dihydro dehydrogenation bis-coniferyl alcohol-9'-O-beta-d-glucopyranoside, (+)-lyonia ovalifolia tree ring lignans-9-O-beta-d-glucopyranoside and (+)-isolariciresinol-9-O-beta-d-pyran xyloside in the effective part ranges from 40% to 50%.The effective part is determined through the method that a modern separation means and pharmacological activity screening are combined, the ingredients of obtained effective part are clear, the content of active ingredients is high, it is shown through the in-vitro and in-vivo experiment results that the spiraea salicifolia stem and branch anti-rheumatoid-arthritis effective part inhibits generation of pro-inflammatory cytokine tumor necrosis factor-alpha, interleukin-1 beta and interleukin-6 to achieve the effect of treating rheumatoid arthritis.

The invention provides a preparation method for a composite material for energy storage elements, which includes the following steps: (1) graphene oxide, meso-erythritol, coniferyl alcohol, tea cake meal, lignin, xylan, lactose and distilled water are mixed and stirred; (2) mixture is loaded into a hydrothermal reaction kettle and heated, and temperature is kept; (3) the mixture is cooled to room temperature, filtered, washed to be neutral and dried, so that a product A is obtained; (4) the product A, potassium hydroxide, sodium hydroxide and distilled water are mixed and stirred; (5) sucrose fatty acid ester, quillaic acid, quercetin, paraben, propylgallate, n-butyl stearate and isopropanol are mixed and stirred; (6) the mixtures are mixed, put into a tube furnace and sintered; (7) the sinter is cooled to room temperature, washed to be neutral and dried, so that the composite material is obtained. The specific capacitance value of the material prepared by the method disclosed by the invention is extremely high, the energy density is much higher than the energy density of conventional energy storage elements, the efficiency of discharge is high, moreover, the composite material can show good cycle stability, and the repetition utilization rate is high.

The invention discloses high-strength carbon paper which is prepared from the following raw materials in parts by weight: 7 to 9 parts of sodium carboxymethylcellulose, 5 to 8 parts of titanium dioxide, 12 to 15 parts of polyamine polyepoxide resin, 3 to 5 parts of polyethylene glycol, 3 to 4 parts of sodium benzoate, 4 to 6 parts of borax, 13 to 18 parts of aramid fiber, 6 to 8 parts of light calcium carbonate, 6 to 7 parts of styrene-butadiene latex, 3 to 5 parts of coniferyl alcohol, 7 to 8 parts of sodium bicarbonate, 7 to 11 parts of corn starch, 4 to 6 parts of fatty acid, 6 to 8 parts of benzotriazole and 12 to 16 parts of pigment. The high-strength carbon paper disclosed by the invention has the advantages of clearness in duplication, good duplication effect, high strength of duplication area and no decoloring.

The invention relates to the field of separation and detection of substances, and provides a method for synchronous detection of coniferyl alcohol and pinoresinol. First, high performance liquid chromatography is used to measure the absorbance of coniferyl alcohol and pinoresinol in a sample to be tested, wherein the detection wavelength is 280nm; The high-performance liquid chromatography adopts gradient elution, and the eluent in the gradient elution includes methanol and water; then according to the standard curve of coniferyl alcohol and the absorbance of coniferyl alcohol in the test sample, the coniferyl alcohol in the test sample is obtained. The concentration of alcohol; According to the standard curve of pinoresinol and the absorbance of pinoresinol in the test sample, obtain the concentration of pinoresinol in the test sample. The method provided by the invention can effectively separate coniferyl alcohol and pinoresinol in the sample to be tested, and detect the corresponding concentrations of coniferyl alcohol and pinoresinol respectively.

The invention discloses a method for degrading lignin in seawater. The method comprises the following steps: at the temperature of 150-500 DEG C, after the lignin is mixed with the seawater for reaction for no less than 0.5 h, separating to obtain the mixed product of phenolic compounds, wherein the total weight of the mixed product of the phenolic compounds accounts for more than 20% of the weight of the lignin in feeding materials. The method has the advantages of wide source of raw materials, simplicity in separation, high product yield and the like, and is suitable for preparing the phenolic compounds such as coniferyl alcohol, tonquinol, vanillic aldehyde, syringyl derivatives and the like by using biomass resources as raw materials.

The invention discloses a method for catalytically synthesizing silybin through laccase, and belongs to the field of biochemical industry. According to the method for catalytically synthesizing the silybin through the laccase, four types of isomerides of the silybin are synthesized by catalyzing coniferyl alcohol and taxifolin through the laccase. The reaction is conducted in a water phase, and use of organic solvent is avoided; the reaction efficiency is high, and 0.9694 mg / L of the silybin can be generated within 1 h. The method for synthesizing the silybin is safe and efficient.

The invention provides an oil-displacing discharge aiding agent as well as a preparation method and application thereof. The preparation method comprises the steps of S1, carrying out ring-opening reaction on coniferyl alcohol, ethylene oxide and a first solvent under an alkaline condition to obtain a product system containing a ring-opening compound; S2, carrying out sulfonation reaction on the product system containing the ring-opening compound, SO3 and a second solvent to obtain a sulfonate compound; and S3, mixing the sulfonate compound and a surface active substance to obtain the oil-displacing discharge aiding agent, wherein the surface active substance is a mixture of a fluorocarbon surfactant and ammonium bicarbonate, and the ring-opening compound and the sulfonate compound respectively have structural formulas shown in the description, and M < + > is a monovalent cation. The method is simple, low in cost and remarkable in effect of solving the problem that the multi-cycle steam huff and puff harvesting effect becomes poor.

A coniferyl alcohol or a Compositae family, Brassicaceae family, Umbelliferae family, Lamiaceae family, Liliaceae family or Amaranthaceae plant extract provides various uses associated with hTRPA1 activation, and, being a natural compound, involves relatively few side effects in the body and has substantial industrial applicability. The coniferyl alcohol or the Compositae family, Brassicaceae family, Umbelliferae family, Lamiaceae family, Liliaceae family or Amaranthaceae plant extract of the present invention not only will be a novel medical or food raw material which is helpful in maintaining homeostasis in the body associated with hTRPA1 activation, but can also be used to advantage in hTRPA1 antagonist screening.

The invention discloses a reinforcing agent for papermaking and a preparation method thereof, which belongs to the field of papermaking. The strengthening agent for papermaking is made of the following components by weight: 20-30 parts of cationic polyacrylamide, 15-20 parts of hydroxypropyl methylcellulose, 20-30 parts of coniferyl alcohol, polyethylene glycol 15-20 parts, 10-20 parts of glyceryl stearate, 10-20 parts of starch, 5-8 parts of aluminum sulfate and 1-2 parts of sodium bicarbonate. The strengthening agent prepared by the method can be used in the field of papermaking, and the paper prepared by adding the strengthening agent has good strength and certain water resistance, and meanwhile, the preparation method of the invention is simple and can be produced repeatedly.

The invention discloses a method for synthesizing silibinin through an enzyme-catalyzed reaction, and belongs to the field of biochemical industry. In the present invention, four isomers of silibinin are synthesized by peroxidase catalyzing coniferyl alcohol and docetaxel in the presence of hydrogen peroxide. The reaction is carried out in the aqueous phase, avoiding the use of organic solvents; the reaction efficiency is high, and 18.52 mg / L silibinin can be produced within 5 minutes, and the conversion rate is 85.31%. The method is a safe and efficient method for synthesizing silibinin.

The invention discloses a high-temperature-resistance low-square-resistance conductive silver slurry and a preparation method for the same. The high-temperature-resistance low-square-resistance conductive silver slurry is made by the weight parts of the following ingredients: silver powder 45-55, yttria nanometer powder 1-2, thallium oxide nanometer powder 1.1-1.2, urea 1.5-2.7, methyl cellulose 0.5-0.9, fatty alcohol sodium sulfate 0.4-0.8, medical stone 2-4, pastern 3-5, alkyd 1-3, glycerinum 2.4-3.7, coniferyl alcohol 2.4-3.6, accessory ingredient 30-40 and water. The conductive silver slurry has excellent performance of resisting high temperature, can resist high temperature of being over 200 DEG, and uses the yttria nanometer powder and the thallium oxide nanometer powder to increase the conductivity and adherence of the conductive slurry and is very promising.

The invention belongs to the biotechnology field, and particularly relates to a method for preparing dihydro-dehydro-di(coniferyl alcohol)glucoside (HMZG) through biotransformation. The dihydro-dehydro-di(coniferyl alcohol)glucoside (HMZG) is obtained from a strain with the preservation number of Bacillus subtilis ATCC 6633 through biotransformation, and three glucoside pure products (HMZG-1, HMZG-2 and HMZG-3) are obtained through repeated silicagel column chromatography purification. Therefore, the biotransformation method for efficiently obtaining the dihydro-dehydro-di(coniferyl alcohol)glucoside (HMZG) is established.

The invention discloses an engineering bacterium for producing coniferyl alcohol, a construction method and an application of coniferyl alcohol production. The construction method comprises the following steps: fully chemically compounding TAL, COMT, 4CL and CCR genes; performing PCR cloning on hpaBC, yahK, metK and pntAB genes; fully chemical compounding pBPE001, pBPE002 and pBPE003; linking the genes TAL, hpaBC and COMT with pBPE001, thereby acquiring pTHM; linking the genes 4CL, CCR and yahK with pBPE002, thereby acquiring pLRH; linking the genes pntAB and metK with pBPE003, thereby acquiring pNAM; integrating the T7RNA polymerase gene into SyBE-002447 base strain, thereby acquiring a SyBE-002447(DE3) strain; converting pTHM, pLRH and pNAM into SyBE-002447(DE3), thereby acquiring the engineering bacterium SyBE-CNF; taking glucose as a carbon source and fermenting, thereby producing coniferyl alcohol. According to the invention, the engineering escherichia coli are used for producing coniferyl alcohol, so that the source problem of the coniferyl alcohol can be solved and the cost can be lowered.

The invention discloses a synthesis method of a valerolactam alkaloid compound. The method comprises the steps that 1) thionyl chloride reacts with methanol, and then ferulic acid is added to synthesize ferulic acid methylester; 2) the ferulic acid methylester reacts under the function of diisobutylaluminum hydride to generate coniferyl alcohol; 3) 2-piperidone reacts with phosphorus pentachloride, and then a reaction product reacts with bromine under the function of potassium iodide to generate 3,3-dibromo-2-piperidone; 4) the 3,3-dibromo-2-piperidone reacts with hydrogen and sodium acetate under the function of palladium carbon to generate 3-bromo-2-piperidone; 5) the 3-bromo-2-piperidone prepared in the fourth step reacts with the coniferyl alcohol prepared in the second step under thefunction of sodium hydroxide to generate the valerolactam alkaloid compound. The synthesis method has the advantages that the sources of the raw materials are easy to obtain, the reaction conditions are mild, and the operation in the reaction process is simple.

The invention belongs to the biotechnology field, and particularly relates to a method for preparing dihydro-dehydro-di(coniferyl alcohol)glucoside (HMZG) through biotransformation. The dihydro-dehydro-di(coniferyl alcohol)glucoside (HMZG) is obtained from a strain with the preservation number of Bacillus subtilis ATCC 6633 through biotransformation, and three glucoside pure products (HMZG-1, HMZG-2 and HMZG-3) are obtained through repeated silicagel column chromatography purification. Therefore, the biotransformation method for efficiently obtaining the dihydro-dehydro-di(coniferyl alcohol)glucoside (HMZG) is established.

The invention relates to the field of substance separation detection and provides a synchronous detection method of coniferyl alcohol and pinoresinol. Absorbance values of coniferyl alcohol and pinoresinol in a to-be-detected sample are measured by using high performance liquid chromatography, wherein the detection wavelength is 280 nm and the high-performance liquid chromatography employs gradient elution and the eluent in the gradient elution includes methanol and water; according to a standard curve of coniferyl alcohol and the absorbance of the coniferyl alcohol in the coniferyl alcohol, the concentration of the coniferyl alcohol in the to-be-detected sample is obtained; and on the basis of the standard curve of pinoresinol and the absorbance of pinoresinol in the to-be-detected sample, the concentration of the pinoresinol in the to-be-detected sample is obtained. Therefore, the coniferyl alcohol and pinoresinol in the to-be-detected sample can be separated effectively; and the corresponding concentrations of the coniferyl alcohol and pinoresinol can be detected respectively.

The invention provides an oil-displacing aid and a preparation method and application thereof. The preparation method includes step S1, performing a ring-opening reaction with coniferyl alcohol, ethylene oxide and a first solvent under alkaline conditions to obtain a product system comprising a ring-opening compound; 3 and a second solvent for sulfonation reaction to obtain a sulfonate compound; and step S3, mixing the sulfonate compound and a surface active substance to obtain an oil-displacing aid; wherein, the surface active substance is a fluorocarbon surfactant and a surface active substance. The mixture of ammonium bicarbonate, the ring-opening compound and the sulfonate compound respectively have the following structural formulas: M + is a monovalent cation. In addition, the method is simple and low in cost, and has a remarkable effect of solving the deterioration of the recovery effect of multi-cycle steam huff and puff.