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Carbon quantum dot doped liquid chromatography filler as well as preparation method and application thereof

The invention discloses a carbon quantum dot doped liquid chromatography filler and a preparation method and application thereof.The preparation method comprises the steps that silica gel is acidified, a silanization reagent, a catalyst, a reaction solvent and the acidified silica gel are mixed, heated, stirred and refluxed, and double-bond modified silica gel is obtained; the preparation method comprises the following steps: mixing and pre-polymerizing a functional monomer, a pore-foaming agent and template molecules to obtain a pre-polymerization system, adding a cross-linking agent, double-bond modified silica gel, an initiator and carbon quantum dots into the pre-polymerization system, carrying out programmed heating, stirring for a period of time, washing and drying to obtain the carbon quantum dot doped liquid chromatography filler. According to the chromatographic packing prepared by the invention, the properties of small size effect, high specific surface area, abundant acting sites and the like of the carbon quantum dot material are combined with the unique selectivity of the molecularly imprinted polymer and various excellent properties that the porous silica gel is suitable for being used as a chromatographic separation material carrier; therefore, the method is suitable for separation and analysis of various small-molecule polar drugs.
Owner:YANTAI UNIV

Agricultural composition with Chinese herbal medicine

The invention discloses an agricultural composition with Chinese herbal medicine. Raw materials of the Chinese herbal medicine are composed of Chinese herbal medicine which has the insecticidal function on plants and Chinese herbal medicine which has the nutrient function on the plants; the composition is prepared from macleaya cordata (willd.) r. brownbocconia cordata willd., sophora moorcroftiana, herba houttuyniae, radix angelicae dahuricae, pericarpium granati, manglietia fordiana, rhizoma curcumae longae, radix stemonae, radix aconiti kusnezoffii, golden larch bark, rhizoma arisaematis, rhizoma pinelliae, Chinese tallow leaves, vitex leaf ash, camellia oleifera tree leaf ash, ailanthus altissima leaf powder, radix adenophorae root powder, gynostemma pentaphyllum stem leaf powder and medicago sativa stem leaf powder. The agricultural composition with the Chinese herbal medicine has the advantages that the composition is environmentally friendly and safe, low in cost, simple in preparation method and good in insecticidal effect, pests do not generate drug resistance easily, and the yield of crops is remarkably improved, and the agricultural composition with the Chinese herbal medicine is worthy of application and popularization on large-scale agricultural production.
Owner:惠州市支持网知识产权运营有限公司

Preparation method and application of molecularly imprinted photonic crystal for detecting sulfamethoxazole

The invention discloses a preparation method and application of a molecularly imprinted photonic crystal for detecting sulfamethoxazole. The preparation method comprises the following steps of firstly, depositing polystyrene emulsion microspheres on the surface of a glass slide by utilizing a vertical deposition method to obtain a photonic crystal template, filling gaps of the polystyrene microspheres on the photonic crystal template with a precursor solution containing sulfamethoxazole, a functional monomer, a cross-linking agent and an initiator, carrying out a constant temperature reaction for a period of time, and eluting the polystyrene microspheres and sulfamethoxazole with a solvent to prepare the molecularly imprinted photonic crystal. The molecularly imprinted photonic crystal provided by the invention shows different colors in sulfamethoxazole solutions with different concentrations, and the concentration range of sulfamethoxazole can be roughly judged through naked eye observation. Furthermore, the displacement of the Bragg diffraction peak of the photonic crystal is measured by using a fiber optic spectrometer, so that quantitative analysis on trace sulfamethoxazole can be realized.
Owner:TIANJIN UNIV
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