The invention relates to a line selection ring cavity for a chemical laser device. The device is in a stable ring cavity structure and is sequentially provided with a blazed grating, a plane mirror, a plane mirror, a plano-concave reflector, a Brewster piece, an activating medium area and a Brewster piece, and a zero level zero level output of the blazed grating is provided with the plane mirrors. According to the laser device provided by the invention, the line selection output of the chemical laser device can be realized by using the zero level, primary diffraction vibration and zero diffraction output. A resonant cavity of the laser device is in either a four-mirror rectangular travelling-wave cavity or a four-mirror '8'-shaped annular travelling-wave cavity, therefore, the laser device can more effectively extract active particles in a gain medium area and the output power of the line selection laser can be improved; furthermore, the line selection ring cavity has the characteristics of compact structure, high power, good beam quality, high stability and the like, thereby being extensively applied to the fields of laser physics, laser chemistry, materials processing and the like.