The application relates to the secondary battery technical field, and discloses a
manganese-based positive
pole piece, a preparation method thereof, a secondary battery and an
electric equipment. The positive
pole piece comprises, in sequence from the thickness direction of the
pole piece, a
current collector, a
manganese-based positive active material layer, an
oxide layer and a
phosphorus-containing
oxygen acid
covalent modification layer; the
oxide layer and the
phosphorus-containing
oxygen acid
covalent modification layer are connected through P-O bonds. The application proposes that the application constructs a stable multilayer interface modification structure by covalently combining the
oxide layer and the
phosphorus-containing
oxygen acid
covalent modification layer through sequentially stacking a multilayer structure, can cover the entire pole piece macroscopic interface, has
strong binding force, can strengthen the adsorption capacity of
manganese ions, block the interface
side reaction chain, avoids the problems that the traditional particle-level
coating is easy to break and fail, the
binding force of the conventional protective film is weak and the distribution is uneven, and therefore can effectively inhibit the manganese
ion elution and
electrolyte decomposition, has the advantages of improving the
battery capacity retention rate, the cycle stability and the
thermal safety.