The invention provides a low-
silicon SAPO-34
molecular sieve as well as a preparation method and an application thereof. The preparation method of the low-
silicon SAPO-34
molecular sieve comprises steps as follows: (1), guiding lyogel is prepared from a
silicon source, an aluminum source, a
phosphorus source, a
seed crystal, a template agent and water through stirring and mixing at the temperature of 0-20 DEG C, and a
seed crystal guiding liquid is prepared after the guiding lyogel is subjected to hydrothermal
crystallization; (2), initial gel of the SAPO-34
molecular sieve is prepared from the silicon source, the aluminum source, the
phosphorus source, the
seed crystal guiding liquid, the template agent and water through stirring and mixing at the temperature of 0-20 DEG C; the initial gel of the SAPO-34 molecular
sieve is subjected to low-temperature hydrothermal
crystallization and high-temperature hydrothermal
crystallization sequentially and then is subjected to aftertreatment, and the low-silicon SAPO-34 molecular
sieve is prepared. According to the method, an inexpensive template agent can be used less or even cannot be used, and a product meeting requirements for
crystallinity and purity is obtained without prolonging of crystallization time, and the preparation method of the low-silicon SAPO-34 molecular
sieve is suitable for large-scale industrial production.