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37results about How to "Play a role in enrichment" patented technology

Method of performing oxidation treatment on waste lithium ion batteries

The invention relates to a method of performing oxidation treatment on waste lithium ion batteries, and belongs to the technical field of environment. The method comprises the following steps of adding waste lithium ion battery powder into an acidic water solution to obtain mixed slurry; inputting oxidizing gas to the mixed slurry with an aerating device, and performing oxidizing leaching; after areaction is completed, regulating the pH of the reaction slurry with an acid regulating reagent to remove few valuable metal ions in lixivium, and then performing solid-liquid separation to obtain lithium-enriched purifying liquid and reaction tailings; and then performing lithium sinking and solid-liquid separation on the purifying liquid so as to obtain lithium carbonate products or lithium phosphate products. Through the adoption of the method disclosed by the invention, through an aeration means, under a milder condition, high-selectivity extraction of lithium elements in the waste lithium ion batteries is realized; the reaction process is green and clean, simple and easy to operate, and wide in application range; and the lithium extraction rate is 85% or above, and the extracting selectivity is 95% or above, so that the problem that in a conventional processing method, lithium resources cannot be economically and effectively recovered can be solved from the source.
Owner:INST OF PROCESS ENG CHINESE ACAD OF SCI

Heavy metal activator and application thereof in soil joint restoration

The invention provides a heavy metal activator and application thereof in soil joint restoration. The activator preparation comprises the following steps that (1) straws are crushed and sieved, the crushed straws are added into an alkaline solution, a heating reacting is conducted, filtering is conducted after finishing the heating reaction, the filtration residue is taken and washed with water, washing is repeated until the eluent is neutral, and drying is conducted to obtain the lignin-removed straws; (2) urea is added into the lignin-removed straws, composting fermentation is conducted, rapeseed meal is added after the fermentation is thoroughly decomposed, a functional microbial agent is added, secondary fermentation is conducted after uniform stirring, and then after the second fermentation, the straw bio-organic fertilizer is obtained; and (3) organic acid is added into the straw bio-organic fertilizer, and uniform mixing is conducted to obtain the heavy metal activator. According to the application, through crop-rotation combined planting of soybeans and oilseed rape, the heavy metal is activated by the heavy metal activator, so that heavy metal in the soil can be convertedinto an effective state as much as possible to realize the continuous absorption of heavy metal, the joint restoration efficiency is improved, and the easy-to-implement and efficient combined restoration method is also provided for restoring heavy metal contaminated farmland soil.
Owner:湖南泰谷生态工程有限公司

Method for detecting lime-like substance in flour

The invention relates to the field of foodstuff safety, and discloses a method for detecting lime-like substances in flour. The invention comprises the steps of: collecting microscopic mid-infrared images of flour samples requiring detecting; carrying out image analysis upon the microscopic mid-infrared images of the flour samples according to mid-infrared spectral features of lime-like substances and pure flour; calculating derivative spectrums of the lime-like substances and the pure flour according to the mid-infrared spectrums; and carrying out spectrum enhanced image analysis upon the microscopic mid-infrared images of the flour samples according to the derivative spectral features. According to the method for detecting lime-like substances in flour, complicated pretreatment is not required during a detection process; the detection steps are simple and quick; and detection results are accurate and reliable. Also, a target sample dimension of microscopic mid-infrared imaging reaches a micrometer grade, which is similar to a dimension of lime-like substance particles. Therefore, relative to a small lime-like additive amount, the method contributes to a lime-like substance enriching effect within a dimensional scope, such that the additive is easy to be detected.
Owner:BEIJING ACADEMY OF AGRICULTURE & FORESTRY SCIENCES

Wet pre-separation process for copper-containing magnetite ore

The invention discloses a wet pre-separation process for copper-containing magnetite ore, and belongs to the technical field of ore separation. The method comprises the following steps that raw ore ofthe copper-containing magnetite ore is crushed, crushed products are screened, screened copper-containing magnetite ore particles are subjected to wet magnetic separation, and concentrate products obtained after magnetic separation are fed into a ball mill to be subjected to ball milling; tailings obtained after wet magnetic separation are screened, oversize products obtained after screening aredirectly discharged, the ore grinding amount of follow-up ball milling operation can be reduced, the ore dressing production cost is reduced, loss of the copper element is avoided as much as possible,and the oversize products are sold as building material products to increase benefits; the ball-milled ore discharge and undersize products are fed into a hydrocyclone for grading, and settled sand of the hydrocyclone is returned to the first-section ball mill to form closed-loop ore grinding; overflow products of the hydrocyclone enter subsequent sorting operation to sort magnetite and chalcopyrite, and therefore the technical effect that copper elements should be completely collected is achieved.
Owner:马钢集团设计研究院有限责任公司

Novel method for purifying and recycling arsenic-containing flue gas by using acidic liquid medium

The invention relates to a novel method for purifying and recycling arsenic-containing flue gas by using an acidic liquid medium, belonging to the technical field of heavy metal pollution treatment. According to the invention, water washing in an acid making process is replaced with acid pickling, so heavy metal ions can be effectively enriched, acid recycling is achieved, and the method is suitable for heavy non-ferrous metal smelting flue gas purification and arsenic pollution treatment. After heavy non-ferrous smelting flue gas is subjected to gravity dust collection and electric dust collection, a part of auxiliary additives are added into an acid medium solution containing sulfuric acid to prepare a proper washing solution before the heavy non-ferrous smelting flue gas enters an acidmaking link, the flue gas is subjected to spraying or spray washing, sulfuric acid and heavy metal are recycled through concentration of mixed liquid obtained after washing, and meanwhile, a fluorineand chlorine removing agent is added to remove fluorine and chlorine. The acidic liquid medium is used for replacing water washing to purify SO2 flue gas, so generation of waste acid can be avoided, arsenic and heavy metal elements are effectively recycled, and soluble sulfur oxide in SO2 flue gas is fully utilized and recycled, so the method is of important significance in arsenic pollution treatment in the heavy non-ferrous metal smelting industry.
Owner:CHUXIONG DIANZHONG NON FERROUS METALS LLC +1

Blue Dream white liquor aroma component concentrating method

The invention provides a Blue Dream white liquor aroma component concentrating method. Blue Dream white liquor is measured and is added into a container, then a saturated salt solution is added, mixing is performed to obtain a solution to be extracted, wherein the volume ratio of the Blue Dream white liquor to the salt solution is 1:3-7; a mixed solution of dichloromethane, diethyl ether and hexane is added into the solution to be extracted, continuous extraction is performed to obtain an upper-layer organic phase, moisture in the organic phase is removed, and then filtration is performed by adopting a filter membrane; the mixed solution obtained after filtration by adopting the filter membrane is added into an impalement type fractionation device, the fractionation device is put into a constant-temperature water bath kettle of 45-55 DEG C to perform impalement type fractionation and concentration, and the mixed solution subjected to impalement type fractionation and concentration is concentrated by using a pressure blowing concentrator to obtain a Blue Dream white liquor aroma component. The Blue Dream white liquor aroma component concentrating method is simple and convenient to operate, capable of saving time and effort and low in cost, can play enrichment and concentration roles on minor components, facilitates qualitative and quantitative analysis on extremely trace amounts of substance, meanwhile effectively reduces loss of volatile components and improves the recovery rate of aroma substance.
Owner:SHANGHAI INST OF TECH

A combined method for repairing heavy metal-contaminated soil

The invention discloses a method for remediating soil contaminated by heavy metals such as cadmium by combining in-situ leaching, deep-layer fixing and phyto-extracting. According to the method, the heavy metals are leached into a deep layer along with a leaching solution through the in-situ leaching in a surface layer and are fixed in the deep layer, then willow with the heavy metal accumulation function is planted after organic fertilizer is applied, and therefore the residual heavy metals can be further removed, and the soil function can be restored; the heavy metals in a plough layer are leached to the deep layer, the absorption of crops to the heavy metals is reduced, the heavy metals which are leached to the deep layer are fixed, underground water is not polluted, and therefore the residual heavy metals can be further removed through phytoremediation, and the soil function can be restored; an iron-containing compound used in the method does not destroy the soil structure and can serve as a rice field soil conditioner; and compared with the phytoremediation, the method has the advantage that the remediation efficiency can be improved, and compared with leaching remediation, the method has the advantage that the steps of excavating, stirring, separating and the like can be omitted. The invention provides the remediation method. The remediation method has the advantages of being short in time, low in cost and high in efficiency and having a wide application prospect in the field of remediation of a large-scale farmland contaminated by the heavy metals.
Owner:NANJING UNIV

Preparation method of nano-composite catalyst titanium dioxide pseudo-boehmite

The invention discloses a preparation method of a nano-composite catalyst titanium dioxide pseudo-boehmite. The preparation method comprises the following steps of a, adding TiO2 into anhydrous ethanol, b, adding aluminum tri-sec-butoxide into the solution and carrying out stirring to obtain a mixed solution I, c, carrying out heating stirring to obtain a mixed solution II in a gel form, d, adding deionized water into the mixed solution II, and carrying out aging to obtain a mixed solution III, e, carrying out pumping filtration of the mixed solution III by a pumping filtration device to obtain a mixed solution IV, f, flushing the mixed solution IV by acetone several times to obtain a sample, and g, drying the sample to obtain the nano-composite catalyst titanium dioxide pseudo-boehmite. The preparation method utilizes gamma-AlOOH as a carrier, modified TiO2 as a catalyst and aluminum tri-sec-butoxide as an aluminum source to prepare the nano-composite catalyst titanium dioxide pseudo-boehmite by a one-step method. The nano-composite catalyst titanium dioxide pseudo-boehmite has strong adsorption and photocatalysis performances, good response to ultraviolet light and stable performances and can effectively treat water pollutants such as methyl orange.
Owner:UNIV OF SHANGHAI FOR SCI & TECH

Method for preparing Fe2O3/Ti-mesoporous composite material (MCM)-41

The invention discloses a method for preparing a Fe2O3 / Ti-MCM-41 mesoporous composite material. In the method, ordered MCM-41 is used as a carrier, TiO2 is used as a catalyst and is modified by being doped with iron, the iron source is ferric sulfate, the ordered MCM-41 is synthesized by a hydrothermal process, metal titanium atoms are introduced in a framework forming process, and the molar ratio of elements, namely TiO2, SiO2 and cetyltrimethyl ammonium bromide (CTAB), in precursor solution is 0.02:1:0.2. The preparation method comprises the following preparation steps: adding 100 to 200-mesh silica gel into 1.5 mol / l solution of sodium hydroxide, and violently stirring at a constant speed; adding CTAB solution at a mass percentage concentration of 10 percent into the solution of sodium hydroxide, and violently stirring at a constant speed; adding tetrabutyl titanate into the mixed solution and violently stirring at a constant speed; adding ferric sulfate into the mixed solution and violently stirring at a constant speed; regulating the pH value to 11.5 with 2mol / l HCl regulating solution, and performing a crystallization reaction at 100 DEG C; washing a sample till the sample is neutral and drying in an oven at 100 DEG C; and taking the product out and baking in a muffle furnace at 300 DEG C. The obtained Fe2O3 / Ti-MCM-41 mesoporous composite material has high absorption and photocatalytic performance, high response to sun light and stable performance and can effectively treat a formaldehyde indoor air pollutant.
Owner:UNIV OF SHANGHAI FOR SCI & TECH

A kind of metacarb three-signal sensing material and its preparation method and application

The invention discloses a meta-tolyl-N-methylcarbamate ternary signal sensing material as well as a preparation method and application thereof, and belongs to the field of pesticide detection. The ternary signal sensing material adopts a dinaphthyl calix[4]arene modified gold interface, and is prepared by the method which comprises the following steps: using calix[4]arene as a raw material to be reacted with propargyl bromide and 1,2-dibromobutane respectively under the action of potassium carbonate and sodium hydride, and enabling the obtained product to be reacted with alpha-naphthol to obtain dinaphthyl calix[4]arene; modifying a gold material with an azide group, and then using a click chemistry method to modify the gold material with dinaphthyl calix[4]arene, so as to obtain the dinaphthyl calix[4]arene modified gold interface. Meta-tolyl-N-methylcarbamate can be detected by a fluorescent spectrometry with dinaphthyl calix[4]arene and can further be detected by an electrochemical impedance method and a contact angle method with the dinaphthyl calix[4]arene modified gold interface. Meta-tolyl-N-methylcarbamate is recognized by ternary signal output; the meta-tolyl-N-methylcarbamate ternary signal sensing material is reliable in result, high in sensitivity, reusable, and wide in application prospect in recognition and detection of pesticides.
Owner:HUAZHONG NORMAL UNIV

Preparation method of nano-composite catalyst titanium dioxide pseudo-boehmite

The invention discloses a preparation method of a nano-composite catalyst titanium dioxide pseudo-boehmite. The preparation method comprises the following steps of a, adding TiO2 into anhydrous ethanol, b, adding aluminum tri-sec-butoxide into the solution and carrying out stirring to obtain a mixed solution I, c, carrying out heating stirring to obtain a mixed solution II in a gel form, d, adding deionized water into the mixed solution II, and carrying out aging to obtain a mixed solution III, e, carrying out pumping filtration of the mixed solution III by a pumping filtration device to obtain a mixed solution IV, f, flushing the mixed solution IV by acetone several times to obtain a sample, and g, drying the sample to obtain the nano-composite catalyst titanium dioxide pseudo-boehmite. The preparation method utilizes gamma-AlOOH as a carrier, modified TiO2 as a catalyst and aluminum tri-sec-butoxide as an aluminum source to prepare the nano-composite catalyst titanium dioxide pseudo-boehmite by a one-step method. The nano-composite catalyst titanium dioxide pseudo-boehmite has strong adsorption and photocatalysis performances, good response to ultraviolet light and stable performances and can effectively treat water pollutants such as methyl orange.
Owner:UNIV OF SHANGHAI FOR SCI & TECH
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