59results about How to "Small rolling angle" patented technology

The invention relates to a super-hydrophobic polyurethane/ oxide nano particle hybrid coating and a preparation method thereof. The super-hydrophobic coating is prepared by oxide nano particles, silane coupling agent and polyurethane which have wide material source and are easily obtained through a self-assembly method, and has the contact angle of 140-168 degrees and the rolling angle of 1-20 degrees as well as good visible light permeability. The invention solves the problems that the currently prepared transparent super-hydrophobic coating needs extremely low surface energy perfluorinated silane modification, has high production cost and complicated technique, and can not realize large-scale production. The method has simple technique, easily obtained raw material and low cost; and theprepared super-hydrophobic coating can be taken as a dustproof and antifogging protective coating of the surface of solids such as glass and the like, and a waterproof insulating layer used in a micro-electronic device, a sensor and the like.

The invention relates to a self-cleaning microwave absorption paint and uses thereof. According to the invention, a urethane foam pyramidal material is coated with a layer of paint to form a micron-nano composite structure layer which has an angle of contact larger than 150 degrees and an angle of roll smaller than 5 degrees. The paint consists of a nano material, a micrometer material, a coupling agent, bonding resin, a base material, a curing agent, an auxiliary and an organic solvent. By means of the microwave absorption paint provided by the invention under a fireproof spraying mode, water beads can roll off a pyramidal surface rapidly with ashes contained in the water beads, thus achieving the effect of self cleaning, reducing the ashes in a microwave darkroom and accordingly meeting the special requirement of a cleaning-type dark room on maintaining high long-term cleanness. The self-cleaning microwave absorption paint provides a new way for implementing the cleaning-type dark room.

The invention provides a resin matrix composite with a super-hydrophobic bionic surface and a preparation method of the resin matrix composite. The method comprises steps as follows: the surface of a matrix of the resin matrix composite is polished until the surface turns white; the matrix of the resin matrix composite is processed through ultrafast laser, and a microstructure is formed on the surface; a first coating is sprayed on the microstructure surface of the matrix of the resin matrix composite through a pneumatic type paint spray gun to form a bonding layer, a second coating containing nanosilicon dioxide particles is sprayed to form a surface hydrophobic function layer, and the resin matrix composite with the super-hydrophobic bionic surface is obtained. The preparation method is simple to operate and facilitates production, the prepared resin matrix composite with the super-hydrophobic bionic surface can allow water drops to freely slip off, and the real self-cleaning super-hydrophobic function is realized.

The invention provides a superhydrophobic coating prepared from particles with ultrahigh roughness. The superhydrophobic coating is prepared from the following components: particles with protrusions or holes and unsmooth structures, protective particles, a bonding agent and an assistant, wherein the volume ratio of the particles with the protrusions or the holes and the unsmooth structures to the protective particles to the bonding agent is (0.1-7):(1-7):(1-10). A lotus effect technical theory is applied to obtain a super-hydrophobic, underwater superhydrophobic oil or super-amphiphobic surface coating, further the performance of the coating is improved, and the defects of the conventional superhydrophobic coating that the structure is easy to damage, the service life is short and the like are overcome. The prepared coating has super hydrophobic properties (super-hydrophobic, underwater superhydrophobic oil or super-amphiphobic properties), self-cleanness and excellent wear resistance; substrate materials suitable for the coating are glass, plastic, rubber, textiles, paper, metal, cement, ceramic materials or the materials covering other coatings.

The invention discloses a preparation method of a rubber-based composite material with the super-hydrophobic surface. The preparation method comprises the following steps: firstly placing an aluminum sheet into chemical corrosive liquid to corrode for 2-120 minutes, washing the corroded aluminum sheet by deionized water, drying for standby; placing a mixed rubber compound onto the corroded aluminum sheet, then using a press vulcanizer to vulcanize or tablet the sheet; separating the cooled aluminum sheet from the rubber; brush coating an ethanol solution of a low surface energy substance on the rough surface of the separated rubber-based composite material, taking reaction for 1-36 hours at the temperature of 40-200 DEG C, and at last obtaining the rubber-based composite material with the micro-nano coarse structure super-hydrophobic surface. The surface water contact angle of the super-hydrophobic rubber-based composite material is more than 150 degrees; the rolling angle is smaller than 8 degrees; the super-hydrophobic rubber-based composite material has excellent comprehensive properties such as high elasticity, high abrasion resistance and high strength, is simple in preparation technology and beneficial to large-scale production and application.

The invention provides a method for preparing a super hydrophobic film on the surface of a zinc substrate, which belongs to the technical field of a functional material. The method comprises the following steps of: ultrasonically washing a zinc sheet substrate, blow-drying by nitrogen gas, oxidizing by formamide water solution, and forming a rod-like nanometer zinc oxide array on the surface of a zinc sheet; and modifying by low surface energy substances, namely, stearic acid, 12-hydroxystearic acid and normal dodecyl mercaptan, and forming the super hydrophobic film with high static contact angle and low roll angle on the surface of the zinc sheet substrate. The super hydrophobic film may not be changed after being placed in the air for long time due to better stability and can be used for preventing water, resisting frost, preventing snow and resisting metal corrosion due to better acid and alkali resistance.

The invention discloses graphene oxide/copper silicate composite powder, a preparation method of the composite powder and application thereof in a super-hydrophobic coating. The graphene oxide/copper silicate composite powder with a micro-nano structure on the surface comprises a core formed by flake graphene oxide and a shell layer formed by needle-like nano copper silicate, wherein the needle-like nano copper silicate is arranged on the surface of the core in an array form. The super-hydrophobic coating is prepared by the following steps: coating the surface of a base material with the graphene oxide/copper silicate composite powder with the micro-nano structure on the surface, drying, and performing fluoroalkyl silane low-surface energy treatment, thereby obtaining the product. The preparation method disclosed by the invention is mild in reaction conditions, easy to realize and excellent in process repeatability; the prepared high-transparency, self-cleaning and anticorrosive super-hydrophobic coating has a static water drop contact angle of not less than 150 degrees; the slide angle does not exceed 1 degree; and the light transmissivity is not lower than 90% in a visible-ultraviolet light wave range. The product has excellent corrosion resistance and is expected to be widely applied to the fields of automobiles, spaceflight, solar cells, articles of daily use and the like.

The invention discloses a cone-shaped Janus particle and its preparation method and application. The underside material of the cone-shaped Janus particle is a hydrophobic polymer and is formed by polymerization of monoolefine monomer; and the side material of the particle is a hydrophilic material and is formed by sulfonation hydrophilic modification of a hydrophobic polymer or formed by hydrophobic polymer surface grafting with a hydrophilic polymer. The side face of the cone-shaped Janus particle can also undergo hydrophobic modification and the bottom surface undergoes amino-modification. The cone-shaped Janus particle can be used in particle emulsifiers, and also can be used in preparing a surface coating of a material, especially a hydrophobic surface coating.

The invention belongs to the field of preparation of micro or/and nano-structures on surfaces of solids and specifically relates to a copper-based super-hydrophobic composite film with a low friction coefficient and a preparation method thereof. The copper-based super-hydrophobic composite film with the low friction coefficient is characterized in that a composite structure with a micro-scale cuprous oxide crystal structure and submicro-scale metal silver particles is firstly formed on the surface of a copper-based material, and then surface chemical modification is performed to obtain a product. Each contact angle between the copper-based super-hydrophobic composite film with the low friction coefficient and water exceeds 150 degrees, the friction coefficient is low (can be as low as about 0.1) and can be stably kept, and the copper-based super-hydrophobic composite film has good super-hydrophobic performance and relatively low friction coefficient.

The invention relates to a method for simultaneously preparing two types of super-hydrophobic films by utilizing copper chloride, relating to a method for preparing a myristic acid copper film of a micrometer/nanometer structure and a myristic acid film inlaid with copper grains. The method is technically characterized by comprising the following steps of: dispersing the copper chloride and myristic acid powder into absolute ethyl alcohol to form uniform electrolyte; and electrolyzing two copper sheets under certain direct voltages in certain time by taking two copper sheets of 60 mm*25 mm*1.5 mm as electrodes so as to form different myristic acid copper films of the micrometer/nanometer structures on an anode and a cathode. The super-hydrophobic films are simultaneously prepared on the anode and the cathode for the first time by using the simple method; and in addition, the super-hydrophobic films have good super-hydrophobic property and extensive application prospect.

The invention relates to the technical field of material surface engineering, in particular to a super-hydrophobic anti-fouling anti-icing water-based paint which comprises the following components in parts by weight: 10-15 parts of fluoride-grafted nano silicon dioxide on the surface, 40-60 parts of perfluorodecyltrimethoxysilane, 10-20 parts of carbon microspheres, 5-8 parts of modified graphene, 30-40 parts of binder and 100-150 parts of solvent. According to the super-hydrophobic anti-fouling anti-icing water-based paint, the super-hydrophobic material and the near-infrared photothermal material are added, so that the super-hydrophobic anti-fouling anti-icing water-based paint has the dual effects of super-hydrophobicity and photothermal deicing, and the near-infrared photothermal material is modified graphene which is a compound of graphene and CdS; and the super-hydrophobic material is very beneficial to formation of a rough micro-nano structure on the surface of the coating, so that the coating can obtain a larger static contact angle and a smaller rolling angle, the icing time of water drops on the surface of the coating is further prolonged, and a better anti-icing effect is achieved.

The invention discloses a method for enhancing surface wettability of a hexagonal-prism-structure nano zinc oxide material, relating to a method for lowering surface energy of zinc oxide. The surface contact angle and roll angle of the fluorizated hexagonal-prism-structure nano zinc oxide are enhanced, and the Cu2O/ZnO composite material can enhance the photoelectric conversion efficiency. The method adopts an electrochemical deposition process and comprises the following steps: by using copper sulfate, lactic acid and sodium hydroxide as raw materials, adding cationic and nonionic surfactants; in a two-electrode system, by using graphite as an anode and an ITO (indium tin oxide) glass sheet deposited with hexagonal-prism-structure zinc oxide structure as a cathode, carrying out cathode reduction while controlling the deposition voltage, time and temperature to deposit granular cuprous oxide on the hexagonal-prism-structure zinc oxide, sintering at certain temperature, treating with a low-surface-energy substance, and measuring the surface static contact angle. The method has the advantages of low production cost, simple preparation process, low requirements for reaction equipment, mild reaction conditions and no environmental pollution, and can large-scale production.

The invention provides a silver nanowire-polyperfluorinated ethylene propylene super-hydrophobic porous membrane and a preparation method. The method comprises the following steps: first, preparing acellular polystyrene porous membrane according to a breath figure method, and performing reverse repeated etching by taking the polystyrene porous membrane as a template to produce a polyperfluorinated ethylene porous membrane with micro-nanograde bulge array, and further depositing a layer of etching silver nanowire orientation film on the surface of the polyperfluorinated ethylene porous membrane, thereby producing the silver nanowire-polyperfluorinated ethylene propylene super-hydrophobic porous membrane. Compared with the traditional method, the super-hydrophobic porous membrane prepared according to the method of the invention is not only large in water contact angle, small in rolling angle, and strong in super-hydrophobic capacity and self-cleaning ability, but also has high antibacterial capability; the preparation method is simple, the membrane pore structure can be dynamically controlled or regulated, and the pollution cannot be produced.

The invention relates to a method for preparing two types of super-hydrophobic membranes simultaneously by utilizing nickel chloride, in particular to a method for preparing a copper myristate membrane with a micro/nano-structure at an anode and a myristic acid membrane embedded with nickel particles at a cathode simultaneously. The method is technically characterized in that: the nickel chloride and myristic acid powder are dispersed in absolute ethanol to form uniform electrolyte, and two copper sheets with 60mm*25mm*1.5mm are taken as electrodes and are electrolyzed under certain direct-current voltage for a certain period of time, so that the copper myristate membrane with the micro/nano-structure is formed at the anode and the myristic acid membrane embedded with the nickel particles is formed at the cathode. The invention provides a simple method for preparing super-hydrophobic membranes at the anode and the cathode simultaneously for the first time; and the super-hydrophobic membranes have good super-hydrophobic performance and have wide application prospect.

The invention discloses a glass self-cleaning liquid and self-cleaning glass and a preparation method thereof. The glass self-cleaning liquid comprises the following ingredients (by weight): 100-300 parts of SiO2 sol, 1-5 parts of ethyl orthosilicate, 1-10 parts of ammonia water, 50-300 parts of polyethylene glycol, 10-50 parts of n-butanol, 0.1-0.5 part of PVPK30, 0.5-2.0 parts of Dipropylene glycol mono butyl ether, and 10-50 parts of water glass. The self-cleaning glass prepared by the use of the self-cleaning liquid has a good self-cleaning effect and also has good weatherability and lighttransmittance. In addition, usability of the glass is enhanced.

The invention discloses a composite material with a self-cleaning function, which is prepared from the following raw materials in parts by weight: 20-30 parts of epoxy resin, 25-40 parts of thermoplastic resin, 10-15 parts of polydimethylsiloxane, 8-14 parts of polytetrafluoroethylene, 6-12 parts of a heat stabilizer, 4-8 parts of a curing agent, 6-10 parts of silane, 8-16 parts of a coupling agent, 10-16 parts of a lubricant, 10-20 parts of a processing aid and 6-12 parts of a flame retardant. The invention relates to the technical field of new materials. According to the composite material with a self-cleaning function, through the composite material with a super-hydrophobic function, condensed water drops can be quickly collected and flow away and cannot be adhered to the surface of the composite material, so that the adhesion of dust is greatly reduced, the contact angle between the surface of the composite material and water is greatly increased, the rolling angle is reduced, the water drops can freely slide on the composite material, a self-cleaning super-hydrophobic function is achieved in real sense, the the composite material can be applied to resin-based composite materials in the fields of life, industry, military affairs and the like, and the implementation process is simple and high in controllability and engineering application feasibility.

The invention discloses a preparation process of a fluorine-free superhydrophobic surface. The process comprises the following steps: putting metal aluminum into a hydrochloric acid solution of copperchloride, performing a reaction to obtain a sample having a rough structure, uniformly coating the sample by using a prepared rosin ethanol solution, and performing drying to obtain a sample having ahigh contact angle and a small rolling angle with water. According to the process provided by the invention, the fluorine-free low-price environmentally-friendly superhydrophobic surface can be easily prepared on the metal aluminum by chemical corrosion and rosin coating methods, and the process is simple and easy to operate; a rosin coating is used to replace a traditional modified fluoride molecular layer, so that the mechanical stability of the superhydrophobic surface is greatly improved, and the production costs are reduced; and the prepared superhydrophobic surface has the characteristics of self cleaning, icing resistance and drag reduction.