The invention discloses 
graphene oxide / 
copper silicate composite 
powder, a preparation method of the composite 
powder and application thereof in a super-hydrophobic 
coating. The 
graphene oxide / 
copper silicate composite 
powder with a micro-nano structure on the surface comprises a core formed by flake 
graphene oxide and a shell layer formed by needle-like 
nano copper silicate, wherein the needle-like 
nano copper silicate is arranged on the surface of the core in an array form. The super-hydrophobic 
coating is prepared by the following steps: 
coating the surface of a base material with the graphene oxide / 
copper silicate composite powder with the micro-nano structure on the surface, 
drying, and performing fluoroalkyl 
silane low-
surface energy treatment, thereby obtaining the product. The preparation method disclosed by the invention is mild in 
reaction conditions, easy to realize and excellent in process 
repeatability; the prepared high-transparency, self-cleaning and anticorrosive super-hydrophobic coating has a static water drop 
contact angle of not less than 150 degrees; the slide angle does not exceed 1 degree; and the light transmissivity is not lower than 90% in a visible-
ultraviolet light wave range. The product has excellent 
corrosion resistance and is expected to be widely applied to the fields of automobiles, 
spaceflight, solar cells, articles of daily use and the like.