The invention relates to the field of organic chemicals, aims to solve the problems that a solvent is used and the reaction yield is low in the synthesis process of vinyl tri(2,2,2-trifluoroethoxy) silane, and discloses a method for preparing the vinyl tri(2,2,2-trifluoroethoxy) silane. The method comprises the following steps: adding dropwise trifluoroethanol into vinyl trichlorosilane which is maintained to a certain temperature in advance, keeping the temperature to implement a reaction, increasing the temperature till refluxing, and maintaining the refluxing process; cooling the reaction material to the room temperature so as to obtain a crude synthesis produce, neutralizing the system by using an alkali neutralizer, performing filtering, and collecting filtrate; and transferring the collected filtrate into a rectification tower, and performing treatment, so as to obtain the vinyl tri(2,2,2-trifluoroethoxy) silane. The method is simple in operation condition, simple in step, free of extra solvent except raw materials for reactions, high in target product yield, easy in separation and purification, and very applicable to large-scale production.