215 results about "Formic anhydride" patented technology

The invention discloses unsaturated polyester resin for imitation jade handicrafts and a preparation method thereof, and belongs to the technical field of polyester resin. Comprising the following components: diethylene glycol, methylpropanediol, propylene glycol, maleic anhydride, phthalic anhydride, an antioxidant, a polymerization inhibitor, paraffin, a stabilizer, an ultraviolet light absorber, a whitening agent and a diluent. The weight ratio of the propylene glycol to the methyl propylene glycol is (1.0-1.3): 1, and the methyl propylene glycol accounts for 20-22% of the total amount of the dihydric alcohol; the weight ratio of maleic anhydride to phthalic anhydride is (0.46-0.52): 1; the preparation method comprises 1) adding the raw materials and the antioxidant into a reactor, carrying out heating, carrying out heat preservation for 0.5-1.0 h and continuing heating, 2) carrying out a reaction for 2-3 h after heating, carrying out dehydration until an acid value is 20-25 mgKOH / g, and 3) carrying out cooling, adding the auxiliary agent and carrying out uniform mixing so that the unsaturated polyester resin is obtained.

The invention relates to high-flexibility phenolic-aldehyde-free rosin modified resin, and belongs to the technical field of rosin resin. The raw materials comprise rosin, maleic anhydride, phthalic anhydride, pentaerythritol, glycerol, an acrylate monomer and magnesium oxide. The preparation process comprises four key reactions: (1) rosin and maleic anhydride are subjected to a Diels-Alder reaction to construct a rigid skeleton; (2) introducing phthalic anhydride to form a compact cross-linked network; (3) carrying out composite esterification on pentaerythritol and glycerol; and (4) the interface binding energy is improved by regulating and controlling the in-situ RAFT polymerization of the acrylate monomer. The resin does not contain phenolic aldehyde components, VOCs emission is smaller than 50 g / L, free formaldehyde is not detected, and the resin has high flexibility, heat resistance and excellent chemical resistance.

The invention provides a photoacid generator, a preparation method thereof and a photoresist based on the photoacid generator. The photoacid generator is 4-alkyl-N-hydroxyl naphthalimide fluoroalkyl sulfonate, and the molecular structural formula of the photoacid generator is # imgabs 0 #, and in the formula, R is alkyl. The preparation method of the photoacid generator comprises the following steps: S1, dissolving 5-alkyl acenaphthene in a first solvent, heating, adding potassium permanganate in the heating process, then heating to reflux for reaction, and after the reaction is finished, purifying to obtain 4-alkyl-1, 8-naphthalic anhydride; s2, dissolving the 4-alkyl-1, 8-naphthalic anhydride, hydroxylamine hydrochloride and a first inorganic base in a second solvent for reaction, and after the reaction is finished, purifying to obtain 4-alkyl-N-hydroxy-1, 8-naphthalic imide; and S3, adding the 4-alkyl-N-hydroxy-1, 8-naphthalimide and an organic alkali into a third solvent, dropwise adding fluoroalkyl sulfonic anhydride, heating to react after dropwise adding is completed, and purifying after the reaction is completed to obtain the 4-alkyl-N-hydroxy-1, 8-naphthalimide. The photoresist based on the photoacid generator provided by the invention is large in ADR, and the negative photoresist development defect and the standing wave are improved.

The invention discloses a copper (II) coordination type naphthalimide fluorescent probe and a preparation method and application thereof in pasture detection, and relates to the field of fluorescent probes, the preparation method of the fluorescent probe comprises the following steps: (1) preparation of an intermediate a: preparing the intermediate a by using 2-bromo-1, 8-naphthalic anhydride; (2) preparing an intermediate b: preparing the intermediate b by using the intermediate a; (3) preparing an intermediate c: preparing the intermediate c by using the intermediate b; (4) preparing Nap2: preparing Nap2 by using the intermediate c; the raw materials for preparing the Nap2 are easy to obtain, the synthesis steps are simple, the operation is simple and convenient, and the Nap2 has high application value in the field of rapid detection of pasture copper pollution.

The invention discloses lighting resin as well as a preparation method and application thereof, and belongs to the technical field of lighting type unsaturated polyester resin. Comprising the following components: ethylene glycol, benzoic acid, phthalic anhydride, maleic anhydride, an antioxidant, a defoaming agent, a surfactant, a stabilizer, styrene, a solvent, a first polymerization inhibitor, a second polymerization inhibitor and a third polymerization inhibitor. The alcohol-acid ratio is (1.03-1.13): 1; the molar ratio of unsaturated acid to saturated acid is (2.5-3.5): 1; the mass ratio of benzoic acid to the surfactant is (26.8-44): 1; the preparation method comprises the following steps: 1) reacting ethylene glycol, maleic anhydride, phthalic anhydride, benzoic acid, an antioxidant and a first polymerization inhibitor; the preparation method comprises the following steps of (1) adding a first polymerization inhibitor, (2) heating and preserving heat after the reaction is completed, and (3) cooling, adding a second polymerization inhibitor, cooling, adding a third polymerization inhibitor, a cross-linking agent, a surfactant and a defoaming agent, and adding a solvent to obtain the daylighting resin.According to the preparation method, the surfactant and benzoic acid have a synergistic effect, so that the compatibility of polyester and the cross-linking agent is improved.

The invention relates to rosin modified resin and a preparation process thereof and low-odor printing ink, the rosin modified resin is prepared from maleic anhydride, sulfonate alkyd resin, rosin and a metal organic framework, and the sulfonate alkyd resin is prepared from neopentyl glycol, dibutyltin dilaurate, m-phthalic acid-5-sodium sulfonate, phthalic anhydride and pentaerythritol. The printing ink has the effect of improving the strength and smell of the printing ink.

The invention provides hyperbranched polyhydroxy polyester resin as well as a preparation method and application thereof in preparation of an acrylic resin coating, and relates to the technical field of polymer coating compositions. According to the hyperbranched polyhydroxy polyester resin, pentaerythritol is adopted as a core, succinic anhydride, tetramethyl cyclobutanediol and trimellitic anhydride are sequentially connected to a hyperbranched molecular structure in a comonomer form through a continuous esterification reaction method, and the hyperbranched polyhydroxy polyester resin is prepared. In the preparation process of the hyperbranched polyhydroxy polyester resin, the reaction process can be controlled only through an acid value, meanwhile, polyester with a hyperbranched structure is synthesized by adopting a one-pot method, and the hyperbranched polyhydroxy polyester resin has the technical advantages that the synthetic resin step is simple, and a separation process is not needed. The hyperbranched polyhydroxy polyester resin can be widely applied to the preparation process of an acrylic resin coating.

The invention discloses high-strength corrosion-resistant unsaturated polyester resin and a preparation method thereof, and belongs to the technical field of unsaturated polyester resin. The high-strength corrosion-resistant unsaturated polyester resin is prepared from the following components in percentage by mass: 4 to 5 percent of isophthalic acid, 6.5 to 8 percent of terephthalic acid, 7.5 to 8.4 percent of phthalic anhydride, 18 to 18.5 percent of maleic anhydride, 19 to 20 percent of diethylene glycol, 0.007 to 0.015 percent of a catalyst, 0.02 to 0.03 percent of an antioxidant, 9.5 to 10.5 percent of propylene glycol, 0.018 to 0.025 percent of a polymerization inhibitor, 0.015 to 0.03 percent of paraffin and 31.7 to 32.94 percent of a cross-linking agent. The mass ratio of the terephthalic acid to the isophthalic acid is (1.3-2.0): 1, and the mass ratio of the phthalic anhydride to the isophthalic acid is (1.6-2.05): 1. By optimizing the proportion of the binary acid and adding a proper amount of phthalic anhydride, the crystallinity problem of the terephthalic unsaturated resin can be improved, and the compatibility of the resin to a cross-linking agent is improved; the prepared high-strength corrosion-resistant unsaturated polyester resin has the advantages of high strength, high thermal deformation temperature, high water resistance and high corrosion resistance.

The invention relates to the field of materials, and provides an adhesive as well as a preparation method and application thereof, and the adhesive comprises the following components in parts by weight: 100-150 parts of maleimide resin; 60 to 100 parts of epoxidized polybutadiene; 10 to 30 parts of fluorine-containing anhydride; 15 to 30 parts of a cross-linking agent; 0.5 to 1 part of an initiator; 300 to 460 parts of a filler; and 375-580 parts of a solvent. The fluorine-containing anhydride is one or a mixture of more than two of hexafluoroglutaric anhydride, tetrafluorophthalic anhydride and hexafluoroisopropyl phthalic anhydride. The adhesive has the advantages that a laminated board prepared from the adhesive has uniform appearance and a series of excellent comprehensive properties such as excellent dielectric property, mechanical property, heat resistance and processability, can meet the strict requirements of the laminated board as a semiconductor packaging substrate material in the aspects of application and processing, and is applied to the field of high-frequency high-speed communication.

The invention discloses a cellulose acetate based 1, 8-naphthalimide fluorescent probe for detecting Hg < 2 + > as well as a preparation method and application of the cellulose acetate based 1, 8-naphthalimide fluorescent probe. The preparation method comprises the following steps: by taking 4-bromo-1, 8-naphthalic anhydride as a raw material, carrying out condensation reaction on the 4-bromo-1, 8-naphthalic anhydride and 4-aminobutyric acid to prepare 4-(4-bromo-1, 8-naphthalic diimide) butyric acid (BNA-B); the BNA-B and piperazine are subjected to a substitution reaction, and a compound PNA-B is prepared; the PNA-B and 4-(bromomethyl) pyridine hydrochloride are subjected to a substitution reaction, and a compound PNA-B is prepared; and the PNA-B and cellulose acetate (CA) are subjected to an esterification reaction, such that the cellulose acetate-based 1, 8-naphthalimide fluorescent probe PNA-CA is prepared. The compound can specifically recognize Hg < 2 + >, after Hg < 2 + > is added into a PNA-CA acetonitrile / PBS buffer solution under 365nm ultraviolet irradiation, the fluorescence color of the solution is changed from colorless to yellow, the response time is 20s, the detection limit reaches 9.3 * 10 <-8 > M, and the probe has a good application prospect.

This invention discloses a cellulose acetate-based 1,8-naphthalenedimide fluorescent probe for detecting hydrazine, its preparation method, and its application. The invention uses 4-bromo-1,8-naphthalenedimide as a raw material, which undergoes a condensation reaction with 4-aminobutyric acid to obtain 4-(4-bromo-1,8-naphthalenedimide)butyric acid (BNA-B); BNA-B undergoes a coupling reaction with 4-formylphenylboronic acid to obtain 4-(4-(4-formylphenyl)-1,8-naphthalenedimide)butyric acid (FNA-B); compound FNA-B then undergoes an esterification reaction with cellulose acetate (CA) to obtain the cellulose acetate-based 1,8-naphthalenedimide fluorescent probe FNA-B-CA. This compound specifically recognizes hydrazine. Under 365 nm ultraviolet light irradiation, the addition of hydrazine to a DMF / H2O solution of FNA-B-CA changes the fluorescence color of the solution from bright blue to colorless, indicating a detection limit of 8.4 × 10⁻⁶ for hydrazine. ‑8 M has promising applications as a fluorescent probe for the detection of hydrazine.

The invention discloses a cellulose acetate based 1, 8-naphthalimide fluorescent probe for detecting hydrazine as well as a preparation method and application of the cellulose acetate based 1, 8-naphthalimide fluorescent probe. The preparation method comprises the following steps: by taking 4-bromo-1, 8-naphthalic anhydride as a raw material, carrying out condensation reaction on the 4-bromo-1, 8-naphthalic anhydride and 4-aminobutyric acid to prepare 4-(4-bromo-1, 8-naphthalic diimide) butyric acid (BNA-B); the preparation method comprises the following steps: carrying out a coupling reaction on BNA-B and 4-formyl phenylboronic acid to prepare 4-(4-(4-formyl phenyl)-1, 8-naphthalimidoyl) butyric acid (FNA-B); and the compound FNA-B and cellulose acetate (CA) are subjected to an esterification reaction, such that the cellulose acetate-based 1, 8-naphthalimide fluorescent probe FNA-B-CA is prepared. The compound can specifically recognize hydrazine, after hydrazine is added into a DMF / H2O solution of FNA-B-CA under the irradiation of 365nm ultraviolet light, the fluorescence color of the solution is changed from bright blue to colorless, the detection limit of hydrazine reaches 8.4 * 10 <-8 > M, and the compound has a good application prospect as a fluorescent probe for detecting hydrazine.

The present invention provides a production process for preparing biomass-based hard carbon precursor materials by a hydrothermal method. The following steps are included: S1, using biomass raw materials and water for batching to obtain slurry; S2, adding an auxiliary agent to the slurry, performing a hydrothermal reaction, setting the hydrothermal reaction temperature to 80-350°C, and stirring at a constant temperature for 1-24 hours to obtain a slurry after the reaction, wherein the auxiliary agent is a mixture of methacrylate, acrylonitrile and pyromellitic anhydride in a mass ratio of 1:0-4.5:0.05-2.5; S3, the slurry is separated into a liquid phase and a solid phase, wherein the solid phase is a crude product, the liquid phase is a mother liquor, and the crude product enters the next process; S4, washing, drying and crushing the crude product to form a carbon hard precursor material. The biomass-based hard carbon precursor material produced by the invention has an adjustable particle size, a narrow particle size distribution range, good uniformity, and low ash content.

The invention discloses a sewage treatment membrane and a preparation method thereof, and relates to the field of sewage treatment. When the sewage treatment membrane is prepared, porous nano titanium dioxide, 3, 5-diaminopyrazole and benzo [1, 2-B: 3, 4-B ': 5, 6-B'] trithiophene-2, 5, 8-trialdehyde are uniformly mixed to prepare modified nano titanium dioxide; the preparation method comprises the following steps: reacting 1, 3, 5, 7-tetramethylcyclotetrasiloxane, 1, 3-bis (3-aminopropyl) tetramethyldisiloxane, 2-vinyl imidazole and 1-allylhydantoin to prepare functionalized amino siloxane; and uniformly mixing p-phenylenediamine, functionalized amino siloxane, pyromellitic dianhydride, modified nano titanium dioxide and zinc nitrate hexahydrate, and treating with a sodium hypochlorite solution to obtain the sewage treatment membrane. The sewage treatment membrane prepared by the invention has excellent heavy metal ion complexing property, antibacterial property and photocatalytic degradability.

The invention discloses tetraisononyl pyromellitate as well as a preparation method and application thereof. The tetraisononyl pyromellitate is obtained by carrying out esterification reaction on pyromellitic acid or pyromellitic anhydride and isononyl alcohol under the action of a catalyst. The raw materials used in the synthesis process of the tetraisononyl pyromellitic acid are safe, the cost is low, the synthesis procedures and steps are simple, and the synthesis method is suitable for industrial processing and production. The trioctyl trimellitate plasticizer can be used as one of substitutes of the trioctyl trimellitate TOTM plasticizer, and even is a better improved product.

The invention relates to the field of rubber, in particular to toughened modified nitrile rubber and a preparation method thereof.Magnesium hydroxide is selected as a flame retardant, nano molybdenum oxide hybridized magnesium hydroxide is prepared with a hydrothermal method and epoxidized with gamma-(2, 3-epoxypropoxy) propyltrimethoxysilane, then epoxy-amino reaction is utilized, and the toughened modified nitrile rubber is obtained. Grafting a vanillin-based phosphorus-nitrogen synergistic flame retardant; the vanillin-based phosphorus-nitrogen synergistic flame retardant is prepared by taking bio-based vanillin as a raw material, firstly synthesizing a phosphorus-containing dialdehyde intermediate serving as a precursor from the bio-based vanillin and phenylphosphonic dichloride, then carrying out condensation reaction on the phosphorus-containing dialdehyde intermediate and cyclic imidization melamine, and then carrying out addition with DOPO (9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide), and the cyclic imidization melamine is prepared from melamine and 1, 2-cyclohexanedicarboxylic anhydride. Cellulose nanocrystals are selected to reinforce and toughen nitrile rubber, a sodium periodate oxidation method is adopted to prepare dihydroformylated cellulose nanocrystals, and then aldehyde group-amino reaction is utilized to graft a vanillin-based phosphorus-nitrogen synergistic flame retardant.

The invention discloses a 4-BrPA / beta-CD supramolecular photosensitizer as well as a preparation method and application thereof, and belongs to the field of biomedical materials. According to the method, beta-cyclodextrin is used as a subject, 4-bromophthalic anhydride is used as an object, and the water-soluble photosensitizer is constructed through a chemically modified supramolecular assembly strategy. The preparation method comprises the following specific steps: reacting beta-cyclodextrin with paratoluensulfonyl chloride to obtain mono-(6-O-paratoluensulfonyl)-beta-cyclodextrin; then carrying out a reaction with ethidene diamine to obtain mono-(6-ethidene diamine-6-deoxy)-beta-cyclodextrin; then reacting with 4-bromophthalic anhydride in N, N-dimethylformamide, and precipitating and purifying through ethyl acetate to obtain a crude product; and finally, carrying out ultrasonic treatment, centrifugal separation and freeze drying to obtain a pure product. The prepared 4-BrPA / beta-CD supramolecular photosensitizer is excellent in water solubility, has at least 7 excitation centers in a visible light region of 400-520 nm, correspondingly generates at least 7 emission centers in a range of 500-780 nm, has a maximum excitation wavelength of about 460 + / -10 nm and a maximum emission wavelength of about 620 + / -10 nm, has an extremely wide visible light response characteristic, and can be used for antibacterial photodynamic therapy.

The present application relates to photosensitive polyimide oligomer, preparation method and polyimide photosensitive resin composition prepared by the same, the present application provides the molecular formula of photosensitive polyimide oligomer, which is prepared from 1, 4, 5, 8-naphthalene tetracarboxylic anhydride, N, N-dimethylacetamide, triethylamine, tetramethyl benzene dimethyl diisocyanate, hydroquinone methyl ether, dibutyl tin dilaurate and hydroxyethyl acrylate according to the molar ratio of 2.5:10-15:1.2-1.6:3.0:0.0035-0.0045:0.007-0.01:2-2.5.The good solubility group is introduced into the molecular structure, so that it has good solubility in active diluent, and the polyimide oligomer can be photocured reaction;The device printed by the polyimide photosensitive resin composition prepared by the same has small shrinkage, high precision, and has the excellent performance of photosensitive polyimide oligomer, and has certain toughness and excellent weather resistance.

The application discloses an indoor moisture-proof and water-resistant gypsum board and a preparation method thereof, and belongs to the technical field of gypsum board preparation. The preparation method of the indoor moisture-proof and water-resistant gypsum board comprises the following steps: S1, uniformly mixing building gypsum, modified fluorite gypsum, deionized water, a polyester adhesive, a composite water reducing agent, blast furnace slag powder and the like to obtain a gypsum slurry; S2, paving the gypsum slurry on a first layer of cover paper, paving a second layer of cover paper on the gypsum slurry, and performing compaction, final setting, drying and solidification to obtain the indoor moisture-proof and water-resistant gypsum board. The composite water reducing agent is obtained by the reaction of ethyl vinyl ether, trichlorofluoroethylene and allyltrimethoxysilane. The polyester adhesive is obtained by the reaction of allyl alcohol, phthalic anhydride and triallyl cyanurate. The prepared gypsum board not only has good moisture-proof and water-resistant performance, but also has good mechanical properties, thereby prolonging the service life and ensuring the quality of the gypsum board to a certain extent.

The application discloses a brazing flux capable of enhancing the radiation resistance of aluminum alloy brazing joints, and a preparation method and application thereof. The brazing flux is composed of 5-18% of an organic mixture and the balance of an inorganic mixture. The organic mixture is composed of 7-15% of EP-12 epoxy resin, 8-16% of EP-16 epoxy resin, 5-8% of F-51A high-temperature-resistant flame-retardant thermosetting phenolic resin, 5-8% of F-52A high-temperature-resistant flame-retardant thermosetting phenolic resin, 5-8% of resorcinol, 5-8% of hydroquinone and the balance of phthalic anhydride. The inorganic mixture is composed of 40-55% of CsF, 20-30% of AlF3, 0.005-0.01% of GaF3 and the balance of Al(OH)3. The brazing flux matches Zn-Al filler metal, can make the aluminum alloy brazing joint have good radiation resistance, and can significantly improve the shearing strength of the brazing joint.

The invention relates to the technical field of chemical preparation, and discloses a preparation method of a phthalimide compound, which comprises the following steps: S1, raw material mixing: sequentially adding phthalic anhydride, a primary amine compound, p-toluenesulfonic acid and phosphorus pentoxide into a reaction container with a stirring device and a temperature control module, and stirring for 1-2 hours; adding ethanol as a solvent, and carrying out a stirring reaction; s2, curing: cooling the reaction liquid to 20-25 DEG C, slowly adding deionized water into the reaction liquid while stirring, standing, and separating out a solid product; a traditional dehydrating agent is changed into a low-cost green dehydrating agent combination, so that the cost loss is reduced, the stimulation effect is reduced, the catalytic activity is equivalent to that of p-toluenesulfonic acid by adding a new sulfonic group functional polymer, but the problems of volatility of liquid acid and equipment corrosion are avoided, a low-toxicity and low-cost solvent of ethanol is added, the toxicity is reduced, and the environment-friendly dehydrating agent is prepared. The preparation is safer, the cost is lower, and the applicability is wider.

This invention relates to a taraxasterol nitrobenzoate derivative in the field of medicinal chemistry, with the following structural formula: Compound B is obtained by reacting taraxasterol 1 with 4-nitrophthalic anhydride in a suitable alkaline catalyst and organic solvent. This synthetic route offers high yield and is easy to implement. Activity tests demonstrate that the taraxasterol nitrobenzoate derivative shown as B, designed and synthesized in this invention, is a suitable antitumor drug candidate, particularly as a candidate drug for lung cancer.

This invention discloses a method for preparing a supported low-carbon hydrocarbon deodorization catalyst. The method includes: (1) preparing a catalyst containing M... 2+ and M' 3+ (1) Add molecular sieve to the solution and stir evenly; (2) React the obtained suspension with a mixed solution of NaOH and Na2CO3 or a weak alkaline solution under stirring; (3) Obtain the composite carrier by drying and calcination; (4) Prepare a cobalt salt solution and transfer Co to the cobalt salt solution by ion exchange. 2+ (5) After filtration and drying, Co molecular sieve solid alkali is obtained; (6) Co molecular sieve solid alkali, ammonium phthalate sulfonate, urea, ammonium molybdate, and phthalic anhydride are added in proportion and ground evenly; (7) The obtained material is heated under an inert atmosphere to react and obtain the catalyst product. In the catalyst prepared by this invention, sulfonated cobalt phthalocyanine is combined with molecular sieve through chemical bonds, the active component has a stronger binding force and a longer service life.

The present application belongs to the field of polymer materials, and particularly relates to a self-toughened epoxy resin with high temperature resistance and a preparation method thereof. The modifier is a multifunctional epoxy resin containing a polyetherimide structure. The modifier is dissolved and blended with a bisphenol A type epoxy resin. The curing agent comprises one or more of methyl nadic anhydride, methyl tetrahydrophthalic anhydride, methyl hexahydrophthalic anhydride, dodecenyl succinic anhydride and pyromellitic anhydride. The curing accelerator comprises one or more of dimethylaminomethylphenol, ortho-hydroxybenzyl dimethylamine, 2,4,6-tris(dimethylaminomethyl)phenol, triethylamine and triethanolamine. The multifunctional epoxy resin containing a polyetherimide structure not only has good solubility in the bisphenol A type epoxy resin, but also can participate in the curing reaction of the bisphenol A type epoxy resin, so that the toughness and temperature resistance of the bisphenol A type epoxy resin can be significantly improved.

The invention discloses an oil exploitation aid and a preparation method thereof, and relates to the technical field of oil exploitation aids. The oil exploitation aid comprises the following raw materials in parts by weight: 30-40 parts of a modified carboxylate surfactant, 15-20 parts of a nonionic surfactant, 5-6 parts of a cosolvent, 4-6 parts of a stabilizer, 3-5 parts of an anti-scaling agent and 140-160 parts of deionized water. The preparation method comprises the following steps: firstly, carrying out a ring-opening acylation reaction by taking n-hexylamine, 1, 8-naphthalic anhydride and 12-bromo-1-dodecene as raw materials, carrying out an alkylation reaction to obtain 1-(dodecyl-11-ene-1-yl (amyl) carbamoyl)-2-sodium naphthoate, then carrying out a reaction with a first-generation polymer prepared from urotropine and p-aminophenol, and carrying out a reaction to obtain the 1-(dodecyl-11-ene-1-yl (amyl) carbamoyl)-2-sodium naphthoate. Finally, the modified carboxylate type surfactant is obtained. The oil exploitation auxiliary agent prepared by the invention has the effects of changing the wettability of a rock core and preventing swelling of clay, and the recovery rate of oil displacement of a low-permeability reservoir is improved.

According to the synthesis method, methylbenzene is used as a solvent, benzoic anhydride is used as an acylation reagent, and on the premise that the synthesis efficiency and quality are guaranteed, the defects that in the prior art, when a reagent is used, safety risks exist, and the cost is high are effectively overcome. In the production process, special storage and operation conditions are not needed, the product quality is controllable, and the method is suitable for industrial production.

The invention discloses an isooctyl / isononyl / isodecyl pyromellitic acid plasticizer composition as well as a preparation method and application thereof, and the isooctyl / isononyl / isodecyl pyromellitic acid plasticizer composition is prepared from pyromellitic acid or pyromellitic anhydride, isooctyl alcohol (A), isononyl alcohol (B) and isodecyl alcohol (C) through esterification reaction, the molar ratio of the pyromellitic acid or the pyromellitic anhydride to the total alcohol is 1: (4-5); the molar ratio of the isooctyl alcohol (A) to the isononyl alcohol (B) to the isodecyl alcohol (C) is (0-5): (0-5): (0-5). The raw materials used in the synthesis process of the isooctyl / isononyl / isodecyl pyromellitic acid plasticizer composition are safe, the cost is low, the synthesis process is simple, and the isooctyl / isononyl / isodecyl pyromellitic acid plasticizer composition is suitable for industrial processing and production and has excellent heat resistance and low precipitation performance.

The invention discloses an ultrasonic sound absorption material, which comprises 20-50% of a polymer matrix, 20-50% of a curing agent, and 20-50% of a curing agent, wherein the polymer matrix comprises low-viscosity epoxy resin, a toughening modifier and a curing agent; the scattering absorption balls are made by wrapping rubber with spherical tungsten powder with the diameter smaller than 100 micrometers, the rubber accounts for 10%-30% of the weight of the tungsten powder, and the scattering absorption balls account for 38%-72% of the total weight; the thickness of the graphite flake is 0.05-1mm, and the graphite flake accounts for 8-12% of the total weight; the toughening modifier is one of liquid polysulfide and polyurethane; the curing agent is one of m-phenylenediamine, polyamide and phthalic anhydride; the preparation method has the beneficial effects that by optimizing the material composition and the preparation process, the preparation time is remarkably shortened, and the production efficiency is improved; due to unique material combination and structural design, the ultrasonic sound absorption material has better acoustic absorption and scattering performance; the device is suitable for the fields of ultrasonic probes, acoustics laboratories and noise control, and has wide market prospects.

The application belongs to the technical field of polymer synthesis, and provides a preparation method of a polyimide covalent organic framework.The application mixes anhydride compounds (one or more of the following: pyromellitic dianhydride, 1,4,5,8-naphthalene tetracarboxylic anhydride and 3,4,9,10-perylenetetracarboxylic dianhydride) and an alcohol solvent to perform pre-reaction to obtain a carboxylic esterate solution; disperses amino blocks (tris(4-aminophenyl)amine, 1,3,6,8-tetrakis(4-aminophenyl)pyrene, etc.) to obtain an amino block dispersion solution; mixes the amino block dispersion solution and the carboxylic esterate solution to perform reaction to obtain the polyimide covalent organic framework.The preparation method of the application can be performed under normal pressure, and the operation is safer; meanwhile, the preparation method of the application is not performed in a sealed tube, and can be used for mass production of the polyimide covalent organic framework.

The invention discloses a preparation method of a bumetanib injection, and belongs to the technical field of medicines. The method comprises the following steps: (1) preparing materials, namely respectively weighing bumetanib, xylitol, sodium dihydrogen phosphate dihydrate, disodium hydrogen phosphate dihydrate and benzoic anhydride modified polyoxyethylated castor oil according to prescription amounts for later use; (2) preparing a solution: weighing water for injection, adding xylitol, sodium dihydrogen phosphate dihydrate and disodium hydrogen phosphate dihydrate according to the prescription dosage in a stirring state, stirring and dissolving, then adding benzoic anhydride modified polyoxyethylated castor oil and bumetanib according to the prescription dosage, and stirring until the materials are completely dissolved; and (3) fixing the volume: supplementing the water for injection to the total amount of the prescription, and uniformly stirring and mixing. According to the bumetanib injection disclosed by the invention, the polyoxyethylated castor oil is modified by benzoic anhydride, so that the dissolution rate of bumetanib is effectively improved, and meanwhile, the high-temperature and illumination stability of the bumetanib injection is remarkably enhanced.