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36 results about "Skin photosensitivity" patented technology

Increased sensitivity of the skin to light and other sources of UV

Preparation method of double-sensitivity cyclodextrin supermolecule aggregate

The invention discloses a preparation method of a double-sensitivity cyclodextrin supermolecule aggregate, belonging to the technical field of functional materials. The preparation method comprises the following steps of preparing a host molecule-photosensitive 4-hydroxycinnamic acid-cyclodextrin (4HCA-CD) by using 4-hydroxycinnamic acid (4HCA) to modify beta-cyclodextrin (beta-CD); using trithioester with adamantine (AD) at tail end as a chain transfer agent, and preparing temperature-sensitive object polymer-double-arm adamantine-poly(N-isopropyl acrylamide)-adamantine (AD-PNIPAM-AD) by using a reversible addition-fragmentation chain transfer free radical polymerization (RAFT) method; constructing a double-sensitivity supermolecule inclusion complex 4HCA-CD/AD-PNIPAM-AD by utilizing comprehensive performance of a beta-CD dewatering cavity and AD; and self-assembling the 4HCA-CD/AD-PNIPAM-AD to form the supermolecule aggregate which is capable of realizing reversible conversion in shape and size by changing light and temperature. The supermolecule aggregate prepared by the preparation method disclosed by the invention has good light/temperature double sensitivities and is capable of carrying out smart response onto external stimulus, so that the supermolecule aggregate has a wide application prospect in the fields of drug loading, controlled release, and the like.
Owner:JIANGNAN UNIV

Preparation method and application of castor oil-based polyamide capable of being cross-linked by ultraviolet light

The invention discloses a preparation method of castor oil-based polyamide capable of being cross-linked by ultraviolet light, and relates to the technical field of macromolecules, the preparation method comprises the following steps: (1) adding castor oil-based functional polyamide and a photo-crosslinking functional monomer into tetrahydrofuran, and heating until dissolving; (2) dissolving dimethylaminopyridine in tetrahydrofuran, and then mixing with the mixture obtained in the step (1); and (3) dissolving a dehydrating agent in tetrahydrofuran, then mixing with the mixture obtained in the step (2), carrying out sealed reaction at 65 DEG C for 12 hours, and purifying to obtain a polymer, namely the ultraviolet-crosslinkable castor oil-based polyamide. The invention also provides a product obtained by the method and application thereof. The castor oil-based polyamide has the beneficial effect that the ultraviolet light sensitive side group endows the castor oil-based polyamide with light sensitivity. According to the invention, the preparation of the castor oil-based photo-crosslinked polyamide elastomer is realized, so that the bio-based polyamide elastomer has ultraviolet light crosslinking functionality, and the application field of castor oil-based polyamide is expanded.
Owner:ANHUI AGRICULTURAL UNIVERSITY

Preparation method of photochromic material based on boron cluster anions

The invention discloses a preparation method of a photochromic material based on boron cluster anions, which comprises the following steps: adding conjugated polypyridine molecules into ultrapure water, regulating the pH value to -1-7 with an inorganic acid, and carrying out ultrasonic stirring at room temperature until the solution is completely clear and transparent to obtain a solution A; and adding an aqueous solution containing a boron cluster compound into the solution A, continuously stirring for 0.5-24 hours after generating a precipitate, filtering to obtain a precipitate, washing, and carrying out vacuum drying to obtain the photochromic material based on boron cluster anions. The method is mild in reaction condition, simple in process and easy to operate. The absorption spectrumdifference before and after material discoloration is large, and preparation cost is low. The synthesized material has the advantages of higher photosensitivity, quicker discoloration and longer freeradical service life. A reference thought is provided for subsequently utilizing the photochromic material in the application fields of biological treatment, photoelectric conversion and the like, and the photochromic material has a great application prospect in the aspect of photoelectrocatalysis.
Owner:WUHAN UNIV

Positive photoresist composition and preparation method and application thereof

The invention provides a positive photoresist composition and a preparation method and application thereof, and relates to the technical field of photoresist preparation, the positive photoresist composition comprises phenolic resin, a cross-linking agent, an acid catalyst, a photoinduced deactivator and an optional solvent, and the photoinduced deactivator comprises an anionic initiator. The positive photoresist composition belongs to chemical amplification photoresist, the phenolic resin in the positive photoresist composition has excellent physical and chemical properties, proper dissolution rate and good film-forming property, in a non-exposure area, an acid catalyst catalyzes a cross-linking agent to be subjected to a cross-linking reaction with the phenolic resin, and after the positive photoresist composition is exposed by ultraviolet light with the wavelength of 365 nm or 436 nm in an exposure area, the compound generated by the anionic initiator deactivates the acidic catalyst and does not catalyze the cross-linking reaction any more. According to the invention, the technical problem of large exposure dose demand caused by poor photosensitivity of the photoresist is solved, and the technical effects of high photosensitivity of the photoresist, small exposure dose demand, improvement of production efficiency and reduction of production cost are achieved.
Owner:SUNTIFIC MATERIALS WEIFANG LTD

Polyurethane, single-component light-sensitive reversible hydrogel as well as preparation method and application of single-component light-sensitive reversible hydrogel

ActiveCN114409908AEasy to prepareFunctional group content is easy to controlAerosol deliveryOintment deliveryPolymer scienceSide chain
The invention belongs to the technical field of high polymer material preparation, and particularly relates to polyurethane, single-component light-sensitive reversible hydrogel and a preparation method and application of the single-component light-sensitive reversible hydrogel, a side chain of the polyurethane contains a beta-cyclodextrin (beta-CD) group and an azobenzene group, a main chain is based on polyethylene glycol, the preparation method is simple, and the content of functional groups is easy to control; the hydrogel prepared on the basis of the polyurethane has high photosensitivity and high response speed to white light and ultraviolet light media, can realize solution-gel-solution circulation along with irradiation of ultraviolet light-white light-ultraviolet light, and can be repeatedly used for multiple times; the hydrogel is extremely sensitive to light rays, the time T (liquid-gel) for converting a solution into a gel state is 0.5-1.5 min, the time T (gel-liquid) for converting the gel into a liquid state is 5-10 min, and the hydrogel shows excellent light response speed; the hydrogel has relatively high anti-cracking strength, and the anti-cracking strength can reach 5 to 20 kPa.
Owner:SHANDONG NORMAL UNIV

Nanogold-containing polyvinyl pyrrolidone/poly (N-vinylcaprolactam) hybrid microgel and preparation method thereof

The invention belongs to the field of preparation of nano noble metal particle-containing hybrid microgel materials, and particularly relates to nano gold-containing polyvinyl pyrrolidone/poly (N-vinylcaprolactam) hybrid microgel and a preparation method of the nano gold-containing polyvinyl pyrrolidone/poly (N-vinylcaprolactam) hybrid microgel. The preparation method comprises the following steps: firstly, synthesizing polyvinyl pyrrolidone/poly (N-vinylcaprolactam) intelligent composite microgel through a seed soap-free emulsion polymerization method, and then reacting with a chloroauric acid (HAuCl4) solution by utilizing the reducibility of the polyvinyl pyrrolidone component in the microgel, so as to reduce gold ions into simple substance nanogold. And changing synthesis conditions and experimental formulas to obtain the hybrid microgels with different forms, different gold nanoparticle contents and different performances. In the final product, the size of the gold nanoparticles is 5-80 nm, and the size of the gold nanoparticles can be regulated and controlled through reaction conditions. The obtained hybrid microgel material organically combines the photo-thermal conversion capability of the gold nanoparticles and the temperature sensitivity of the microgel, and has special photosensitivity.
Owner:沈阳先进涂层材料产业技术研究院有限公司

A kind of preparation method of double sensitive cyclodextrin supramolecular aggregate

The invention discloses a preparation method of a double-sensitivity cyclodextrin supermolecule aggregate, belonging to the technical field of functional materials. The preparation method comprises the following steps of preparing a host molecule-photosensitive 4-hydroxycinnamic acid-cyclodextrin (4HCA-CD) by using 4-hydroxycinnamic acid (4HCA) to modify beta-cyclodextrin (beta-CD); using trithioester with adamantine (AD) at tail end as a chain transfer agent, and preparing temperature-sensitive object polymer-double-arm adamantine-poly(N-isopropyl acrylamide)-adamantine (AD-PNIPAM-AD) by using a reversible addition-fragmentation chain transfer free radical polymerization (RAFT) method; constructing a double-sensitivity supermolecule inclusion complex 4HCA-CD / AD-PNIPAM-AD by utilizing comprehensive performance of a beta-CD dewatering cavity and AD; and self-assembling the 4HCA-CD / AD-PNIPAM-AD to form the supermolecule aggregate which is capable of realizing reversible conversion in shape and size by changing light and temperature. The supermolecule aggregate prepared by the preparation method disclosed by the invention has good light / temperature double sensitivities and is capable of carrying out smart response onto external stimulus, so that the supermolecule aggregate has a wide application prospect in the fields of drug loading, controlled release, and the like.
Owner:JIANGNAN UNIV
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