The invention relates to an ultra-thin section steel structure weather-resistant fireproof paint, and a preparation method thereof. The ultra-thin section steel structure weather-resistant fireproof paint is composed of, by weight, 20 to 35 parts of modified acrylic resin, 10 to 18 parts of a nonsaturated polyester, 5 to 15 parts of alkyd resin, 10 to 20 parts of melamine phosphate, 4 to 10 partsof hydrated zinc borate, 5 to 10 parts of nanometer calcium carbonate, 3 to 7 parts of vermiculite, 25 to 40 parts of a solvent, 1 to 10 parts of modified barium metaborate, 1.5 to 3.6 parts of bentonite, 1 to 3 parts of a plasticizer, 0.5 to 3 parts of a levelling agent, and 1 to 5 parts of an ultraviolet ray absorber. The preparation process is simple; energy consumption is low; production costis low; the ultra-thin section steel structure weather-resistant fireproof paint possesses excellent flame resistance, weather resistance, bonding performance, sealing performance, is friendly to theenvironment, is wide in application range, and shedding is not easily caused.