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55results about How to "Short molecular chain" patented technology

Intelligent surface-hydrophilicity-and-hydrophobicity-convertible fabric finishing liquid and preparation method thereof

The invention discloses intelligent surface-hydrophilicity-and-hydrophobicity-convertible fabric finishing liquid and a preparation method thereof. An effective component of the finishing liquid provided by the invention is a perfluoroalkyl azophenyl acrylate copolymer. Perfluoroalkyl azophenol is used as an initial raw material, and esterification reaction is performed on the perfluoroalkyl azophenol and acryloyl chloride, thus obtaining a perfluoroalkyl azophenyl-containing acrylate monomer; the perfluoroalkyl azophenyl-containing acrylate monomer, hydroxyethyl methylacrylate and butyl acrylate are polymerized through an emulsion, thus preparing a perfluoroalkyl azophenyl-containing acrylate copolymer emulsion. During emulsion polymerization, the use amount of an initiator is increased, so that an obtained copolymer is low in degree of polymerization, a copolymer molecular main chain is relatively short, and the degree of twisting of a molecular chain is small; therefore, the molecular isomerism capacity of lateral radical azophenyl is high, and conversion of surface hydrophilicity and hydrophobicity is facilitated. An intelligent water repellent finishing agent provided by the invention is mild in preparation reaction conditions, simple in preparation process and suitable for industrial production.
Owner:烟台品成洗化用品有限公司

Method for synthesizing ternary-copolymerized super-absorbent resin

The invention discloses a method for synthesizing a ternary-copolymerized super-absorbent resin. The method comprises the following operating steps: weighing chitosan hydrochloride, itaconic acid and acrylic acid according to the mass ratio of (1-11): (2-10): (3-17); firstly, dissolving chitosan hydrochloride and itaconic acid, which are in the mass ratio, into distilled water, and transferring a mixed solution into a four-mouthed flask which is provided with a nitrogen gas conduit and a reflux condensation tube; heating to the temperature of 30-80 DEG C, then, adding a 1%-18% initiator, continuing to react for 1-6 hours under the protection of nitrogen gas, and dropwise adding acrylic acid which is in the mass ratio during reaction; mixing a reactant and ethanol, purifying and baking, thereby obtaining the ternary-copolymerized super-absorbent resin. According to the method disclosed by the invention, the process is simple, and the selected chitosan hydrochloride is a monomer, so that the problem of chitosan solubility is solved, and polymerization reaction can be carried out under neutral conditions; itaconic acid added during the synthesis of the product is a monomer, so that the water absorbency of the product is further improved, the highest absorption volume of deionized water is 1,000-1,100 times, the highest absorption volume of tap water is 300-400 times, and the highest absorption volume of normal saline is 100-120 times.
Owner:QINGDAO UNIV OF SCI & TECH

Intelligent textile finishing agent with convertible surface hydrophilicity and hydrophobicity and method for preparing intelligent textile finishing agent

The invention discloses an intelligent textile finishing agent with convertible surface hydrophilicity and hydrophobicity and a method for preparing the intelligent textile finishing agent. The intelligent textile finishing agent comprises effective components which are perfluoroalkyl group azobenzene acrylic ester copolymers. The method includes carrying out esterification reaction on perfluoroalkyl group azophenol and acryloyl chloride to obtain acrylic ester monomers with perfluoroalkyl group azobenzene; polymerizing the acrylic ester monomers, hydroxyethyl methacrylate and butyl acrylate by the aid of emulsion to obtain acrylic ester copolymer emulsion with the perfluoroalkyl group azobenzene. The perfluoroalkyl group azophenol is used as an initial raw material. The intelligent textile finishing agent and the method have the advantages that the usage of initiators is increased during emulsion polymerization, obtained copolymers are low in polymerization degree and have short molecular main chains, and molecular chains are low in twining degree, accordingly, side group azobenzene is high in molecular isomerism capacity, and the surface hydrophilicity and hydrophobicity can be advantageously converted; reaction conditions for preparing the intelligent textile finishing agent which is an intelligent water repellent finishing agent are mild, processes for preparing the intelligent textile finishing agent are simple and convenient, and accordingly the intelligent textile finishing agent and the method are suitable for industrial production.
Owner:SUZHOU UNIV

External energy oil with effects of clearing and activating channels and collaterals and increasing blood circulation and preparation method thereof

The invention relates to external energy oil with effects of clearing and activating channels and collaterals and increasing blood circulation and a preparation method thereof. The external energy oil is prepared from the following raw materials in parts by volume: 25.2 to 38.28 parts of stephania sinica diels essential oil, 3.6 to 6 parts of permanent flower essential oil, 8.8 to 13.8 parts of magnolia flower essential oil, 5.2 to 8.4 parts of salvia sclarea essential oil, 2.8 to 4.8 parts of cistus essential oil, 2.8 to 4.8 parts of marjoram essential oil or valerian essential oil, 17.6 to 27 parts of grapefruit essential oil, and 12 to 18.6 parts of evening primrose essential oil or lemon grass essential oil. The preparation method comprises the following steps of mixing the raw materials, and uniformly stirring. The external energy oil has the advantages that the external energy oil can fundamentally permeate into subcutaneous tissues and the blood system, the blood circulation is enhanced, cold and dampness are removed, the weak physique with slow blood circulation is relieved, a human body is regulated in physiology and psychology, and the purpose of quick healing is realized; after using the external energy oil, a patient has no allergic reaction, and any toxic or side effect is avoided.
Owner:曾惠民 +1

Engine oil-resistant low-pressure-change addition type liquid fluorinated silicone rubber and preparation method thereof

The invention relates to engine oil-resistant low-pressure-change addition type liquid fluorosilicone rubber and a preparation method thereof. The engine oil-resistant low-pressure-change addition type liquid fluorosilicone rubber comprises the following components in parts by weight: 100 parts of fluorosilicone base rubber; 10 to 20 parts of fumed silica; 10-20 parts of precipitated white carbon black; 1-3 parts of hydroxyl fluorosilicone oil; 2 to 5 parts of trifluoropropyl methyl cyclosilazane; 0.1 to 0.3 part of divinyl tetramethyl disilazane; 1-3 parts of distilled water; 0.1 to 0.3 part of a heat-resistant additive; 1.3 to 2.9 parts of a cross-linking agent; 0.3 to 0.6 part of a platinum catalyst; and 0.05 to 0.2 part of an inhibitor. According to the preparation method, fluorosilicone treating agents such as low-molecular-weight hydroxyl fluorosilicone oil and trifluoropropyl methyl cyclosilazane are used, the fumed silica and the precipitated silica are compounded to achieve a synergistic effect, and the specific cross-linking agent and the preparation method are matched, so that the compression set of the addition type liquid fluorosilicone rubber is greatly reduced, and the service life of the addition type liquid fluorosilicone rubber is prolonged. Even if the lubricating oil is soaked in high-temperature engine oil for a long time, the system cannot be damaged, the lower deformation rate can still be kept, and the oil pressure change resistance is very excellent.
Owner:新元化学(山东)股份有限公司 +1

Secondary battery

The invention provides a secondary battery, at least one of a positive pole piece, a negative pole piece and an electrolyte of the secondary battery comprises an additive with small molecular weight and short molecular chain segment, and the additive can be fully mixed with an active substance, a conductive agent and a binder in the positive pole piece and the negative pole piece. And the additive can be in full contact with each component in the positive electrode and the negative electrode and is immersed into internal pores of the pole piece. In addition, the additive has good compatibility with electrolyte components in the electrolyte, and can be easily dissolved in the electrolyte within the addition amount of the additive. The additive can form a film on the surfaces of positive and negative active substances, can effectively improve the composition of a solid electrolyte film on the surfaces of the positive and negative active substances, improves the content of polymer components in a solid interface film, improves the conduction of electrons and lithium ions in positive and negative pole pieces of the battery, and enhances the dynamics of lithium ions in the pole pieces. The internal resistance of the battery in the cycle process is prevented from increasing and the cycle life is prolonged.
Owner:ZHUHAI COSMX BATTERY CO LTD

Quaternary ammonium salt type dendritic polythioether modified polymer microsphere

ActiveCN111548526ASignificantly sterilizingImprove stabilityBiocideFungicidesPolymer scienceMicrosphere
The invention discloses a quaternary ammonium salt type dendritic polythioether modified polymer microsphere. The preparation method comprises the following steps: under an ultraviolet light condition, with methoxy polyoxyethylene as a pore-foaming agent and alkyl dithiol, propargyl glycidyl ether and 1,7-octylene as raw materials, synthesizing epoxy microporous polymer spheres by using a sulfydryl-alkyne addition suspension polymerization method; and performing a reaction on the epoxy microporous polymer spheres with excessive organic amine containing unsaturated substituent groups to obtainunsaturated substituent group functionalized porous polymer spheres; then with cysteamine hydrochloride and glycidyl ether containing unsaturated groups as raw materials and methanol as a solvent modifying the surfaces of the epoxy polymer microspheres with dendritic polythioether by adopting multiple iterative reactions alternately performed by a sulfydryl-epoxy addition reaction catalyzed by analkaline compound and a sulfydryl-ene/alkyne addition reaction initiated by free radicals. The quaternary ammonium salt type dendritic polythioether modified porous polymer microsphere prepared by theinvention has bactericidal activity, and does not generate bubbles when being used as a bactericide.
Owner:YANTAI UNIV

Synthesis method of polyester chip for low extraction membrane

The invention relates to a synthetic method of a polyester chip for a low extraction membrane, which belongs to the technical field of polyester preparation, and comprises the following steps: 1) carrying out esterification reaction, 2) carrying out pre-polycondensation reaction; 3) carrying out final polycondensation reaction; (4) melting and kneading the PET original sheet obtained in the step (3) with phosphate, crown ether and a bisphenol alkene oxide at the melting temperature of 280 DEG C for 5 minutes; According to the invention, 25% KF/Al2O3 and nano antimony trioxide are adopted as a compounded catalyst, the addition amount of antimony trioxide can be reduced, and introduction of impurities is reduced. Compared with ethylene glycol antimony, antimony trioxide is added, due to the fact that monovalent and subsequent water removal is not needed, and the use cost is lower, so that the defects that ethylene glycol antimony is extremely prone to absorbing moisture, and after the package is unsealed, the package must be completely used up for one time can be overcome. In addition, during the pre-polycondensation stage, reaction materials are low in concentration and small in molecular chain, so that the vacuum degree is increased at a constant speed in the pre-polycondensation stage, and flooding caused by the fact that a large number of materials are brought out can be avoided.
Owner:常州浩阳新材料科技有限公司

External energy oil capable of supplementing water, whitening skin and eliminating and improving pimples and preparation method of external energy oil

The invention relates to external energy oil capable of supplementing water, whitening the skin and eliminating and improving pimples and a preparation method of the external energy oil. The energy oil is prepared from the following raw materials in parts by volume: 27.2-41.4 parts of green bamboo essential oil, 5.2-8.4 parts of vetiver essential oil and/or dill essential oil, 11.6-18 parts of grapefruit essential oil and/or lemon essential oil, 6-9.6 parts of niaouli essential oil, 10.4-16.2 parts of chamomile essential oil, 10.8-16.8 parts of geranium essential oil, 4.4-7.2 parts of rose essential oil and 3.6-6 parts of jasmine essential oil. The preparation method is that raw materials are mixed evenly. The external energy oil fundamentally permeates into subcutaneous tissue and a blood system, the skin problems of skin hydropenia, dark and gloomy complexion and fine liens and scars are solved, and the body is physically and psychologically regulated to achieve the target of fast recovery. The external energy oil is safe, free of thrill and free of toxic or side effect, and can be used for a long period of time. The external energy oil capable of supplementing water, whitening the skin and eliminating and improving pimples and the preparation method of the external energy oil are provided.
Owner:曾惠民 +1
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