The application discloses a
copper-based core / multilayer shell structure
quantum dot based on gradient active
zinc source and a preparation method thereof, and relates to the technical field of
quantum dot materials. The application adopts a CuInZnS
quaternary alloy core-three-layer ZnS shell structure design, cooperates with
zinc source types and
solvent coordination
system to synergistically control a gradient active
zinc source, performs
quantum dot step-by-step growth through gradually reducing the activity of the zinc source from inside to outside, realizes fast and uniform
nucleation, releases interface stress from inside to outside of the ZnS shell layer in stages, passivates defects and avoids
stress concentration to introduce new defects. The prepared
copper-based core / multilayer shell structure
quantum dot has a significantly improved
fluorescence quantum yield; the stability of the
quantum dot film in
luminescence properties is obviously increased under the condition of a general indoor environment below 200 DEG C high temperature. Compared with a regulation mode of changing the zinc
source type alone, the regulation precision is higher, the step-by-step growth requirement of the multilayer shell can be accurately matched, the preparation process is an
oil phase conventional process, the operation is simple, the
repeatability is good, and the application is suitable for industrialized scale production.