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93results about How to "Microstructural stability" patented technology

High-dispersion high-load high-activity nickel-based catalyst for low-temperature methane reforming and application of high-dispersion high-load high-activity nickel-based catalyst for low-temperature methane reforming

The invention belongs to the field of chemical industry, and relates to a high-dispersion, high-load, high-activity low-temperature methane reforming nickel-based catalyst and its application. The invention provides a high-dispersion, high-load, high-activity low-temperature methane reforming nickel-based catalyst, which comprises the following components in terms of mass percentage: active component 20-25%; synergistic component 1-30%; carrier 45-79% . The present invention further provides a preparation method of a high-dispersion, high-load and high-activity low-temperature methane reforming nickel-based catalyst and its use in low-temperature methane reforming reactions. The invention provides a high-dispersion, high-load, high-activity low-temperature methane reforming nickel-based catalyst and its application, which is suitable for high-pressure and low-temperature methane-carbon dioxide reforming reaction at a reaction temperature of 400-800°C, high-pressure and low-temperature methane-steam reforming, high-pressure and low-temperature reforming Methane reforming processes such as methane-carbon dioxide-steam mixed reforming have high catalytic activity and stability.
Owner:高潞空气化工产品(上海)能源科技有限公司

Preparation method of full water electrolysis catalyst with heterojunction structure

The invention relates to the technical field of nano-materials, in particular to a preparation method of a full water electrolysis catalyst with a heterojunction structure. The preparation method includes: 1) preparing a precursor solution, and putting a pretreated conductive substrate into the precursor solution for hydrothermal reaction to obtain a trimetal precursor; and 2) placing the trimetalprecursor in a reducing atmosphere, carrying out first-step heating to a first-stage temperature and then carrying out heat preservation for a period of time, then carrying out second-step heating toa second-stage temperature, and then conducting heat preservation for a period of time, thus obtaining the full water electrolysis catalyst with a heterojunction structure. The preparation method isconcise and efficient, low in equipment requirement, and convenient to popularize and realize industrial production; meanwhile, the catalyst has the double functions of hydrogen evolution and oxygen evolution, can be directly used as a self-supporting electrode, and has wide universality; and the prepared full water electrolysis catalyst with a heterojunction structure has stable microstructure, homogeneous nano-structure size and uniform component distribution, and has good electro-catalytic performance and mechanical performance.
Owner:ZHEJIANG UNIV OF TECH

Tungsten oxide and zirconium oxide high-temperature solar selective absorption coating and production method thereof

The invention discloses a tungsten oxide and zirconium oxide high-temperature solar selective absorption coating and a production method thereof. The tungsten oxide and zirconium oxide high-temperature solar selective absorption coating comprises three layers of films; a first layer of infrared reflective layer is a cuprum or argentum film which is located on the surface of a substrate, wherein the thickness of the cuprum or argentum film is 100 to 300 nm; a second layer of absorption layer comprises two sub-layers which are tungsten oxide and zirconium oxide films; the thickness of the first sub-layer and the thickness of the second sub-layer are both 150 to 300 nm; the volume percent of zirconium oxide in the first sub-layer is 50 to 75% and the rest is tungsten oxide; the volume percent of zirconium oxide in the second sub-layer is 30 to 50% and the rest is tungsten oxide; the first sub-layer is adjacent to the first layer of infrared reflective layer; the second sub-layer is adjacent to a third layer of antireflection layer; the third layer of antireflection layer is a zirconium oxide film, wherein the thickness of the zirconium oxide film is 120 to 200 nm. According to the tungsten oxide and zirconium oxide high-temperature solar selective absorption coating and the production method thereof, the high-temperature stability is excellent and the good thermal stability can be maintained under the 500 to 600 DEG C high-temperature vacuum conditions or under the 400 DEG C atmospheric conditions.
Owner:北京天瑞星光热技术有限公司

Processing method for improving anti-radiation performance of quartz optical fibers

The invention relates to a processing method for improving anti-radiation performance of quartz optical fibers. Quartz optical fiber materials are high-pure quartz materials. The processing method adopts methods of a preheating treatment, rapid quenching, and pre-radiation and a re-preheating treatment. The preheating treatment is that the temperature is maintained in a certain range to make the structure of quartz optical fiber materials more stable. Rapid cooling makes sure that the structure of the quartz optical fiber materials remains in stable at the room temperature. Pre-radiation is that pure quartz optical fiber materials are subjected to a certain amount radiation to break the fatigue bonds of the pure quartz fiber optical material to give off redundant power. The re-preheating treatment makes the broken bonds pre-radiated recover so as to form stable structures. The anti-radiation quartz optical fiber materials, which are produced according to the processing method for improving anti-radiation performance of quartz optical fibers, have a very good anti-radiation performance and a very good anti-radiation effect under a very high radiation dose. The anti-radiation quartz optical fiber materials not only can be used for the production of optical fibers, but also can be used for the production of related devices made of anti-radiation quartz materials.
Owner:SHANGHAI UNIV

Method for encapsulating CaO-Y2O3-Al2O3-SiO2 glass at port of SiCf/SiC core cladding tube

The invention relates to a method for encapsulating CaO-Y2O3-Al2O3-SiO2 glass at a port of a SiCf / SiC core cladding tube. Part of raw materials which are low in reaction activity and low in nuclear irradiation decay rate and have no side effects on the nuclear reaction process are selected, and a glass brazing filler metal is prepared through a melting-water cooling method; by means of the SiCf / SiC matched thermal expansion coefficient, good wettability and low high-temperature viscosity, packaging / connection of the SiCf / SiC composite core cladding tube is achieved under the conditions that the temperature is lower than the applicable temperature (<=1450 DEG C) of domestic third-generation SiC fibers and no pressure exists. The SiCf / SiC core cladding tube is promoted to be applied to a nuclear reactor, nuclear radiation leakage accidents are prevented in advance, and the operation safety of the nuclear reactor is improved. The method has the beneficial effects that the raw materials selected by an encapsulating agent are low-activity elements, the nuclear radiation decay of the encapsulating agent is small, the encapsulating agent has no side effect on a nuclear reaction process, and the mechanical and airtight requirements of port encapsulation of the core cladding tube are met, so that nuclear radiation leakage in the cladding tube can be effectively prevented in a harsh service environment, and nuclear radiation leakage accidents are prevented in advance.
Owner:NORTHWESTERN POLYTECHNICAL UNIV

Porous polyimide oil storage and retention structure and preparation method and application thereof

The invention provides a porous polyimide oil storage and retention structure and a preparation method and application thereof, and relates to the technical field of polyimide materials. The porous polyimide oil storage and retention structure comprises an oil storage layer and an oil control layer; the oil storage layer is made of monoether type polyimide, the porosity of the monoether type polyimide is 18-26%, and the aperture of the monoether type polyimide is 1.0-3.0 [mu] m; the oil control layer is made of pyromellitic polyimide, the porosity of the pyromellitic polyimide is 12-18%, and the pore diameter of the pyromellitic polyimide is 0.6-1.0 [mu] m. The pyromellitic polyimide is low in porosity and small in aperture so that the oil release rate of the composite material can be slowed down, and the oil retention rate can be increased; the monoether polyimide is high in porosity and large in aperture, so that the porosity and the oil storage rate of the composite material can be improved; the composite material provided by the invention has high oil storage rate and oil retention rate and good strength and wear resistance, and can meet the requirement of a high-speed and high-precision bearing on the service life.
Owner:LANZHOU INST OF CHEM PHYSICS CHINESE ACAD OF SCI

High-nickel ternary lithium ion battery electrolyte and ternary lithium ion battery

The invention belongs to the technical field of lithium ion batteries, and particularly relates to a ternary lithium ion battery non-aqueous electrolyte and a lithium ion battery. The ternary lithiumion battery electrolyte comprises a non-aqueous organic solvent, an electrolyte lithium salt and an additive, the additive comprises an oxalic acid lithium phosphate additive with a structure shown ina formula (I), and can also comprise conventional additives such as vinylene carbonate (VC), 4-vinyl-1,3-dioxolan-2-one (VEC), 1, 3-propane sultone (PS), ethylene sulfate (DTD), tris (trimethylsilane) phosphate (TMSP) and the like. Under the combined action of the uniquely combined conventional additive and the oxalic acid lithium phosphate additive with the structure shown in the formula (I), the generation of cracks in positive electrode material particles in the circulation process can be inhibited, the dissolution of transition metal elements at high temperature can be reduced, the reduction reaction decomposition of a solvent on a negative electrode interface can be inhibited, the cycle performance, the high-temperature storage performance and the low-temperature performance of the ternary lithium ion battery are effectively improved.
Owner:SHANSHAN ADVANCED MATERIALS QUZHOU CO LTD

Magnetic nanorod demulsifier, preparation method thereof and method for treating nano-emulsion by using magnetic nanorod demulsifier

The invention discloses a magnetic nanorod demulsifier, a preparation method thereof and a method for treating nano-emulsion by using the magnetic nanorod demulsifier, and belongs to the technical field of demulsifiers. The preparation method of the demulsifier comprises the steps that FeCl3. 6H2O and FeSO4. 7H2O are dissolved in deionized water under the N2 introduction condition to obtain a ferric salt solution, the molar ratio of Fe < 3 + > to Fe < 2 + > is 2.15, polyethyleneimine is taken and dissolved in distilled water to obtain a polyethyleneimine solution, the molecular weight of polyethyleneimine is 10000, and the molar ratio of N to Fe is not lower than 1.47; the polyethyleneimine solution is added into the ferric salt solution dropwise while continuously introducing N2 and stirring, concentrated ammonia water is dropwise added at the water bath temperature of 50-80 DEG C, stirring is carried out to react for 1-4 hours, solid particles in the reaction solution are separated by using a magnet, the solid particles are cleaned with deionized water, re-dispersing the solid particles into the deionized water, a glutaraldehyde solution is added, and stirring, uniformly mixing and magnetic field separation are carried out to obtain the demulsifier. The demulsifier prepared by the preparation method disclosed by the invention can be used for efficiently demulsifying the nano-emulsion of which the mass ratio of the surfactant to the oil is 0-0.909.
Owner:TONGJI UNIV

Non-fullerene receptor with collaborative assembly characteristic as well as preparation method and application of non-fullerene receptor

The invention discloses a non-fullerene receptor with synergistic assembly performance as well as a preparation method and application thereof. The non-fullerene receptor comprises oligomeric ethylene glycol side chains which are substituted at different positions and have different lengths. The non-fullerene receptor is used as a guest component, so that the active layer (main body) component is dissolved in various non-halogen solvents, the compatibility and phase separating size and morphology among the active layer components are regulated and controlled, and the dependence of the active layer on low-boiling-point and high-toxicity halogen-containing solvents is reduced. In addition, the object non-fullerene receptor can regulate and control the crystallization kinetics of the subject in a high-boiling-point solvent through a self-assembled side chain, the crystallization time of receptor molecules is prolonged, the overall crystallinity of the active layer is improved, and the dependence of active layer processing on a post-treatment process is reduced. The three advantages are combined, the photoelectric conversion efficiency of the organic solar cell processed by the high-boiling-point and green solvent is greatly improved, an annealing process is not needed, the device preparation process is simplified, and the device preparation energy consumption is reduced.
Owner:SUZHOU UNIV

A preparation method of high-temperature-resistant and wear-resistant brake pads

The invention relates to a preparation method of a high-temperature-resistant and wear-resistant brake pad, belonging to the technical field of brake pad preparation. In accordance with that invention, titanium pow, Carbon powder, aluminum powder and iron powder are mixed, A metal composite product is prepare by adding urea and absolute ethanol, oxidizing graphite powder, A modified mixture is prepared by reduction and modification, A metal composite product of that mix slurry, A high-temperature-resistant and wear-resistant brake pad is obtain by mixing that modify mixture and pressing the mixture into a mold, Volatilization of urea particles, A metal mixture is microscopically porou, in the pores of the metal mixture filled with the modified nano-graphene, making the microstructure of the metal mixture stronger, The impact resistance and mechanical strength of the brake pads are effectively improved, and the high temperature resistance and strength of the metal mixture can be greatlyimproved by the introduction of titanium, and the high temperature resistance of the metal mixture can be further improved by the modified graphene, and the carboxyl and ester groups in tung oil canimprove the mechanical strength and wear resistance of the brake pads, so that the brake pads have a broad application prospect.
Owner:山西罗克森实业有限公司
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