The invention discloses an online extraction and dephenolization method of
coal tar wastewater. The method comprises the following steps: heating water-containing
coal tar, carrying out reduced pressure
flash evaporation to obtain mixed steam, sending the mixed steam to a rectifying
tower, introducing an extractant from the top of the
tower as a
reflux liquid, carrying out azeotropic rectification in the rectifying
tower, extracting components with the
boiling point of 170-210DEG C from the
lateral line of the rectifying tower, fractioning components with the
boiling point being greater than 210DEG C, allowing the components with the
boiling point being greater than 210DEG C to heavy oil components in the middle portion of the tower, and extracting other components from the top of the tower; sending the components extracted from the top of the tower to a tower top condenser, cooling to a temperature being smaller than 40DEG C, sending the cooled components to a tower top refluxing tank, carrying out oil-water settlement separation, and separating to obtain water which is dephenolized water; and mixing oil obtained after the separation with the component extracted from the
lateral line, sending the obtained mixture to a dephenolization device, and dephenolizing. The method directly realizes online extraction dephenolization in the rectifying tower in the
coal tar rectification process, simultaneously realizes
coal tar rectification and
phenol substance removal purposes, and saves the cost.