The invention provides an anti-rust and weather-resistant brush-coating macromolecular material as well as a preparation method and the application thereof, and relates to the technical field of an anti-rust macromolecular material. The anti-rust and weather-resistant brush-coating macromolecular material comprises the following raw materials in parts by mass: 70 to 130 parts of 107 silicon rubber, 10 to 30 parts of a nano-silicon powder, 0.5 to 2 parts of a first silane coupling agent, 0.3 to 1.5 parts of a second silane coupling agent, 1 to 5 parts of ethyl silicate and 0.2 to 1 part of organic tin. The technical problems that the traditional brush-coating material has a low fireproof property, a weather resistance and waterproof property, has probability of peeling off, cracking and falling off, has short service life and high cost, is toxic and not environmentally-friendly, and is complex in construction process and difficult in construction are solved. The anti-rust and weather-resistant brush-coating macromolecular material provided by the invention has a high anti-rust property, a fireproof property, weather resistance and a waterproof property, has low probability of peeling, cracking and falling off under various severe environments, is long in service life, non-toxic, environmentally-friendly, low in cost and simple in manufacturing method, can perform brush-coating with rust, is easy to construct and has a good future application prospect.