The invention discloses a ceramic grinding segment for a cement grinder and a preparation method of the ceramic grinding segment. The ceramic grinding segment is prepared from the following components in percentage by weight: 92 to 95% of alumina, 0.5 to 2% of tungsten carbide, 0.8 to 3% of calcium carbonate, 1 to 1.2% of magnesium carbonate, 0.5 to 2% of titanium nitride, 1 to 3% of silicon dioxide, and 0.8 to 1% of zirconia, wherein the ceramic grinding segment for the cement grinder is in a shape of a cylinder, a spherical column combination, a spindle or a frustum of a square pyramid which is symmetrical up and down. The preparation method of the ceramic grinding segment is characterized by carrying out press forming and then high temperature sintering, and comprises the processes of material preparation, ball milling, spray granulation, silo aging, profiling, high temperature sintering, powder removing and polishing, drying of a finished product and the like. The density of the finished product is only half of a steel material, so as to be capable of effectively saving electricity and energy and reduce carbon emission. The finished product further has high hardness, good abrasion resistance, low material consumption, good economy, high temperature resistance, capability of working at high strength for a long time, good toughness, difficult breaking and collapse while being impacted, excellent practicality, good binding force and easier forming.