25 results about "Hydroxyanthraquinone" patented technology

The invention belongs to the technical field of gas sensor materials, and particularly relates to a novel high-conductivity conjugated coordination polymer gas-sensitive material, an ammonia gas sensor and a preparation method. Copper salt and 1, 5-diamino-4, 8-dihydroxy anthraquinone or 1-amino-4-hydroxy anthraquinone are used as raw materials, two novel high-conductivity conjugated coordination polymer materials are prepared by adopting a simple solvothermal method, and the preparation method is simple in process and can be used for mass production of materials. The obtained material can form a film on planar electrodes at two ends to prepare a resistance-type ammonia gas sensor, so that ammonia gas can be detected in a concentration range of 2.3 ppb-100 ppm, and the defects of narrow detection range and insufficient sensitivity of a single material in the prior art are overcome.

The invention relates to viologen-anthraquinone composite electrochromic liquid and a preparation method thereof, the viologen-anthraquinone composite electrochromic liquid comprises 1.2-2.5 parts by mole of viologen salt, 0.8-1.5 parts by mole of anthraquinone derivative and 8-12 parts by mole of electrolyte; the viologen salt is ethyl viologen tetrafluoroborate or heptyl viologen tetrafluoroborate or octyl viologen tetrafluoroborate; the anthraquinone derivative is 1-ethylamino-4-hydroxy anthraquinone or acid blue 43; the preparation method comprises the following steps: preparing an electrolyte solution; adding purple refined salt and anthraquinone derivatives according to the formula; fully dissolving the electrochromic material to form uniform and transparent initial liquid; and degassing the initial liquid to remove oxygen dissolved in the initial liquid. The electrochromic liquid has the advantages that after the purple refined salt and the anthraquinone derivative are added into the dissolving solution according to the proportion of the formula, the two color-changing materials are jointly dissolved in the electrolyte, and when the two color-changing materials are reduced at the same time, spectrum superposition absorbed by the two color-changing materials can cover the whole visible region, so that black and white switching of the electrochromic liquid is realized, and the use effect is good.

The present invention relates to the field of 1,4-dihydroxyanthraquinone dilution and hydrolysis mother liquor treatment, specifically a kind of cleaning treatment method of 1,4-dihydroxyanthraquinone dilution and hydrolysis mother liquor. Its steps mainly include: decolorization, cooling, neutralization and dissolution in ammonia water, solid-liquid separation, acidification, crystallization, drying pyrolysis, evaporation concentration, decolorization, quicklime reaction. The present invention can reclaim the excess phthalic anhydride added during the production of 1,4-dihydroxyanthraquinone in the dilution and hydrolysis mother liquor, can save resources, while reducing the production cost of the enterprise, meet the basic requirements of clean production, can extract boric acid by evaporation concentration hydroxyl mother liquor, centrifugation, drying, and then reclaim sulfuric acid by adding calcium oxide, truly achieve the unity of wastewater treatment and resource recovery, and realize clean production.

The invention discloses an alizarin A ring glycosylation derivative, a synthesis method thereof and application of the alizarin A ring glycosylation derivative in preparation of a medicine for treating myocardial cell injury. The structural formula of the alizarin A ring glycosylation derivative is # imgabs0 #. A series of alizarin A ring glycosylation derivatives are designed and synthesized through a computer-aided and chemical synthesis method; finally, the alizarin A ring glycosylation derivative, namely 1-amino-2-methyl-3-hydroxy anthraquinone, is found to be basically kept unchanged in antioxidant effect, increased in solubility in water, enhanced in binding capacity with 5 '-AMP activated protein kinase alpha2 protein, and enhanced in effect of treating and preventing myocardial cell dysfunction.

The invention discloses preparation and application of a nano enzyme. The preparation method of the nano enzyme comprises the following steps: dissolving copper salt and hydroxy anthraquinone carboxylic acid in water to obtain a first solution; adjusting the pH of the first solution to be alkaline, and heating for reaction to obtain a product solution; and centrifuging the product solution, taking the precipitate, washing and drying to obtain the Cu nano-enzyme. The copper salt comprises at least one of copper sulfate, copper chloride, copper nitrate and copper hydroxide; the hydroxy anthraquinone carboxylic acid is rhein. According to the invention, Cu is used as a transition metal source and reacts with specific hydroxy anthraquinone carboxylic acid to prepare the Cu nano-enzyme (Cu-Rhein) with excellent peroxidase-like activity. The Cu nano enzyme can be applied to promotion of hydrogen peroxide oxidation TMB color development and detection of penicillamine, the accuracy of penicillamine detection is high, and the Cu nano enzyme has good application prospects.

This invention relates to the field of biomedicine, specifically to the application of banana fruit extract in the preparation of anticoagulant or antithrombotic drugs. The banana fruit extract provided by this invention contains flavonoids, polyphenols, polysaccharides, hydroxyanthraquinones, triterpenoids, and other components. Flavonoids and polyphenols have been widely proven to have anti-inflammatory and antioxidant effects, which can synergistically enhance the anticoagulant effect. The high potassium content of banana fruit can indirectly improve vascular function by regulating sodium-potassium balance. The banana fruit extract provided by this invention can inhibit platelet production or promote platelet metabolism, prolong clotting time, and inhibit platelet aggregation. Its natural plant components interfere with platelet aggregation by inhibiting the production of thromboxane A2, achieving anticoagulant and antithrombotic effects. The mechanism of action of banana fruit extract differs from traditional anticoagulants such as heparin, reducing the risk of bleeding. Its natural component characteristics provide a direction for the development of novel plant-derived anticoagulant drugs.

The utility model provides a 1, 4-dihydroxy anthraquinone washing and drying device which comprises a supporting plate, and an open type drying machine is installed on the supporting plate. According to the 1, 4-dihydroxy anthraquinone washing and drying device, 1, 4-dihydroxy anthraquinone is filtered and collected in a collecting frame through a filter screen, waste water flows into a purifying pond, a first servo motor is controlled to rotate anticlockwise, then the collecting frame is driven to turn over, the collecting frame is inversely buckled above an open type drying machine, and the 1, 4-dihydroxy anthraquinone collected in the collecting frame is recycled. 1, 4-dihydroxy anthraquinone falls into the open type dryer, then the open type dryer is started, the 1, 4-dihydroxy anthraquinone can be rapidly dried, the 1, 4-dihydroxy anthraquinone adhered to the collecting frame and the filter screen is dried, then the vibration motor is started to vibrate the adhered 1, 4-dihydroxy anthraquinone into the open type dryer, and then the dried 1, 4-dihydroxy anthraquinone is collected. The utility model discloses 2, 4-dihydroxy anthraquinone.

The invention discloses a clean production method of a 1, 4-dihydroxy anthraquinone medical intermediate for an anti-tumor drug, a 1, 4-dihydroxy anthraquinone product is produced by the steps of feeding, reaction, hydrolysis, suction filtration and drying, and mother liquor wastewater generated in the suction filtration step is sequentially subjected to cooling crystallization and resin adsorption, so that the 1, 4-dihydroxy anthraquinone medical intermediate is obtained. Phthalic acid is obtained after phthalic acid desorption, resin regeneration and phthalic acid refining treatment, phthalic acid is dried and then reused for synthesis of the 1, 4-dihydroxy anthraquinone medical intermediate, and filtrate is merged into the next batch of synthesis mother liquor wastewater to be treated. The resource recycling of the mother liquor wastewater and the clean production of the 1, 4-dihydroxyquinone can be realized, and the resource is effectively saved.

The invention relates to the technical field of dyes, in particular to a high-weather-resistance washable macromolecular dye. The invention relates to a high-weather-resistance washable macromolecular dye, which is characterized in that on the basis of the hydrophilicity of a polyether chain and the stability of an anthraquinone skeleton, 1-amino-2-bromo-4-hydroxy-9, 10-anthraquinone and polyethylene glycol are subjected to condensation reaction under an alkaline condition to form dye macromolecules. The prepared high-weather-resistance washable macromolecular dye has the characteristics of bright color, easiness in washing, good light resistance and strong oxidation resistance, is wide in application range, and is particularly suitable for culture and education ink and daily chemical products.

A protective film substance for laser processing includes a solution including a water-soluble resin, an organic solvent, and a light absorbent. The solution has an absorbance, i.e., an absorbance converted for a solution diluted 200 times, equal to 0.05 or more per an optical path length of 1 cm at a wavelength of 532 nm. Alternatively, the protective film substance for laser processing includes a solution including a water-soluble resin, an organic solvent, and a polyhydroxyanthraquinone derivative.

The present application provides a kind of emulsion delayed crosslinking type plugging gel, the emulsion delayed crosslinking type plugging gel is oil-in-water type, including the following raw materials by weight percentage: non-ionic monomer 25wt%-40wt%, dihydroxy anthraquinone 0.5wt%-2wt%, anionic monomer 5wt%-16wt%, initiator 0.002wt%-0.2wt%, deionized water 10wt%-35wt%, non-polar solvent 15wt%-30wt%, emulsifier 2wt%-8wt%, emulsifying aid 1wt%-4wt%, phase transfer agent 0.5wt%-1.5wt%.The plugging gel is by adding modified functional monomer dihydroxy anthraquinone, dihydroxy anthraquinone and acrylamide copolymerization with other monomers oil-in-water polymer gel, not only initial viscosity is low, intensity and plugging rate is high, and gel time is controllable.

The application discloses a variable color water-based paint and a preparation method and application thereof. The paint comprises the following components in percentage by weight: 30-50% of water-based acrylic emulsion, 1-5% of 2-hydroxyanthraquinone, 1-5% of chitosan, 0.1-3% of wetting agent, 0.1-1% of defoaming agent, 0-2% of pH regulator, 0.5-2% of dispersing agent, and the rest of water. The paint contains 2-hydroxyanthraquinone and chitosan. The hydroxyl group in the 2-hydroxyanthraquinone is located on the side of anthraquinone, the orbit of the hydroxyl group can overlap the orbit of the benzene ring, so that the hydroxyl group can form a p-p conjugation effect with the benzene ring. The chitosan is rich in amino groups and hydroxyl groups at the same time, the amino group on the chitosan can form a hydrogen bond with the carbonyl group on the 2-hydroxyanthraquinone, and the hydroxyl group on the chitosan can form a hydrogen bond with the hydroxyl group on the 2-hydroxyanthraquinone. After cross-linking, electronic transition occurs when the environmental temperature, ultraviolet light, pH or electric field intensity changes, so that the color change of the coating can be observed.

The invention belongs to the technical field of chemical dye production, and particularly discloses an environment-friendly solvent green 3 production process and system.The environment-friendly solvent green 3 production process comprises the following steps that ethyl alcohol is added into a condensation kettle to serve as a solvent, p-methylaniline, 1, 4-dihydroxy anthraquinone, a 1, 4-dihydroxy anthraquinone leuco body, boric acid, lactic acid and anhydrous sodium sulfate are sequentially put into the condensation kettle, after feeding is completed, the kettle is closed, the temperature is raised, heat preservation is conducted, and the solvent green 3 is obtained; sampling and detecting an end point, adding DMF for separation, stirring and heating, preserving heat, cooling and filtering, taking a filter cake into a kettle, adding ethanol for soaking and washing the filter cake, pumping the ethanol, washing the filter cake with warm water, washing the filter cake with hot water until the filter cake is neutral, discharging and drying to obtain a solvent green 3 product, recovering the used ethanol and DMF, and carrying out distillation separation for reuse. According to the method, ethanol and DMF used in the production process of the solvent green 3 are recycled, so that waste of production resources is avoided, pollutants generated by a solvent in wastewater are reduced, and the production cost is reduced.

The invention belongs to the technical field of polyurethane, and particularly relates to large-aperture biocompatible polyurethane sponge as well as a preparation method and application thereof. The large-aperture biocompatible polyurethane sponge is prepared by soaking a component A and a component B, wherein the component A comprises polyether polyol X, polyether polyol Y, a chain extender, a catalyst, a pore opening agent and a foaming agent; wherein the component B is prepared from modified MDI and liquefied MDI; the polyether polyol X is prepared by taking hydroxy anthraquinone and low-molecular-weight polyether polyol as a composite initiator and epoxypropane as a polymerization monomer; the average functionality of the polyether polyol Y is 3 to 4, and the number-average molecular weight of the polyether polyol Y is 4000 to 7000 g / mol. The large-aperture biocompatibility polyurethane sponge provided by the invention is large in aperture and strong in biocompatibility. The preparation method is simple in process and safe to operate. The prepared polyurethane sponge is used for sewage treatment, and the degradation rate of microorganisms is increased.

The invention relates to the technical field of electrochemical energy storage, and discloses an organic rechargeable magnesium battery with a high-voltage discharge platform, which comprises a positive electrode, a negative electrode and an electrolyte, the positive electrode comprises a positive electrode active material, a conductive agent and a binder, and the positive electrode active material is rhubarb free hydroxy anthraquinone; the negative electrode is magnesium metal or magnesium alloy; and the electrolyte is any one of a Mg (HMDS) 2-based electrolyte, a boron-based electrolyte and a Mg (TFSI) 2-based electrolyte. According to the technical scheme, the problems that an existing magnesium ion battery is low in capacity, poor in dynamic performance and low in voltage discharge platform can be solved, and therefore commercialized application and popularization of the magnesium ion battery are promoted.

The invention relates to the field of lithium-sulfur batteries, and discloses a preparation method of a lithium-sulfur battery diaphragm modification material, and the preparation method comprises the following steps: 1, 5-diamino-4, 8-dihydroxy anthraquinone (DADHAQ) and 2, 4, 6-triformyl phloroglucinol (TP) are subjected to a Schiff base reaction to prepare DHAQ-COF and DHAQ-COF-atCNT composite materials; and preparing a modified diaphragm through a vacuum filtration method to obtain the lithium-sulfur battery modified diaphragm material. The redox sites of the lithium-sulfur battery diaphragm modification material provided by the invention are beneficial to enhancing the adsorption effect on polysulfide, so that the shuttle effect of the polysulfide is inhibited, and the overall electrochemical performance of a lithium-sulfur battery prepared on the basis of the lithium-sulfur battery diaphragm modification material can be remarkably improved.

The application discloses a photosensitizer carrier and a preparation method and application thereof, relates to the technical field of photosensitizer carriers, and discloses the following preparation method of the photosensitizer carrier: 4-carboxyphenyl boronic acid is activated by EDC / NHS, and then is subjected to amidation reaction with PEI to construct an intermediate containing a phenyl boronic acid group; then, under alkaline conditions, the phenyl boronic acid group on the intermediate forms a borate ester bond with ortho diols of 1,2,4-trihydroxyanthraquinone, and a photosensitizer carrier with pH responsiveness is obtained; the prepared photosensitizer carrier has good water solubility, can be combined with a hydrophobic photosensitizer through pi-pi conjugation, and can significantly improve the water solubility of the photosensitizer; the carrier is connected through a pH-sensitive borate ester bond, and can be specifically released in a tumor micro-acidic environment; meanwhile, the boronic acid group can be specifically combined with tumor cells overexpressing sialic acid, and the targeting and safety of drug delivery are improved.

The invention discloses a 9, 10-anthraquinone-(5-substituted salicylaldehyde) Schiff base dibutyltin complex which is a compound with the following structural formula (I): # imgabs0, and tin atoms in the molecule of the compound are of a pentacoordinate triangular bipyramid structure. The inventor also establishes a corresponding preparation method which comprises the following steps: by taking 2-amino-3-hydroxyanthraquinone, 5-substituted salicylaldehyde and dibutyltin oxide as raw materials and absolute methanol as a solvent, reacting under the condition of heating reflux. Researches show that the 9, 10-anthraquinone-(5-substituted salicylaldehyde) Schiff base dibutyltin complex has good inhibitory activity on human lung cancer cells, human liver cancer cells, human breast cancer cells and human oral cancer, and the in-vitro anticancer activity of the 9, 10-anthraquinone-(5-substituted salicylaldehyde) Schiff base dibutyltin complex is remarkably superior to that of a classic metal anticancer drug cis-platinum. Therefore, the compound has potential application value in research and development of anti-cancer drugs for human lung cancer, human liver cancer, human breast cancer and human oral cancer. In conclusion, the anthraquinone dibutyltin complex is good in anticancer activity, low in cost and simple in preparation method, and a new way is provided for developing new anticancer drugs.

The utility model relates to the field of dye proportioning, and discloses a 1, 4-dihydroxy anthraquinone raw material accurate proportioning device which comprises a mixing tank for mixing dihydroxy anthraquinone, a bottom plate and a proportioning mechanism, the bottom plate is provided with a mixing tank, the top of the mixing tank is provided with a proportioning mechanism, the mixing tank is fixedly provided with a control panel, and the proportioning mechanism is connected with the control panel; the proportioning mechanism comprises a plurality of storage boxes, a feeding roller, an adjusting block, a circular plate, a threaded rod, a rotating plate, a motor, a sealing ring and a guide plate, and the plurality of storage boxes are fixedly mounted at the top of the mixing tank. The quantitative feeding device has the following advantages and effects that the effect of automatically and quantitatively adding raw materials can be achieved through cooperation of all the components, then the effect of accurately proportioning the 1.4 dihydroxy anthraquinone raw materials is achieved, and the effect of adjusting the sizes of the three quantitative grooves according to the requirements of a user can be achieved.

The invention provides a washing device for synthesizing a 1, 4-dihydroxy anthraquinone leuco body. Relates to the technical field of chemical equipment, in particular to a washing device for 1, 4-dihydroxy anthraquinone leuco body synthesis, which comprises a mounting box, a water storage tank I, a water storage tank II, a water storage tank III and a water storage tank IV are respectively arranged around the mounting box, a drain pipe is fixedly mounted on the water storage tank I, a water inlet pipe is fixedly mounted on the water storage tank IV, and a water outlet pipe is fixedly mounted on the water inlet pipe. Conveying pipes are fixedly installed at the bottoms of the second water storage tank, the third water storage tank and the fourth water storage tank, three water pumps are arranged among the first water storage tank, the second water storage tank, the third water storage tank and the fourth water storage tank, and water inlets of the three water pumps are fixedly connected with the top ends of the three conveying pipes correspondingly; and connecting pipes are fixedly mounted on water outlets of the three water pumps. The washing machine has the advantages that the washing efficiency can be guaranteed through step-by-step cleaning, water consumption is reduced, the washing efficiency is improved, meanwhile, the washing machine is more environmentally friendly, and the whole washing process is more coherent and continuous.

The application discloses a kind of targeted nano photosensitizer carrier and its preparation method and application, it is related to photosensitizer carrier technical field, the preparation method of the targeted nano photosensitizer carrier is as follows: after 4-carboxyl phenylboronic acid is activated, drop into the methanol solution of polyethyleneimine, phenylboronic acid modified polyethyleneimine is obtained by reaction;It is dissolved in phosphate buffer solution, drop into the methanol solution of 1,2,4-trihydroxy anthraquinone, and avoid light reaction to obtain anthraquinone-boronate modified polyethyleneimine;It is activated and reacted with folic acid solution, and is obtained;The targeted nano photosensitizer carrier prepared can stably load photosensitizer containing aromatic ring structure, realizes light-controlled release and pH response, can also specifically recognize tumor cells with high expression of folic acid receptor, and has wide application prospect in the field of photodynamic therapy.

This invention discloses a high-efficiency dehydration device for dihydroxyanthraquinone, comprising a reaction vessel, a control box fixedly mounted on one side of the reaction vessel, a motor fixedly mounted on the top of the reaction vessel, a stirring rod fixedly mounted at the output end of the motor, and an addition mechanism for convenient quantitative addition of materials at the top of the reaction vessel. The addition mechanism includes a storage component, an electronic scale, a support plate, a collection box, an injection pipe, and a first solenoid valve. In use, the storage component pours dry-based sulfonic acid resin into the collection box, while the electronic scale weighs the resin until the desired weight is reached. At this point, the first solenoid valve opens, allowing the dry-based sulfonic acid resin in the collection box to be injected into the reaction vessel through the injection pipe. This utilizes the dry-based sulfonic acid resin to absorb moisture, thereby reducing the amount of sulfuric acid used and further reducing the amount of acidic wastewater, thus saving resources. Simultaneously, the electronic scale allows for convenient control of the amount of dry-based sulfonic acid resin added.

The present application relates to the technical field of dyes, in particular to a high-weather-resistance washable macromolecular dye. The high-weather-resistance washable macromolecular dye is prepared by condensation reaction of 1-amino-2-bromo-4-hydroxy-9,10-anthraquinone and polyethylene glycol under alkaline conditions based on the hydrophilicity of polyether chain and the stability of anthraquinone skeleton. The prepared high-weather-resistance washable macromolecular dye has the characteristics of bright color, easy washing, good light resistance and strong oxidation resistance, and has a wide range of applications, especially for educational ink and daily chemical products.

The invention belongs to the technical field of chemical dye production, and particularly discloses a process for producing solvent blue 104 by a solvent method, which comprises the following steps: adding N-methyl pyrrolidone as a solvent into a condensation reaction kettle, sequentially adding p-tritoluidine, 1, 4-dihydroxy anthraquinone, a 1, 4-dihydroxy anthraquinone leuco body, boric acid and salicylic acid, closing the kettle, heating, keeping the temperature, and cooling to room temperature to obtain the solvent blue 104. And transferring to an oxidation kettle after a side end point, adding potassium hydroxide in batches, introducing air for reaction, cooling, filtering, washing and drying to obtain a finished product, collecting, filtering and washing liquid, and recovering the N-methyl pyrrolidone solvent for reuse. According to the method, N-methyl pyrrolidone used in the production process of the solvent blue 104 is recycled, so that waste of production resources is avoided, pollutants generated by a solvent in wastewater are reduced, and the production cost is reduced.

The utility model belongs to the technical field of production of chemical intermediates, and particularly discloses a system for recovering phthalic anhydride from 1, 4-dihydroxy anthraquinone production mother liquor, which comprises a flocculent precipitation system, a hot melting neutralization system and a crystallization separation system, the flocculation precipitation system comprises a mother liquor cooling kettle and a first filter press, the hot dissolution neutralization system comprises a hot dissolution kettle and a second filter press, the crystallization separation system comprises a crystallization kettle, a centrifugal machine and a drying machine, the input end of the crystallization kettle is communicated with a sulfuric acid feeding tank, the output end of the crystallization kettle is communicated with the centrifugal machine, and the material output end of the centrifugal machine is communicated with the input end of the drying machine. The output end of the dryer communicates with a finished product collecting tank; the filter cake output end of the first filter press is communicated with the input end of the hot dissolving kettle, and the filtrate output end of the second filter press is communicated with the input end of the crystallization kettle. According to the device disclosed by the utility model, the phthalic anhydride is recycled after decoloring and flocculating, neutralizing and dissolving, crystallizing and separating the phthalic anhydride, centrifuging and drying in sequence, so that the phthalic anhydride in the mother liquor is prevented from being wasted.