32 results about "Nickel phthalocyanine" patented technology

The invention belongs to the technical field of preparation of aviation kerosene, and particularly relates to a preparation method of a hydrodeoxidation isocatalyst, a hydrodeoxidation isocatalyst and application thereof. Carbon nanotubes are modified by nickel phthalocyanine so as to introduce Ni and N elements into the carbon nanotubes, iron phthalocyanine is added to cooperate with the nickel phthalocyanine, and the modified carbon nanotubes are added into a SAPO-11 synthetic gel in the form of a gel component, so that the synthesized SAPO-11 has more abundant pores and higher acid strength; and by introducing the Ni, Fe and N, the synthesized molecular sieve has the hydrodeoxidation activity, so that the synthesized NiFeCNTSAPO-11 can be directly used as a biological aviation kerosene catalyst for hydrogenating vegetable oil, thereby omitting the step of impregnating active components into the support and simplifying the preparation procedure. Besides, the hydrodeoxidation isocatalyst has high catalytic efficiency and high biological aviation kerosene yield (up to 78-85%).

The invention discloses a nano silicon-carbon composite material for the negative electrode of a lithium battery. The composite material is prepared from the following raw materials in parts by weight: 52 to 58 parts of nano silicon powder, 125 to 130 parts of phenylaminomethyltriethoxysilane, 80 to 85 parts of graphite, 2500 to 3000 parts of ethylene diamine, 400 to 450 parts of 4-dimethylamino pyridine, 230 to 270 parts of dimethyl sulfoxide, 28 to 32 parts of nano sodium chloride powder, and 34 to 37 parts of nickel phthalocyanine. The provided composite material has a good circulation performance and charge-discharge performance and an important market value and social value, and will not become agglomerated during the preparation process, nano silicon is fully dispersed, and the properties of the material are guaranteed.

The invention discloses a preparation method of a nickel phthalocyanine / copper phthalocyanine / activated carbon Li / SOCl2 battery positive electrode catalytic material. The method comprises the following steps of respectively grinding and then mixing phthalic anhydride, pitch coke activated carbon, urea, ammonium molybdate tetrahydrate, nickel chloride hexahydrate and copper chloride dihydrate to obtain a mixture; putting the mixture into a crucible, carrying out solid-phase sintering at 110-290 DEG C, and cooling to room temperature to obtain a crude product; and grinding the crude product, purifying and drying to obtain the nickel phthalocyanine / copper phthalocyanine / activated carbon Li / SOCl2 battery positive electrode catalytic material. The prepared positive electrode catalytic materialhas the excellent catalytic performance for the Li / SOCl2 batteries.

The invention belongs to the technical field of preparation of aviation kerosene, and particularly relates to a preparation method of a hydrodeoxidation isocatalyst, a hydrodeoxidation isocatalyst and application thereof. Carbon nanotubes are modified by nickel phthalocyanine so as to introduce Ni and N elements into the carbon nanotubes, iron phthalocyanine is added to cooperate with the nickel phthalocyanine, and the modified carbon nanotubes are added into a SAPO-11 synthetic gel in the form of a gel component, so that the synthesized SAPO-11 has more abundant pores and higher acid strength; and by introducing the Ni, Fe and N, the synthesized molecular sieve has the hydrodeoxidation activity, so that the synthesized NiFeCNTSAPO-11 can be directly used as a biological aviation kerosene catalyst for hydrogenating vegetable oil, thereby omitting the step of impregnating active components into the support and simplifying the preparation procedure. Besides, the hydrodeoxidation isocatalyst has high catalytic efficiency and high biological aviation kerosene yield (up to 78-85%).

The invention discloses a graphene / phthalocyanine supercapacitor electrode material, and a preparation method thereof. The method mainly comprises the following steps: obtaining graphene oxide (GO) through the chemical oxidation method, and using p-phenylenediamine (pPD) as a reducing agent to obtain reduced GO-pPD (rGO-pPD) under the action of strong ammonia water; and carrying out azo-coupling reaction of the rGO-pPD and 2,9,16,23-tetraamino nickel (II) phthalocyanine (NiTAPc) with outstanding photoelectric property to obtain a covalently grafted binary composite material, i.e., rGO-p-Pc. The material and the preparation method thereof provided by the invention have the advantages that the method is simple and convenient to operate, and the yield rate reaches 95%; and the specific capacitance of the electrode material reaches 600F.g<-1>, and the cyclic stability is high.

The invention discloses a method for printing a graphene / silver composite pattern by using a phthalocyanine nickel complex in a micro contact manner. The phthalocyanine nickel complex is prestox phthalocyanine nickel. The method comprises the following steps: by taking a dichloromethane solution of prestox phthalocyanine nickel as a printing agent of the micro contact printing, transferring a pattern of a PDMS seal to a polyimide substrate, further adsorbing and reducing graphene and silver, and finally obtaining delicate metal patterns on the substrate. By using the micro contact printing method, the graphene patterns can be printed on the surface of the polyimide substrate which is frequently used in the electronic industry, and a novel idea is provided for the micro contact printing industry.

The method of making thin film humidity sensors uses thermal vapor deposition or drop casting techniques to fabricate nickel phthalocyanine-fullerene-based (NiPc-C60) quick response humidity sensors with negligible hysteresis. Prior to the deposition of aluminum electrodes, a glass substrate is cleaned by using acetone in an ultrasonic bath for 10 minutes. After cleaning, the substrate is washed with de-ionized water and then dried. A gap is created between two electrodes by masking the glass substrate with copper wire. This assembly is plasma-cleaned for 5 minutes in a thermal evaporator. Subsequently aluminum (Al) thin films are deposited on the assembly. Next, a mixture of equal parts NiPc-C60 is deposited onto the gap between the Al electrodes by thermal vapor deposition or by drop casting. A method of forming NiPc-graphene oxide (NiPc-GO) humidity sensors without using instrumentation drop casts an NiPc-GO suspension onto aluminum foil electrodes taped to a substrate.

The invention discloses a nano silicon-carbon composite material for the negative electrode of a lithium battery. The composite material is prepared from the following raw materials in parts by weight: 52 to 58 parts of nano silicon powder, 125 to 130 parts of phenylaminomethyltriethoxysilane, 80 to 85 parts of graphite, 2500 to 3000 parts of ethylene diamine, 400 to 450 parts of 4-dimethylamino pyridine, 230 to 270 parts of dimethyl sulfoxide, 28 to 32 parts of nano sodium chloride powder, and 34 to 37 parts of nickel phthalocyanine. The provided composite material has a good circulation performance and charge-discharge performance and an important market value and social value, and will not become agglomerated during the preparation process, nano silicon is fully dispersed, and the properties of the material are guaranteed.

The invention discloses a spectrophotometric method for quantifying the total lipid content and the application thereof. According to the depolymerization mechanism of lipid on a phthalocyanine aggregate, tetra-sec-octyloxy nickel phthalocyanine is used as a colorimetric material, and petroleum ether is used as a solvent to accurately quantify the total lipid content. The method comprises the steps that (1) according to standard curve preparing, a phthalocyanine solution of specific concentration is prepared; squeezed peanut oil is used as the standard lipid, and an oil-free solution is used as a reference; analyzing is carried out at 675 nm; coordinate points between the absorbance and the peanut oil concentration are fitted to acquire a linear equation; (2) according to lipid extraction,a sample to be analyzed is weighed, extracted, distilled and weighed, and lipid is recovered; and (3) according to total lipid quantifying, the phthalocyanine solution of 2.5 mL is taken and mixed with the recovered lipid sample of 0.5 mL; a lipid-free sample solution is used as a reference; analyzing is carried out at a characteristic wavelength; the absorption of the lipid sample of the same volume is removed; substituting into a linear equation is carried out; the lipid concentration, the corresponding lipid quality and the total lipid content are calculated. Compared with a traditional extraction / weighing method, the method is more accurate and can avoid the influence of a residual solvent in the recovered sample.

The invention discloses a preparation method and application of a high-efficiency carbon nanosheet supported fuel cell positive electrode material. According to the method, the NiCo alloy nanoparticleloaded carbon nanosheet supported electrode material is directly generated on the surface on the basis of maintaining the morphology of the amorphous Co-B nanosheet by utilizing carbonization of nickel phthalocyanine and the Co-B nanosheet under high temperature and reduction reaction of metal ions under the premise that BH4- reduces Co2+ ion to synthesize a Co-B amorphous template. With application of different kinds of metal phthalocyanines, the metal composition of alloys can be controlled effectively. Furthermore, NiCo@BNC-800 having the nanosheet morphology exhibits excellent performance. In the oxygen reduction reaction of the fuel cell positive electrode, the starting potential is 1.03 V and the half-wave potential is 0.85 V, which is higher than that of commercial Pt / C electrode.Meanwhile, the stability and the methanol resistance of the composite electrode are better than those of the commercial Pt / C electrode. A general and simple method can be provided for synthesizing thehigh-efficiency fuel cell positive electrode material.

The invention discloses a spectrophotometric method for quantifying total lipid content and its application. According to the depolymerization mechanism of lipids to phthalocyanine aggregates, tetra-sec-octyloxynickel phthalocyanine is used as a colorimetric material and petroleum ether is used as a solvent. Quantification of total lipid content. There are three steps: (1) Make a standard curve. Prepare a specific concentration of phthalocyanine solution, use pressed peanut oil as standard lipid, and oil-free sample solution as reference, analyze at 675nm, and fit the coordinate points between absorbance and peanut oil concentration to obtain a linear equation. (2) Lipid extraction. Weigh the sample to be analyzed, extract, evaporate the solvent and weigh to recover the lipid. (3) Total lipid quantification. Take 2.5mL of phthalocyanine solution, mix it with 0.5mL of the recovered lipid sample, and use the lipid-free sample solution as a reference, analyze at the characteristic wavelength, remove the absorption of the same volume of lipid sample, and substitute into the linear equation to calculate the lipid concentration and the corresponding lipid amount and total fat content. Compared with the traditional extraction / weighing method, this method is more accurate and can avoid the influence of residual solvent in the recovered sample.

A black-color polymer composite film comprising a phthalocyanine compound dispersed in a polymer selected from the group consisting of polyimide, polyamide, polyoxadiazole, polybenzoxazole, polybenzobisoxazole, polythiazole, polybenzothiazole, polybenzobisthiazole, poly(p-phenylene vinylene), polybenzimidazole, polybenzobisimidazole, and combinations thereof, wherein the phthalocyanine compound occupies a weight fraction of 0.1% to 50% based on the total polymer composite weight. Preferably, the phthalocyanine compound is selected from copper phthalocyanine, zinc phthalocyanine, tin phthalocyanine, iron phthalocyanine, lead phthalocyanine, nickel phthalocyanine, vanadyl phthalocyanine, fluorochromium phthalocyanine, magnesium phthalocyanine, manganous phthalocyanine, dilithium phthalocyanine, aluminum phthalocyanine chloride, cadmium phthalocyanine, chlorogallium phthalocyanine, cobalt phthalocyanine, silver phthalocyanine, a metal-free phthalocyanine, or a combination thereof.

The invention discloses a method for preparing a graphene / carbon nanotube composite material by solid-phase cracking technology. The heating method is to raise the temperature to the pyrolysis autocatalysis temperature, and obtain the final graphene / carbon nanotube composite material by one-step pyrolysis. Using nickel phthalocyanine compound and its derivatives as the only starting material, one-step solid-phase cracking to obtain azagraphene / carbon nanotube composite materials; the cracking temperature is low, saving energy consumption; using inert gas protection, it can be used in a non-hydrogen atmosphere environment The final material is obtained by medium pyrolysis, which has high safety; the nitrogen atoms of the molecular skeleton of the raw material compound remain in the final graphene / carbon nanotube composite skeleton after high temperature pyrolysis, becoming a better conductive material.

The invention discloses a CdS / NiPc photocatalyst which can be used for photolysis of water and a preparation method thereof, belonging to the technical field of photocatalysis. In the present invention, cadmium sulfide seeds are formed in a diethylenetriamine (DETA) solvent, and then nickel phthalocyanine (NiPc) with different contents is added to effectively disperse NiPc, and a CdS / NiPc photocatalyst is synthesized in situ by a solvothermal method, and the introduction of NiPc It is not only beneficial to broaden the visible light response range, but also beneficial to the separation and transfer of photogenerated charges, thereby enhancing the photocatalytic activity. The synthesis method has simple process, easy operation and low cost. The as-prepared CdS / NiPc photocatalyst has excellent performance of photo-splitting water for hydrogen production.