232 results about "Oxalate salt" patented technology

This invention relates to a method for preparing olivine-type phosphate-series lithium ion battery anode material. The method comprises: mixing one or more of ferrous salt solution, cobalt salt solution and manganese salt solution with oxalic acid or oxalate (precipitating agent) aqueous solution to obtain composite oxalate precursor, uniformly mixing with lithium source and phosphorus source by ball milling, and reacting in inert or weak-reductive atmosphere to obtain olivine-type phosphate-series lithium ion battery anode material. The method utilizes co-precipitation method for metal ion doping, and realizes molecular level uniform mixing among different ions. The obtained olivine-type phosphate-series lithium ion battery anode material has uniform chemical and physical compositions. The average particle size can be controlled within 0.3-10 mu.m. The first charge and discharge cycle specific capacity can reach 150 mAh/g at 0.1 C rate and room temperature. The livine-type phosphate-series lithium ion battery anode material has such advantages as high cycle performance and high charge/discharge performance.

The use of lithium bis(oxalate)borate (LiBOB) as an additive in a lithium secondary battery provides improved battery performance such as long life and high capacity retention after high temperature storage.

The invention relates to a method for preparing a lithium-enriched lithium manganese oxide solid solution cathode material. The method comprises the following steps of: adding a mixed aqueous solution of nickel salt, cobalt salt and manganese salt into an oxalic acid or oxalate aqueous solution by an oxalate coprecipitation high-temperature solid state method, and stirring and reacting to generate nickel, cobalt and manganese oxalate coprecipitation; performing solid and liquid separation, washing and drying to obtain a nickel, cobalt and manganese oxalate precursor; and mixing and grinding the precursor and lithium salt, drying, baking at high temperature in an air atmosphere, and thus obtaining the lithium-enriched lithium manganese oxide solid solution cathode material. During preparation of the precursor, the proportion of the nickel salt, the cobalt salt and the manganese salt is adjusted, so that the constituents of the lithium-enriched lithium manganese oxide solid solution cathode material can be adjusted flexibly. The preparation method is suitable for large-scale, economic, stable and reliable production of the lithium-enriched lithium manganese oxide solid solution cathode material, has obvious advantages, and is high in practical value.

The invention relates to a formula and a corresponding preparation technology of a normal temperature formaldehyde removal catalysis material, and belongs to the technical fields of normal temperature adsorption catalysis and air pollution treatment. The catalysis material is prepared by adopting a one-step co-precipitation process or a step-by-step dipping process to load active components with granular, cylindrical, spherical or honeycomb high-specific surface area shell activated carbon as a carrier, one or more non-noble metal salts as main active components, such as nitrate, sulfate or chloride of manganese, iron, cobalt, nickel, copper, zinc, lanthanum or cerium, one or more alkali metal/ alkaline earth metal salts as an inorganic additive, such as oxalate, nitrate, sulfate, acetate, carbonate and bicarbonate of sodium, potassium, magnesium, calcium, and ethylenediamine tetracetic acid/ethylenediamine tetraacetic acid salt, basic amino acid, polyamide monomer and polyurethane monomer as a nitrogen-containing organic additive. The normal temperature formaldehyde removal catalysis material has the characteristics of rapid capture, high efficiency catalytic oxidation and long working cycle, and can meet requirements of long-time effective removal of formaldehyde in indoor real environment.

Organic lithium salts suitable for use in electrolytes for primary or secondary rechargeable batteries include de-localized bulky anions over Lewis acid fragments, typically BF₃, and organic moieties. The organic moieties may be, for example, anions derived from fused nitrogen heterocycles (e.g. benzeneimidate, benzitriazolate and the like); multi carboxylates (e.g. oxalate, 1,2,4,5-benzenetetracarboxylate and the like), and pyromellitic diimidate. The organic lithium salts of the invention have the general formula: Li_q[Org(MX_n)_m], in which Org represents the organic moieties and MX_n represents an organic or inorganic boron, aluminum or phosphorous containing Lewis acid. The organic lithium salts are conveniently prepared by reacting an organic compound having at least one de-protonation group selected from NH, OH, SH or COOH with an inorganic or organic lithium compound to generate an organic lithium processor salt, and thereafter bringing the organic lithium processor salt into contact with an inorganic or organic Lewis acid to obtain the organic lithium product salt.

ABSTRACT Rare earth oxides capable of being re-used as an abrasive are recovered from an abrasive waste liquid by a process comprising the steps of (1) mixing and heating a rare earth element-containing waste liquid with an acid, to dissolve rare earth elements contained in the liquid; (2) removing insoluble matter from the rare earth element solution; (3) incorporating a soluble carbonate salt or a soluble hydrogencarbonate salt, or an oxalic acid in the rare earth element solution, to convert the rare earth elements to rare earth carbonates or rare earth oxalates; (4) separating the rare earth carbonates or rare earth oxalates from a slurry of the rare earth carbonates or rare earth oxalates; (5) baking the separated rare earth carbonate or rare earth oxalate to produce rare earth oxides; and (6) recovering the rare earth oxides.

The invention discloses a method for preparing a cerium oxide-zirconium oxide based composite rare-earth oxide. The method comprises the following steps of: (1) heating a zirconium salt solution at room temperature, slowly adding sulfate ions, controlling the temperature rise rate so that the temperature is increased in the range of 90-95 DEG C when the sulfate ions are added completely, and then preserving heat for 20-100 minutes, thereby forming a zirconium basic sulfate composite salt precursor; (2) adding a cerium salt and a rare-earth metal salt to the precursor solution and stirring evenly, thereby obtaining a slurry; (3) settling the slurry by using basic carbonate and/or a basic oxalate solution, thereby obtaining a precipitate; and (4) filtering and washing the precipitate obtained in the step (3), removing purities, and calcining the washed precipitate. The cerium oxide-zirconium oxide based composite rare-earth oxide prepared by the method by controlling raw materials and process conditions has the characteristics of being high in total fine pore volume, high in fresh specific surface area, high in oxygen storage capacity and the like.

The invention relates to an oxalate coprecipitation preparation method for a high-capacity lithium-rich cathode material. The preparation method is characterized by comprising the following concrete steps: dissolving soluble Ni salt, or Co salt and Mn salt, or Ni salt, Co salt and Mn salt in a proper amount of deionized water according to a stoichiometric ratio to prepare a metal salt solution with certain concentration, dissolving oxalate or oxalic acid in deionized water to prepare an oxalate solution with certain concentration, mixing the metal salt solution with an oxalate or oxalic acid solution in a way of straight adding, reverse adding or combined adding, adjusting the pH value of a mixed solution to be in a range of from 6.5 to 8.5, allowing a coprecipitation solution to be formed, and carrying out filtration with filter paper, rinsing with deionized water and drying on the coprecipitation solution so as to obtain precipitation precursor; and subjecting excess Li salt and the precipitation precursor in a certain stoichiometric ratio to ball milling and mixing and carrying out high temperature sintering so as to obtain an xLi2MnO3.(1 - x)LiMO2 (wherein M is Co, Ni1/2Mn1/2 or Ni1/3Co1/3Mn1/3) material at last. The method costs little and does not need a high temperature in preparation of a lithium-rich material and allows the shape and the size of the prepared material to be easily controllable.

The invention brings forward a preparation method of mesoporous nickel cobaltate fiber. According to the preparation method, an organic solvent is added during the preparation process of a precursor; a mixed phase of a water phase and an organic phase is used as a solvent, soluble nickel salt and cobalt salt are used as raw materials, and oxalate is used as a precipitating agent; in a system of Ni<2+>-Co<2+>-NH3-NH4<+>-SG<n->-C2O4<2->-H20-C2H5OH, a fibrous precursor is prepared; and the fibrous precursor is subjected to thermal decomposition in the air atmosphere at 250-400 DEG C so as to obtain the mesoporous NiCo2O4 fiber. According to the invention, coprecipitation based on the Ni-Co ratio set in the raw materials is effectively realized. The prepared NiCo2O4 powder is a cubic phase, has high purity and large specific surface area, is fibrous and porous, and is applicable to be used as a catalyst or an alkaline solution oxygen-evolution/hydrogen-evolution electrode material or direct alcohol fuel cell anode catalyst. The method provided by the invention is simple to operate and easy to control, has advantages of mild condition and low cost, and is suitable for commercialized production.

A production process which comprises subjecting a basic antibiotic.oxalate (II) to salt-exchange with an alkali earth metal salt (III) of an inorganic acid:wherein the ring A means the basic antibiotic; R<10 >means a protected functional group used in organic synthesis; Ak-E means the alkali earth metal; and B means the inorganic acid, respectively.

The invention discloses a blood sample collecting device. The collecting device comprises a collecting tube, wherein an orifice of the collecting tube is provided with a sealing rubber plug, the outside of the rubber plug is provided with a protective cap, the collecting tube is filled with additives, the additives are composed of a blood anticoagulation, a hemocyte nucleic acid stabilizing agent, a blood plasma nucleic acid stabilizing agent, and a pH buffer solution; the blood anticoagulation is one or more of oxalate, heparinate and citrate, the pH buffer solution is one of glycine-sodium hydroxide-hydrochloric acid buffer solution; the hemocyte nucleic acid stabilizing agent is one or more of allantoin, 5,5-dimethyl hydantoin and oxazolidine; the blood plasma nucleic acid stabilizing agent is N-acetic acid azomethine, N-(3-acetic acid-amylamine)azomethine. The blood sample collecting device simultaneously contains the hemocyte nucleic acid stabilizing agent and the blood plasma nucleic acid stabilizing agent, and does not contain free aldehyde material, so that the blood sample can be stored in long term at normal temperature, and the free nucleic acid level of the blood sample can be stabilized, and the completeness of the free nucleic acid can be maintained.

The invention relates to a ferrite nanometer superstructure porous material and a method for preparing the same, in particular to a method for preparing a nickel ferrite, cobalt ferrite or zinc ferrite nanometer superstructure porous material. The preparation method comprises that: sodium oxalate is used as a precipitator, the soluble nickel, cobalt or zinc salt used as a raw material reacts with the soluble iron salt to prepare a precursor of oxalate, and the precursor is degraded by calcination at certain temperature to obtain the nickel ferrite, cobalt ferrite or zinc ferrite nanometer superstructure porous material. The nickel ferrite, cobalt ferrite or zinc ferrite nanometer superstructure porous material synthesized by the method has the advantages of high purity, uniform size, good dispersibility, mild reaction conditions, simple equipment, easily controlled process conditions and low cost, and meets the need of the actual production.

The invention provides a method for preparing a silica antireflective film, which comprises the following steps of: a) uniformly mixing a tetraethoxysilane and absolute ethyl alcohol-containing system, and preparing silica sol under the alkaline condition through a sol-gel method, wherein the system also comprises one or more of soluble carbonate, bicarbonate, citrate, tartrate and oxalate; and b) coating the silica sol prepared in the step a) and performing heat treatment so as to prepare the silica antireflective film. By the provided preparation method, an antireflective film with the refractive index of 1.18 to 1.32 and the light transmittance of 97 to 99 percent can be stably prepared, the technology is simple and controllable, and the repeatability is high.

A preparation method for yttrium gadolinium europium oxide red fluorescent powder applicable to a 3D PDP (Plasma Display Panel) comprises the steps as follows: a rare earth oxalate coprecipitation body is prepared by adopting a coprecipitation method, rare earth metal oxide is balanced and dissolved in nitric acid or chlorhydric acid to form a rare earth metal salt solution; an oxalic acid solution or a carbonate solution is prepared and added into the rare earth metal salt solution to obtain rare earth metal oxalate or a carbonate precipitate; the carbonate precipitate is filtered and isolated, dried and burned to obtain a rare earth oxide coprecipitation body; the coprecipitation body is oxidized and burned to form a yttrium gadolinium europium oxide red fluorescent powder burned body; the rare earth oxide coprecipitation body is added with a cosolvent and is loaded in an aluminum oxide crucible and is burned under high temperature in an oxidizing furnace; after burned, the rare earth oxide coprecipitation body is shattered after burning to obtain a yttrium gadolinium europium finished product; and finally, the yttrium gadolinium europium oxide red fluorescent powder is obtained according to a downstream treatment process. The fluorescent powder prepared according to the method has the advantages of high lighting brightness, good color purity, complete crystal morphology, small powder center particle size, simple manufacturing method and low production cost, and is suitable for industrial production.

The invention discloses a preparation method of a high-specific-surface CuMn2O4 catalyst for CO low-temperature oxidation removal. The method comprises the steps that soluble copper salt and soluble manganese salt with the mole ratio being 1:2 are prepared into a solution with the total mole concentration of 0.21-0.45 mol/L, then, an ammonium oxalate solution with the mole concentration of 0.3-0.5 mol/L is added, the mixture continues to be stirred and is dried at the temperature of 60-90 DEG C after being precipitated and washed to obtain a copper manganese oxalate precursor, and the copper manganese oxalate precursor is heated at the heating speed of 0.5-2 DEG C/min to 300-400 DEG C to be roasted for 0.5-3 h to obtain the spinel type CuMn2O4 catalyst. The prepared CuMn2O4 catalyst has the advantages of being large in specific surface, simple in preparation process, convenient to operate, good in repeatability and the like, can achieve oxidization removal of CO in air within the wide temperature range, and has the quite good stability.

The invention relates to a preparation method of nickel coated copper composite powder. The preparation method comprises the following process steps that copper salt and oxalate or carbonate take reaction to generate cupric oxalate or copper carbonate sediments, the filtering is carried out, pure water is used for flushing to be in a neutral state, and solution with the concentration being 10 to 80g/L is prepared; and nickel salt solution and the required oxalate or carbonate solution are prepared according to a proportion that the copper nickel weight ratio is 2:1 to 1:2 and are added into the cupric oxalate or copper carbonate solution for reaction to generate nickel coated copper resultants. The preparation method has the advantages that firstly, nickel salts are used for coating copper salts, then, the thermal decomposition is carried out, nickel coated copper powder is obtained, the production process is simple, the operation is easy, the production cost is low, and the industrial production can be realized. The nickel coated copper powder or alloy prepared by the method has the morphology in a spherical shape, a near-spherical shape, an irregular shape or a tree branch shape, and has the advantages that the powder dispersion is uniform, no segregation is generated, the coating effect is good, the coating is compact, the particle size is controllable, and the like. The nickel coated copper powder or alloy can be used for electromagnetic shielding materials and powder metallurgy prealloyed powder. The preparation method can be used for preparing nickel-copper alloy powder.

The invention discloses a lubricant for cold forging and cold extruding and a preparation method and a using method thereof. The lubricant comprises distilled water, sodium carboxymethylcellulose, sodium polyacrylate, polymethacrylate, mica powder, talc powder, boron nitride, zinc stearate, sodium stearate, alkyl sodium sulfonate, diglycol, triethanolamine, polyvinylpyrrolidone, vinyl triethoxy silane, polyisobutene, polyethylene glycol, nonyl phenol polyoxyethylene ether, an ethylene-vinyl acetate copolymer, an alkaline silica sol, sodium silicate, a styrene-acrylic emulsion, oxalate, vulcanized fat, alkylated aromatic amine and sodium methylenedinaphthalene. The lubricant disclosed by the invention can adsorb a uniform plastic film formed on the surface of a workpiece, so that the workpiece and a mold are isolated by the lubricating film all the way, and the lubricant is good in environmental friendliness and convenient to use, can replace a phosphorizing-saponifying treatment process, and is a non-graphite high molecular lubricant suitable for cold forging and cold extruding forming of metals or nonferrous metals.

The invention relates to the technical field of chemical catalyzing, in particular to application of tungsten-based solid acid in lactic acid and lactate preparation using biomass and saccharides. Tungsten-containing salt is allowed to have hydro-thermal synthesis reaction with the chlorine salt, sulfate, nitrate, phosphate and oxalate of barium, calcium, lead, aluminum, chromium, erbium, tin, germanium, niobium and tantalum to prepare a multiple-component tungsten-based solid acid catalyst. The multiple-component tungsten-based solid acid catalyst is simple to prepare, cheap, good in hydrothermal stability, easy to recycle, capable of catalyzing monosaccharides such as fructose and glucose to convert into the lactic acid or lactate, capable of catalyzing polysaccharides such as sucrose, maltose, starch and cellulose even biomass such as wood and corn straw containing cellulose to have hydrolysis reaction so as to prepare the lactic acid or lactate, promising in application prospect and the like, multi-step reaction catalyzing by one single catalyst is achieved, and the range of the biomass and the saccharides which can be converted by the catalyst is wide.

The invention discloses a manganese-based layered lithium-enriched material having a one-dimensional porous structure and a preparation method of the manganese-based layered lithium-enriched material. The preparation method comprises the following steps: adding cetyl trimethyl ammonium bromide into oxalic acid solutions under a stirring condition, and adding n-amyl alcohol, cyclohexane and a mixed solution of manganese salt and cobalt salt to obtain an oxalate micro-nanometer rod with the one-dimensional structure; preparing the oxalate micro-nanometer rod with the one-dimensional structure into a manganese-cobalt oxide micro-nanometer rod having a one-dimensional porous structure; and finally, performing reaction on the manganese-cobalt oxide micro-nanometer rod having the one-dimensional porous structure and a proper amount of lithium sources to obtain the manganese-based layered lithium-enriched material having the one-dimensional porous structure. The manganese-based layered lithium-enriched material having the one-dimensional porous structure is high in specific capacity, high in multiplying power performance and high in cycle performance.