The invention discloses a polyurethane coating layer for aircraft organic glass, and a preparation method thereof, and belongs to the technical field of polyurethane coating layers. The polyurethane coating layer for aircraft organic glass is prepared by mixing raw materials to form a solution, spraying the solution and curing the solution, and the raw materials of the solution comprise 10-15% ofan isocyanate, 3-5% of a diol, 15-20% of a triol, 0.0005% of a catalyst, 0.015% of an antistatic agent, 0.035% of a surfactant, 0.5% of an antioxidant, 1% of an ultraviolet absorber, 0.3% of a leveling agent and 50-70% of an organic solvent. The preparation method of the solution comprises the following steps: 1, adding the isocyanate, the diol, the surfactant and the antistatic agent into a flask. The coating layer has good wear resistance, makes the thickness of a dry film reach 76 [mu]m, has the advantages of high elongation at break, god resistance to impact of raindrops, and excellent weather resistance, and can greatly enhance the wear resistance of aircraft organic glass and prolong the service life of the aircraft organic glass.