The invention discloses
gallium ion imprinted amidoxime-based
macroporous resin as well as a preparation method and application thereof, and belongs to the technical field of functional
polymer materials and separation. The method comprises the following steps: pre-assembling a
gallium trichloride template and monomers such as
acrylonitrile, generating monodisperse liquid drops by utilizing a microfluidic technology, polymerizing by combining
ultraviolet light, eluting the template by
hydrochloric acid, and performing amidoximation modification by a
hydroxylamine hydrochloride alkaline solution, thereby obtaining the resin. The resin is a monodisperse spherical
microsphere, has a macroporous structure, has high selective recognition capability and high adsorption capacity on
gallium ions, is fast in
adsorption kinetics and good in regeneration performance, and is suitable for selectively separating or enriching gallium ions from a complex
solution system.