143 results about "Ammonal" patented technology

The invention provides a process for producing magnesium hydroxide and calcium carbonate by the dolomite conversion method. The process comprises the following steps: calcining dolomite, carrying out a digestion reaction on dolomite and water and refining so as to obtain a refined slurry of calcium hydrate and magnesium hydroxide; reacting the slurry with an ammonium chloride solution to enable calcium hydrate to react with ammonium chloride; carrying out ammonia evaporation so as to obtain a fluid suspension of a calcium chloride solution, ammonia gas and magnesium hydroxide; carrying out filtering and washing so as to obtain a magnesium hydroxide product; carrying out a carbonization reaction on the calcium chloride aqueous solution which has absorbed ammonia gas with kiln gas generated by the calcination of dolomite so as to obtain calcium carbonate; carrying out filtering and washing so as to obtain a calcium carbonate product. In the invention, washing water is used for the digestion of dolomite ashes so as to totally separate magnesium from calcium in dolomite and produce magnesium hydroxide and calcium carbonate products, thereby fully utilizing dolomite. The process provided in the invention enables cyclic utilization of the intermediate product ammonium chloride and no discharge of the three wastes, being in accordance with the developmental requirements for green chemicals in modern society.

The invention discloses a method for preparing alumina by using power plant fly ash, characterized by: grinding the fly ash, leaching with concentrated sulfuric acid to obtain an aluminum sulfate solution, precipitating aluminum sulfate crystals by concentrating and cooling, dissolving the aluminum sulfate crystals with hydrochloric acid, then letting an HCl gas in the solution to saturate the solution to precipitate AlCl3-6H2O crystals, reacting the AlCl3-6H2O crystals with an ammonium hydroxide solution or liquid ammonia or an ammonium bicarbonate solution or an ammonium carbonate solution to obtain an aluminium hydroxide and ammonium chloride solution, calcining aluminium hydroxide to obtain alumina, displacing ammonium chloride by using magnesium oxide to obtain ammonia gas and magnesium chloride, and hydrolyzing magnesium chloride to obtain magnesium oxide and hydrochloric acid for recycling.

The invention provides a new formula and a process method for preparing an electrolytic manganese slag brick, and belongs to the fields of the comprehensive utilization of industrial solid wastes and building materials. At present, the patent technology of preparing the building materials by using manganese slag has the common defect that before alkaline materials such as cement and the like are added, a large quantity of ammonium salts such as ammonium sulfate in the electrolytic manganese slag are not extracted, and the ammonium salts react with the alkaline materials to release a large amount of ammonia during operation, so environmental pollution and the loss of ammonia nitrogen are caused; and before being used, the electrolytic manganese slag is not modified, so the gelatinization activity of the electrolytic manganese slag cannot be well exerted. In order to solve the problem, programs for washing the slag and processing lime slurry and the operations of atomizing and adding a water glass dilute solution are added specially in the process, wherein by the program for washing the slag, the problem of the pollution of the electrolytic manganese slag is solved; and water glass is used as an active initiator for the electrolytic manganese slag serving as gelled materials and a reinforcer for reinforcing the strength of silicate concrete, so that the strength of the electrolytic manganese slag brick serving as a finished product can be reinforced greatly.

The invention relates to methods for coproducing sodium carbonate and ammonium sulfate from melamine tail gas and mirabilite. The method for producing the sodium carbonate comprises the following steps of: a, providing a sodium sulfate water solution; b, introducing melamine tail gas into the sodium sulfate water solution to form an ammonium carbonate-sodium sulfate water solution; c, introducing carbon dioxide into the ammonium carbonate-sodium sulfate water solution to obtain a suspension serous fluid of sodium bicarbonate crystals; and d, carrying out solid and liquid separation on the suspension serous fluid to obtain sodium bicarbonate and a mother solution I, calcining sodium bicarbonate solid to obtain the sodium carbonate. The method further comprises the following steps of: e, adding the mother solution I into an ammonia stilling tower, heating, forming tower top mixed gas containing ammonia and carbon dioxide, generating a deamination solution in the tower; f, evaporating the deamination solution for dewatering to obtain sodium sulfate crystals and a mother solution II; g, cooling the mother solution II for crystallizing to obtain Na2SO4.(NH4)2SO4.4H2O salt crystals and a mother solution III; and h, evaporating the mother solution III for dewatering, and separating out ammonium sulfate crystals. The methods have the advantages of high utilization rate of raw materials and low energy consumption.

The invention provides a method for the combined production of ammonia and basic calcium chloride by decomposing ammonium chloride, which comprises the following steps: grinding or crushing calcareous materials and ammonium chloride according to a mol ratio of 1:0.5-2 in a ball grinder or a crusher at -20-200 DEG C, enabling the calcareous materials and the ammonium chloride to be subject to a chemical reaction to decompose the ammonium chloride so as to release ammonia gas and generate basic calcium chloride. The invention fully uses the large amount of ammonium chloride as the byproducts of the combined soda process and the ammonia soda process, realizes the recycling of ammonia and generates the basic calcium chloride as the byproduct. The invention has the characteristics of simple process, low investment, high conversion rate, no pollution and low energy consumption, is applicable to industrial production and meets the requirements green chemical development in the present society.

The present invention discloses an ammonium metavanadate preparation method, which comprises that: a sodium vanadate solution contacts an ammonium salt under an acid condition, and the contacting product is subjected to precipitation and separation to obtain an ammonium polyvanadate solid; and the ammonium polyvanadate solid contacts water and an ammonium vanadate structure reforming agent to convert the ammonium polyvanadate into ammonium metavanadate, and the contacting product is subjected to solid-liquid separation to obtain an ammonium metavanadate solution, wherein the ammonium vanadate structure reforming agent is one or a plurality materials selected from ammonium carbonate, ammonium bicarbonate and ammonia water. According to the ammonium metavanadate preparation method, ammonium ions of the original ammonium polyvanadate can be completely utilized so as to reduce ammonium salt consumption; alkality of the ammonium vanadate structure reforming agent is completely adopted to achieve ammonium polyvanadate dissolving, such that the sodium salt (sodium hydroxide, sodium carbonate, and the like) is not required to be adopted to dissolve the ammonium polyvanadate so as to simplify steps and reduce cost; and no converted ammonia gas escapes so as to reduce burden on the environment .

The invention discloses a method for preparing ammonia water and calcium chloride solution through the decomposition recovery of ammonium chloride waste liquor. The method comprises the following steps: the waste liquor is pretreated, and ammonium chloride and calcium oxide or calcium hydroxide powder is added into the pretreated ammonium chloride waste liquor; ammonia is distilled from the treated ammonium chloride waste liquor and is transferred into an ammonia absorption tower after being condensed, and a reaction liquid flows out from the bottom of a distillation tower; ammonia is absorbed from the condensed ammonia in the absorption tower by using desalted water, and the tail gas is exhausted after residual ammonia is washed by a tail gas washing tower; reaction liquid out of the bottom of the distillation tower is subjected to flash vaporization for recycling the energy and then is transferred into a clarifying barrel, and the clarified calcium chloride supernatant is used as the target product. According to the invention, the method is particularly suitable for the transformation of ammonium chloride wastewater treatment technology of enterprises in the existing rare earth industry, potassium carbonate industry and baking soda industry, and is simple in process; the ammonia is recycled by using desalted water through multi-stage absorption, and the recovery rate is up to 99%; the high-concentration calcium chloride solution can be used for producing calcium chloride products and the products can be recycled so as to have better economic benefits.

The invention relates to a comprehensive treatment technology of waste aluminum ash, and concretely relates to processes for producing aluminum hydroxide from the waste aluminum ash, producing refractory materials through utilizing waste residues, and producing ammonium chloride through utilizing wastewater and an exhaust gas. The technology is characterized in that a sodium aluminate solution and a plaster are generated through dissolving out the aluminum ash by a cycle alkaline solution having a high concentration Na2Ok 220g/l at a temperature of above 260DEG C under a pressure of above 60kg/cm<3>; the aluminum ash is washed with water to remove most chlorides before the dissolving-out of the aluminum ash by the cycle alkali solution, and the obtained washing solution is used for absorbing ammonia generated in the dissolving-out process; and the plaster generated by the aluminum ash is used for producing refractory bricks or castable materials. A large amount of ammonia is contained in the waste aluminum ash, and ammonium chloride is prepared through recovering the ammonia with a salt washing solution in a cycle mode, so the ammonia pollution is eliminated, and products are prepared from the ammonia. The sodium aluminate solution undergoes crystal seed decomposition to generate an aluminum hydroxide fire retardant and a decomposition mother solution, and the aluminum ash is dissolved after the decomposition mother solution evaporates.

The invention discloses a harmless treatment and utilization method for aluminum ash. On the basis of a conventional process, the method comprises the following steps: additionally pretreating an aluminum ash raw material, namely performing primary disliquid washing treatment on the aluminum ash with a diluted alkali liquid or water, performing gas-water separation on a gas with ammonia gases, hydrogen and acetylene in the disliquid washing process, collecting the gas, recycling the ammonia gases with a diluted acid liquid for preparing an ammonium salt, and utilizing a combustible gas after ammonia removal as fuel of later procedures; dissolving cyanide, dissoluble fluoride and chloride in the aluminum ash into a liquid phase in disliquid washing to form an alkali pretreatment liquid, thereby separating the dissoluble substances from insoluble solid phases in the aluminum ash. Due to addition of a specific procedure of harmless treatment on environment danger sources, main danger sources, namely cyanide and dissoluble fluoride in the aluminum ash are separated from the aluminum ash, convenience is brought to later harmless treatment, meanwhile the chloride in the aluminum ash is dissolved, and the situation that later disliquid process is affected by the chloride is avoided; and therefore, the purpose that potential danger is eliminated while the aluminum ash is recycled is achieved.

The invention discloses a method for preparing high-purity magnesium oxide from nesquehonite by a carbon-ammonia recycle method, belonging to the field of chemical production of inorganic salts. The method comprises the following steps of: with brine magnesium chloride as a raw material, preparing a nesquehonite intermediate which has good crystalline form and is easy to filter by using the carbon-ammonia recycle method; further calcining to produce high-purity magnesium oxide and simultaneously realize the recycle of carbon dioxide and ammonia, wherein the carbon dioxide is generated in the process of calcining the nesquehonite, and the ammonia is obtained by evaporating the ammonium chloride mother liquid and used for depositing magnesium. The method has the advantages of fully solving the problem of greenhouse effect and environmental pollution caused by ammonium chloride emission in the process of producing magnesium oxide and realizing high-value utilization of sea salt magnesium chloride resources. The method disclosed in the invention has high operability and is easy for industrialized production.

The invention relates to a method for simultaneously preparing magnesium hydroxide, magnesium oxide and gypsum from dolomite lime denitration and desulfurization of flue gas, and belongs to the technical field of flue gas pollution control. The problems of separation of dolomite lime calcium-magnesium separation are ingeniously solved by a low-cost solution of NH4Cl. Ammonia gas (NH3) obtained by ammonia distillation in a calcium-magnesium separation process is heated for denitration. Mg(OH)2 precipitates formed in the calcium-magnesium separation process are used for the desulfurization of the flue gas. A solution of CaCl2 subjected to solid-liquid separation after calcium-magnesium separation is used for precipitating a solution of MgSO4 generated by desulfurization to produce byproducts CaSO4.1/2H2O building gypsum and a solution of MgCl2. Residual Mg(OH)2 is dried or calcinated to form a finished product Mg(OH)2 or MgO. According to the method, the denitration and desulfurization cost is greatly lowered; in addition, a novel production process for magnesium hydroxide and magnesium oxide products are created, and waste is comprehensively utilized.

The invention discloses a harmless treatment method and device for aluminum ash residues, wherein the aluminum ash residues comprise aluminum nitride. The harmless treatment method comprises the stepsthat water and a reactant are added into the aluminum ash residues for a nitrogen removal reaction to obtain aluminum ash residue turbid liquid, wherein the aluminum ash residue turbid liquid comprises ammonium salts and aluminum ash residues subjected to nitrogen removal, and the reactant comprises one or more of hydrogen peroxide, peracetic acid, calcium oxide, sodium carbonate, acetic acid anddilute sulfuric acid. According to the harmless treatment method and device for the aluminum ash residues, ammonia gas is avoided, the phenomenon that aluminum nitride is coated with aluminum hydroxide is avoided, the nitrogen removal rate is increased, and then the aluminum nitride in the aluminum ash residues is efficiently removed in a low-cost and harmless mode.

The invention relates to the technical field of medium and low grade phosphorus ore pretreatment, particularly to a medium and low grade phosphorus ore magnesium removal treatment method. A magnesium element in a phosphorus ore is converted into an oxide from carbonate after steps of calcining digestion, leaching, absorption, separation and ammonium carbonate treatment, the ionic state is presented in a solution to enable the magnesium element to be separated out, and the treatment is performed on obtained filtrate to enable nitrate in the filtrate to be recycled; absorption and utilization are performed on the waste gas produced in the calcining process and the ammonia gas produced in the leaching process to obtain ammonium carbonate; the ammonium carbonate is reacted in the filtrate to obtain an ammonium nitrate solution and magnesium contained calcium carbonate, the ammonium nitrate solution is returned to the leaching step, and accordingly the discharge of the waste liquid is avoided, the magnesium contained calcium carbonate additional product is obtained, and the additional process value is increased.

The invention discloses a titanium dioxide-based catalyst, and a preparation method and application thereof. The preparation method comprises the following steps: mixing titanyl sulfate, niobium pentachloride, urea, sodium dodecyl benzene sulfonate and water, then carrying out a reaction, carrying out cooling after the reaction, and subjecting a precipitate to centrifugation, washing, drying and calcinations so as to obtain a titanium niobium binary oxide carrier; and mixing the titanium niobium binary oxide carrier with an aqueous copper nitrate solution and then carrying out ultrasonic treatment, stirring, drying and calcining successively so as to obtain the titanium dioxide-based catalyst. The preparation method provided by the invention is simple in process and easy to operate and implement. The titanium dioxide-based catalyst prepared in the invention can be used for selective catalytic reduction of nitrogen oxides in virtue of ammonia, has high nitrogen oxide reduction ability and nitrogen selectivity, a wide reaction window, high anti-sulfur dioxide poisoning performance and high hydrothermal stability, and also has the advantages of economic performance, environment friendliness, easiness in industrialization, etc.

The invention discloses a method for preparing magnesium hydrate through ammonia spray method. The method comprises the following steps: by using caustic calcined magnesite and ammonium salt as raw materials, carrying out ammonia stilling reaction to obtain an ammonium and magnesium salt solution, wherein the ammonium and magnesium salt are contacted in a spray type reactor and magnesium hydrate precipitation reaction is performed, aging product mother liquor for a proper time, filtering, returning filtrate containing ammonium salt to an ammonia stilling system, washing and drying filter cake to obtain magnesium hydrate product with uniform particle shape and good dispersion state. The process disclosed by the invention is used for preparing magnesium hydrate through one-step reaction, is simple in operation step, mild in reaction condition, uniform in product particle shape, and the particle shape can be regulated by changing the reaction condition. The ammonium slat is circulated with the ammonia in the reaction process, the production cost is low, the pollution is less, and the scale production is realized, the product can be used as production raw material of high-pure magnesium oxide and inflaming retarding additive of polymer material.

The invention relates to a clean method for extracting vanadium during roasting vanadium slag. The method comprises the following steps that vanadium in the vanadium slag is converted into calcium vanadate which is stable at high temperature by adopting a calcification roasting method, high-concentration ammonium sulfate and/or ammonium bisulfate solution are utilized for leaching roasted clinkerto enable most of ammonium metavanadate to be crystallized and then to be mixed with tailings to form crystal-containing slag, then the crystal-containing slag is dissolved in a hot liquid to obtain avanadium-containing solution, and efficient extraction of the vanadium can be realized. According to the method, the problem of high-temperature vanadium volatilization does not exist, the comprehensive recovery rate of the vanadium is higher, ammonia gas is not generated in the leaching process, and compared with other easily-decomposed ammonium salts, the conversion rate of the vanadium is higher under the same concentration and the same leaching temperature; and meanwhile, the problems of small solubility of ammonium metavanadate in the ammonium salt solution and low vanadium extraction rate can be effectively solved. In the subsequent processes, ammonia gas generated by calcining ammonium metavanadate is adsorbed by using a sulfuric acid solution, the ammonium sulfate can be resynthesized, the ammonia recycling can be realized, the whole process is clean, the production cost is greatly reduced, and the method has good economic benefit and application prospect.

The invention relates to method for preparing magnesium oxide, nickel and cobalt or white carbon black through utilizing serpentine, or for simultaneously preparing magnesium oxide, nickel, cobalt and white carbon black through utilizing serpentine. The method comprises the following steps: roasting a raw material serpentine, milling, leaching by an ammonium salt containing NH4<+> to obtain a magnesium ion solution, preparing a magnesium carbonate hydrate intermediate which has a good crystal form and is easy to filter through an ammonium carbonate cycle process, calcining to produce highly pure magnesium oxide; leaching above filter residues by hydrochloric acid, filtering, adding magnesium oxide to an obtained filtrate to adjust the pH value to obtain precipitated nickel and cobalt; dissolving an obtained filtrate residue through a concentrated alkali, and neutralizing by sulfuric acid to prepare a white carbon black product. The method has the following advantages: magnesium, nickel, cobalt and silicon in the serpentine are comprehensive utilized, and the cycle use of carbon dioxide, ammonia gas and a mother liquor containing NH4<+> is realized; an aqueous solution containing the NH4<+> is adopted as a leaching solvent, so there is no extract Ca, Al and Fe impurity removal operation of an obtained magnesium ion solution; and magnesium oxide is adopted to adjust the pH value, so other impurities are not introduced.

The invention provides a method for extracting vanadium from vanadium-contained raw material clinker via ammonium oxalate leaching. The method comprises the following steps: conducting blank roasting on a vanadium-contained raw material, so as to obtain the vanadium-contained raw material clinker; leaching the vanadium-contained raw material clinker in an ammonium oxalate solution for vanadium extraction; carrying out solid-liquid separation, so as to obtain leaching residue and vanadium-contained liquid. The method has the advantages that the selective vanadium leaching rate can reach up to 90% or higher; the impurity element content of the obtained vanadium-contained liquid is low; the PH value of the obtained vanadium-contained liquid is proper; the purification and impurity removing process can be simplified or eliminated, so as to facilitate the nest step of vanadium precipitation and preparation of a high-purity vanadium product; no salinity-contained wastewater is generated; the ammonium oxalate solution, which serves as a leaching agent, cannot volatilize, so as to avoid the volatilization problem of ammonia gas; and moreover, the method is simple in leaching technological process, environmentally friendly in operation, and low in production cost.

The invention relates to a method for producing industrial monoammonium phosphate through a fluoride salt purification method. Wet process phosphoric acid is used as a raw material, powdered rock phosphate is added for desulfuration, sodium carbonate is added for defluorination, sodium fluosilicate prepared in the defluorination process is added into ammonia water to react, a fluoride salt purifying agent is prepared, after desulfurized and defluorinated phosphoric acid is neutralized with ammonia gas, the prepared fluoride salt purifying agent is added to adjust the pH value, the reaction continues to be conducted after a period of time, filtering is carried out while the mixture is hot to obtain a monoammonium solution, a complexing agent is added to complex microelements, and after complete dissolution, water-soluble monoammonium phosphate is prepared through concentration, crystallization, separation and drying. The fluoride salt purifying agent produced from fluorine in wet process phosphoric acid is used for removing most impurities in monoammonium phosphate slurry, the impurity removal effect is remarkable, and industrial monoammonium phosphate has the advantages of being high in purity, simple in process, low in cost and suitable for industrial large-scale production and has few impurities.

A method for preparing high-purity ammonium polyvanadate belongs to the technical field of hydrometallurgy and vanadium chemical industry. The method comprises the following steps: feeding ammonia gas into the vanadium-containing purified leaching solution, adjusting the pH value to 4.0-7.0, stirring, Sodium ammonium vanadate is obtained after filtration; the sodium ammonium vanadate is heated and dissolved after adding water, ammonium salt is added and the pH value is adjusted to 2.0-3.0 to obtain high-purity ammonium polyvanadate. The method has the advantages of simple process, low cost, and easy operation. The content of the prepared high-purity ammonium polyvanadate is greater than 90%, and the vanadium yield is greater than 90%. It has good social and economic benefits and is convenient for industrial promotion.

The invention discloses a method for preparing hydrogen fluoride and sodium fluoride by use of fluosilicic acid. The method comprises the following steps of: adding ammonium bifluoride into fluosilicic acid for reaction, and performing distillation, thereby obtaining a hydrogen fluoride gas and an ammonium fluosilicate solid; 2) adding aqueous ammonia into ammonium fluosilicate for reaction, performing filtration to obtain white carbon black, heating and distilling a filtrate to obtain an ammonia gas and an ammonium bifluoride solid; and 3) reacting the ammonium bifluoride obtained in the step 2) with sodium carbonate or sodium bicarbonate, filtering the filtrate after reaction is over, thereby obtaining a sodium fluoride precipitate, distilling the filtrate, and collecting the ammonia gas. The method is wide in raw material source, low in cost, low in equipment requirement, less in pollution and low in energy consumption, is capable of repeatedly using ammonium bifluoride and aqueous ammonia and converting ammonium bifluoride and sodium carbonate or sodium bicarbonate into sodium fluoride and hydrogen fluoride which are relatively high in application value and wide in application range, and has favorable economic benefits and environmental benefits.