9 results about "Perchlorate ion" patented technology

The preparation method comprises the following steps: after a micro electrode is prepared through 3D printing, iodine is loaded on the surface of the micro electrode to form an iodine positive electrode; preparing a zinc negative electrode matched with the iodine positive electrode in shape through laser engraving; uniformly mixing water, hyaluronic acid, hydrophilic silicon dioxide, zinc perchlorate and zinc bromide to form a gel electrolyte; and sequentially laminating the iodine positive electrode, the gel electrolyte and the zinc negative electrode on the substrate, and packaging to obtain the wide-temperature-range micro zinc-iodine battery. According to the gel electrolyte disclosed by the invention, hyaluronic acid and hydrophilic silicon dioxide lock water through hydrogen bonds formed between hyaluronic acid and hydrophilic silicon dioxide and water molecules, evaporation of water at a high temperature is inhibited, perchlorate inhibits solidification of water at a low temperature by destroying hydrogen bond structures between water molecules in a gel network, and a wide temperature range of a miniature battery is realized; meanwhile, bromide ions in the electrolyte are transmitted to a positive electrode through an interface to excite a four-electron reaction of iodine, so that the energy density of the micro zinc-iodine battery is improved.

The present application provides a kind of medicament for treating waste water containing perchlorate, it consists of two parts of targeted removal agent and guide activator, the core component of the targeted removal agent includes dodecyl trimethylammonium chloride, dodecyl dimethyl benzyl ammonium chloride, hexadecyl trimethylammonium chloride, octadecyl trimethylammonium chloride and the like.The guide activator includes one or more of polymeric ferric sulfate, polymeric ferric chloride, polymeric aluminum ferric chloride, polymeric aluminum ferric silicate.The treatment medicament component of the present application is simple, wherein a large number of high perchlorate ion groups contained therein can be fully combined with perchlorate in waste water, and perchlorate is precipitated from water in the form of precipitation, and then separated and removed, with a removal rate of more than 95% in one step.

The invention relates to an adsorption coagulation treatment method for perchlorate wastewater. The method comprises the following steps: reducing the turbidity of the wastewater by using activated carbon as a pretreating agent; capturing perchlorate radicals through a hydrolysate by adopting polyaluminum chloride as a coagulant; then potassium permanganate and manganese chloride tetrahydrate are subjected to an oxidation-reduction reaction to generate nascent state manganese dioxide in situ; the nascent state manganese dioxide and the polyaluminum chloride hydrolysate form a composite floc through a bonding effect, and perchlorate is removed through an adsorption-coagulation synergistic effect. According to the treatment method disclosed by the invention, on the basis of the volume of the wastewater, the dosage of each component is as follows: 0.1-0.5 g / L of activated carbon, 30-45 mg / L of polyaluminum chloride, 20-80 mg / L of potassium permanganate and 40-160 mg / L of manganese chloride tetrahydrate. The invention relates to an adsorption and coagulation treatment method for perchlorate wastewater, which is used for treating perchlorate wastewater generated in industries such as military industry, spaceflight and firework production.

The application discloses a wide-temperature-range micro zinc-iodine battery and a preparation method thereof, and comprises the following steps: after a micro electrode is prepared through 3D printing, an iodine anode is formed by loading iodine on the surface of the micro electrode; a zinc cathode matching the shape of the iodine anode is prepared through laser engraving; water, hyaluronic acid, hydrophilic silicon dioxide, zinc perchlorate and zinc bromide are uniformly mixed to form a gel electrolyte; the iodine anode, the gel electrolyte and the zinc cathode are sequentially laminated on a substrate, and then the wide-temperature-range micro zinc-iodine battery is obtained after packaging. In the gel electrolyte, the hyaluronic acid and the hydrophilic silicon dioxide lock water through hydrogen bonds with water molecules, inhibit the evaporation of water at high temperature, and the perchlorate ion inhibits the freezing of water at low temperature by destroying the hydrogen bond structure between water molecules in the gel network, so that the wide-temperature-range micro battery is realized; meanwhile, the bromide ion in the electrolyte is transmitted to the anode through the interface to excite the four-electron reaction of iodine, so that the energy density of the micro zinc-iodine battery is improved.

The invention discloses a curable additive containing a polymer monomer I and a perfluoroalkyl ionic liquid II, a high oxidation potential electrolyte containing the curable additive and a battery, the structural formula of the polymer monomer I is shown in the specification, wherein R1-R3 are selected from C1-C4 alkyl, alkoxy, halogenated alkyl or halogenated alkoxy, and the structural formula of the perfluoroalkyl ionic liquid II is shown in the specification. R4 is selected from alkylene groups or halogenated alkyl groups of C1-C6, and R5 is selected from alkyl groups or halogenated alkyl groups of C1-C2; the structural formula of the perfluoroalkyl ionic liquid II is shown in the specification, wherein X and Y are respectively and independently selected from one or more of imidazoles, pyridines, quaternary ammonium, quaternary phosphorus, pyrrolidines or piperidines, and R is selected from perfluoro-substituted C1-C10 alkylene; z <-> and Z < '-> are respectively and independently selected from one or more of halide ions, phosphate ions, perchlorate ions, sulfimide ions, oxalato borate ions, sulfonate ions and acetate ions. The invention constructs the high oxidation potential electrolyte and the battery with high safety and conductivity.

The invention provides an aqueous sodium-ion battery electrolyte, a preparation method and application thereof, and an aqueous sodium-ion battery. The aqueous sodium-ion battery electrolyte comprises electrolyte salt and water, wherein positive ions of the electrolyte salt are sodium ions and quaternary ammonium salt positive ions, and negative ions of the electrolyte salt are perchlorate ions; the quaternary ammonium salt cations are asymmetric quaternary ammonium salt cations. The aqueous sodium-ion battery electrolyte contains asymmetric alkyl perchlorate quaternary ammonium salt, the quaternary ammonium salt is used as a large-size cation, so that the relative proportion of water is reduced, the asymmetric structure can endow the aqueous sodium-ion battery electrolyte with higher polarity and water solvation action capability, and an electrochemical window is broadened more efficiently; and the irregularity of the molecules also endows the electrolyte with weaker crystallization tendency, so that the stability of the electrolyte and the corresponding battery cycle is improved.

This invention discloses a novel anion exchange resin for adsorbing perchlorate ions and its preparation method. The novel anion exchange resin is prepared using polyvinylbenzyl chloride, dioxane, and N,N-dimethylethanolamine. This resin improves the adsorption efficiency and effect for perchlorate ions, has a high regenerability, can resist interference from complex systems, and enhances the stability and service life of the resin.

The invention relates to the field of energy storage devices, in particular to a multifunctional aqueous zinc-iodine battery and an electrolyte thereof, and the multifunctional aqueous zinc-iodine battery comprises zinc ions and an electrolyte additive, the zinc ion source is zinc salt, and anions of the zinc salt are one or more of sulfate ions, acetate ions, nitrate ions, trifluoromethanesulfonate ions, perchlorate ions and the like; during working, the zinc-iodine battery is subjected to an I- / I2 / I + reversible oxidation-reduction reaction on the positive electrode side, and is subjected to Zn / Zn < 2 + > reversible dissolution / deposition on the negative electrode side. When Zn / Zn < 2 + > reversible dissolution / deposition occurs in the zinc negative electrode, through interaction of the electrolyte additive and Zn < 2 + >, crystal face growth of Zn metal (002) is promoted, hydrogen evolution reaction is inhibited, uniform deposition of zinc in the negative electrode is finally induced, and the cycle life of the negative electrode is prolonged. On one side of the positive electrode, the electrolyte additive interacts with other functional groups through a halogenated group to form a negative potential accumulation region, so that stable existence of I < + > ions is realized.

The invention discloses a high-voltage cross-linked perfluoroalkyl ionic liquid and application thereof in a battery. The high-voltage cross-linked perfluoroalkyl ionic liquid has a structure shown in a formula (1), wherein X and Y are independently selected from one or more of imidazoles, pyridines, quaternary ammonium, quaternary phosphorus, pyrrolidines or piperidines, and R is selected from perfluoro-substituted C1-C10 alkylene; z <-> and Z < '-> are respectively and independently selected from one or more of halide ions, phosphate ions, perchlorate ions, sulfimide ions, oxalato borate ions, sulfonate ions and acetate ions. The fluorine element is introduced into the ionic liquid structure through molecular design, so that the ion transmission, oxidation resistance and safety performance of the ionic liquid are improved, and the high-safety and high-energy-density solid-state battery is further prepared.